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Published byJared Rodgers Modified over 9 years ago
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KMT and Graham’s Law
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Molecular Speed Of A Gas Depends on the mass of the gas molecules and the temperature they are at R is in different units and has a different value ( R=8.3145) M is molar mass in kg/mole
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Example Find the speed of hydrogen gas at 25 o C. Find the speed of oxygen gas at 25 o C.
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Effusion Gas escapes through tiny holes when a pressure difference is present
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Diffusion Gases will mix uniformly
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Graham’s Law Rate of both effusion and diffusion is inversely related to the square root of their weights Shows the relationship between rate and molecular weight
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Example If an unknown gas effuses at a rate that is only.468 times that of oxygen at the same temperature, what is its molecular weight?
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Ideal vs. Real Gas Behavior Ideal gases follow all of the gas laws outlined No gas is totally ideal, but at low pressures and/or high temperatures most come close Gases will deviate significantly from ideal at high pressures and/or low temperatures - particles become closer together and intermolecular forces between significant
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