1. Science, Systems, Matter, and Energy
Chapter 2
Science, Systems, Matter, and Energy
Matter
“High-Q” Energy
“Low-Q” Energy

2. Chapter Overview Questions
What is science, and what do scientists do?
What are major components and behaviors of complex systems?
What are the basic forms of matter, and what makes matter useful as a resource?
What types of changes can matter undergo and what scientific law governs matter?

3. Chapter Overview Questions (cont’d)
What are the major forms of energy, and what makes energy useful as a resource?
What are two scientific laws governing changes of energy from one form to another?
How are the scientific laws governing changes of matter and energy from one form to another related to resource use, environmental degradation and sustainability?

4. THE NATURE OF SCIENCE Purpose of science: What do scientists do?
Discover order in the natural world and make predictions about what is likely to happen in the future
What do scientists do?
Collect data.
Form hypotheses.
Develop theories, models and laws about how nature works.
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5. Stepped Art Ask a question Do experiments and collect data
Interpret data
Well-tested and
accepted patterns
In data become
scientific laws
Formulate hypothesis
to explain data
Do more experiments
to test hypothesis
Revise hypothesis
if necessary
Well-tested and
accepted
hypotheses
become
scientific theories
Stepped Art
Fig. 2-3, p. 30

6. Scientific Theories and Laws: The Most Important Results of Science
Scientific Theory
Widely tested and accepted hypothesis.
Atomic Theory
Scientific Law
What we find happening over and over again in nature.
Gravitational Constant
“Peer Review”
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7. by scientific community
Research results
Scientific paper
Peer review by
experts in field
Paper
rejected
Peer Review Process…
Paper accepted
Figure 2.3
Scientists use a peer review process to help identify sound science.
Paper published in
scientific journal
…Brutal!
Research evaluated
by scientific community
Fig. 2-3, p. 30

8. Testing Hypotheses
Scientists test hypotheses using controlled experiments and constructing mathematical models.
Variables or factors influence natural processes
Single-variable experiments involve a control and an experimental group.
Most environmental phenomena are multivariate and are hard to control in an experiment.
Models are used to analyze interactions of variables.

9. A Controlled Experiment:The Effects of Deforestation on the Loss of Water and Soil Nutrients (p.28)9

10. Scientific Reasoning and Creativity
Inductive reasoning
Involves using specific observations and measurements to arrive at a general conclusion or hypothesis.
Bottom-up reasoning going from specific to general.
Deductive reasoning
Uses logic to arrive at a specific conclusion.
Top-down approach that goes from general to specific.

11. Frontier Science, Sound Science, and Junk Science
Reliable science a.k.a. consensus science a.k.a. sound science consists of data, theories and laws that are widely accepted by experts.
Tentative science a.k.a. frontier science has not been widely tested (starting point of peer-review).
Unreliable science a.k.a. junk science is presented as sound science without going through the rigors of peer-review.

12. Paradigm Shift
Paradigm Shift- a complete change in worldview as a result of new information
Ex Earth-centered to sun-centered view of solar system

13. Limitations of Environmental Science
Inadequate data and scientific understanding can limit and make some results controversial.
Scientific testing is based on disproving rather than proving a hypothesis.
Based on statistical probabilities.

14. MODELS AND BEHAVIOR OF SYSTEMS
Usefulness of models
Complex systems are predicted by developing a model of its inputs, throughputs (flows), and outputs of matter, energy and information.
Models are simplifications of “real-life”.
Models can be used to predict if-then scenarios.
Poorly defined models of a system result in unreliable results…models are continuously tested against new real data

15. Feedback Loops: How Systems Respond to Change
Outputs of matter, energy, or information fed back into a system can cause the system to do more or less of what it was doing.
Positive feedback loop (a.k.a.reinforcing loop) causes a system to change further in the same direction (e.g. population, fighting, erosion, greed)
Negative feedback loop (a.k.a. balancing loop) causes a system to change in the opposite direction (e.g. seeking shade from sun to reduce stress, hunger & eating, body temp regulation).

