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Chapter 15 Ionic Bonding and Compounds
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The properties and chemical reactivity of all compounds is based on how they are bonded together. In this unit we will look at Ionic, Covalent and Metallic bonds Ionic compounds are compounds formed by atoms giving up or receiving electrons.
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Ionic compounds (p.422) Fluoride compound Microscopic view of an ionic compound
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Sodium Chloride
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Limestone: Calcium carbonate
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Review electron configuration and Valence Electrons (p.412-414) Na 1s 2 2s 2 2p 6 3s 1 S 1s 2 2s 2 2p 6 3s 2 3p 4 1s 2 2s 2 2p 6 3s 2 3p 4Cl 1s 2 2s 2 2p 6 3s 2 3p 5 Notice that the number of valence electrons (the electrons in the outer most energy levels) correspond with their ‘family/group’ Add this to your periodic tables
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Electron Dot Diagrams (p. 414) Structures that show the element and how many valence electrons it has See Table 15.1 This will be helpful when determining how many elements are required for chemical bonding
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The Duet and Octet Rule (p. 414-415) Remember that most atoms (representative elements) want to obtain the electron configurations of a noble gas; they want their outer most energy level filled This is called the duet (if the atom is closer to helium, such as Lithium) or octet rule (for the rest of the noble gases) 1s 2 for the duet or ns 2 np6 for the octet
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Electron Configuration for Cations (p. 414-416) Remember that Cations are atoms that have LOST electrons. They are positively charged Look at the Lewis Dot Diagrams for Na and Mg It is easier for them to LOSE their outer most electrons, so the will form cations and obtain the electron configuration of Neon Their outer most electrons are in the 3s 2 and 3p 6 They have obeyed the ‘octet’ rule
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Electron Configuration for Anions (p. 417-418) Remember that Anions are atoms that have GAINED electrons. They are negatively charged. Look at the Lewis Dot Diagrams for O and F. It is easier for them to GAIN electrons in their outer most shells, so the will form anions and also obtain the electron configuration of Neon Their outer most electrons are in the 3s 2 and 3p 6 They have obeyed the ‘octet’ rule
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Ionic Bonds (p. 419-421) Ionic bonds are compounds formed between cations and anions How would you write the formula potassium chloride? KCl (a ratio of 1:1) Now go back and write the Lewis Dot Diagrams for each. Notice that K is needing to give up one electron and Cl is wanted to gain one electron Hence the ratio of 1:1
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Practice writing the following: Calcium Oxide Barium Nitride Cesium Oxide
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Homework: p. 418 #1,2,3,4,6; p. 425 #9, 10, 11, 12abc, 13; p. 432 #20, 23, 24, 26, 30, 33, 37 Take your Chemistry book and binder to lab this week
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