16. Feedback Loops: How Systems Respond to Change
Practice Positive Practice Negative
Feedback Loop Feedback Loop
•brother & sister yelling • hunger & eating
Draw each loop and determine if it represents positive or negative feedback:
• thirst & drinking
•pine trees & seeds
•body temperature (hot day) & sweating
•bank account & interest payment
•angry thought & angry feelings

17. Feedback Loops:
Threshold Behavior- Negative feedback can take so long that a system reaches a tipping point and drastically changes.
E.g. tipping over in a chair; the recent economic troubles; a smoker gets cancer
Prolonged delays may prevent a negative feedback loop from occurring.
Synergy- Processes and feedbacks in a system can interact to amplify the results.
E.g. smoking exacerbates the effect of asbestos exposure on lung cancer.

18. Feedback Loops: Some negative feedback loops have explicit goals
Balancing Metersticks
Body Temperature
Blood CO2 levels
Etc.

19. TYPES AND STRUCTURE OF MATTER
Elements and Compounds
Matter exists in chemical forms as elements and compounds.
Elements (represented on the periodic table) are the distinctive building blocks of matter.
Carbon, hydrogen, oxygen, nitrogen, etc
Compounds: two or more different elements held together in fixed proportions by chemical bonds.
CO2, H2O, C6H12O6

20. Atoms
Figure 2-4

21. Ions
An ion is an atom or group of atoms with one or more net positive or negative electrical charges.
The number of positive or negative charges on an ion is shown as a superscript after the symbol for an atom or group of atoms
Hydrogen ions (H+), Hydroxide ions (OH-)
Sodium ions (Na+), Chloride ions (Cl-)

22. *bases are “basic” a.k.a. “alkaline”
The pH (potential of Hydrogen) is the concentration of hydrogen ions in one liter of solution.
0 = strongest acids
7 = neutral
14 = strongest base
pH adjectives:
*acids are “acidic”
*bases are “basic” a.k.a. “alkaline”
Figure 2-5

23. Figure 2-5

24. Compounds and Chemical Formulas
Chemical formulas are shorthand ways to show the atoms and ions in a chemical compound.
Combining Hydrogen ions (H+) and Hydroxide ions (OH-) makes the compound H2O (dihydrogen oxide, a.k.a. water).
Combining Sodium ions (Na+) and Chloride ions (Cl-) makes the compound NaCl (sodium chloride a.k.a. salt).

25. Organic Compounds: Carbon Rules
Organic compounds contain carbon atoms combined with one another and with various other atoms such as H+, N+, or Cl-.
Organic compounds contain at least two carbon atoms combined with each other and with atoms.
Methane (CH4) is the only exception.
All other compounds (without C) are inorganic.

26. Organic Compounds: Carbon Rules
Hydrocarbons: compounds of carbon and hydrogen atoms (e.g. methane (CH4)).
Chlorinated hydrocarbons: compounds of carbon, hydrogen, and chlorine atoms (e.g. DDT (C14H9Cl5)).
Simple carbohydrates: certain types of compounds of carbon, hydrogen, and oxygen (e.g. glucose (C6H12O6)).
Complex carbohydrates: chains of glucose, such as starch or cellulose

27. Cells: The Fundamental Units of Life
Cells are the basic structural and functional units of all forms of life.
Prokaryotic cells (bacteria) lack a distinct nucleus.
Eukaryotic cells (plants and animals) have a distinct nucleus.
Figure 2-6

28. DNA (information storage, no nucleus)
(a) Prokaryotic Cell
DNA (information storage, no nucleus)
Figure 2.6
Natural capital: (a) generalized structure of a prokaryotic cell. Note that a prokaryotic cell lacks the distinct nucleus and generalized structure of (b) a eukaryotic cell. The parts and internal structure of cells in various types of organisms such as plants and animals differ somewhat from this generalized model.
Cell membrane
(transport of
raw materials and
finished products)
Protein construction
and energy conversion
occur without specialized
internal structures
Fig. 2-6a, p. 37

29. (b) Eukaryotic Cell Nucleus (information storage) Energy conversion
Figure 2.6
Natural capital: (a) generalized structure of a prokaryotic cell. Note that a prokaryotic cell lacks the distinct nucleus and generalized structure of (b) a eukaryotic cell. The parts and internal structure of cells in various types of organisms such as plants and animals differ somewhat from this generalized model.
Protein
construction
Cell membrane
(transport of raw
materials and
finished products)
Packaging
Fig. 2-6b, p. 37

30. Macromolecules, DNA, Genes and Chromosomes
Large, complex organic molecules (macromolecules) make up the basic molecular units found in living organisms.
Complex carbohydrates
Proteins
Nucleic acids
Lipids
Figure 2-7

31. Stepped Art Fig. 2-7, p. 38 A human body contains trillions
of cells, each with an identical
set of genes.
There is a nucleus inside each
human cell (except red blood cells).
Each cell nucleus has an identical
set of chromosomes, which are
found in pairs.
A specific pair of chromosomes
contains one chromosome from
each parent.
Each chromosome contains a long
DNA molecule in the form of a coiled
double helix.
Genes are segments of DNA on
chromosomes that contain instructions
to make proteins—the building blocks
of life.
The genes in each cell are coded
by sequences of nucleotides in
their DNA molecules.
Stepped Art
Fig. 2-7, p. 38

32. States of Matter
The atoms, ions, and molecules that make up matter are found in three physical states:
solid, liquid, gaseous.
A fourth state, plasma, is a high energy mixture of positively charged ions and negatively charged electrons.
The sun and stars consist mostly of plasma.
Scientists have made artificial plasma (used in TV screens, gas discharge lasers, florescent light).

33. Matter Quality
Matter can be classified as having high or low quality depending on how useful it is to us as a resource.
High quality matter is concentrated and easily extracted.
low quality matter is more widely dispersed and more difficult to extract.
Figure 2-8

34. Coal-fired power plant emissions
High Quality
Low Quality
Solid
Gas
Salt
Solution of salt in water
Coal
Coal-fired power plant emissions
Figure 2.8
Examples of differences in matter quality. High-quality matter (left column) is fairly easy to extract and is concentrated; low-quality matter (right column) is more difficult to extract and is more widely dispersed than high-quality matter.
Gasoline
Automobile emissions
Aluminum can
Aluminum ore
Fig. 2-8, p. 39

35. CHANGES IN MATTER
Matter can change from one physical form to another or change its chemical composition.
When a physical or chemical change occurs, no atoms are created or destroyed.
Law of conservation of matter.
Physical change maintains original chemical composition.
Chemical change involves a chemical reaction which changes the arrangement of the elements or compounds involved.
Chemical equations are used to represent the reaction.

36. Chemical Change Energy is given off during the reaction as a product.
Mass does not change (Conservation of Matter)

37. Three Types of Atomic Nuclear Changes
Radioactive decay
Fission- splitting atoms (like uranium)
First atomic bombs
All nuclear power plants
Fusion- fusing atoms together (like hydrogen)
“H-Bomb”
Sun and all other stars
100 million degrees Celsius to begin reaction

38. Nuclear Changes: Fission
Nuclear fission: nuclei of certain isotopes with large mass numbers are split apart into lighter nuclei when struck by neutrons.
Figure 2-9

39. Stepped Art Fig. 2-6, p. 28 Uranium-235 Energy Fission fragment n
Neutron
Stepped Art
Fig. 2-6, p. 28

40. Nuclear Changes: Fusion
Nuclear fusion: two isotopes of light elements are forced together at extremely high temperatures until they fuse to form a heavier nucleus.
Figure 2-10

41. Reaction Conditions Products Fuel Proton Neutron Energy Hydrogen-2
(deuterium nucleus) +
100
million °C +
Figure 2.10
The deuterium–tritium (D–T) nuclear fusion reaction takes place at extremely high temperatures.
Helium-4 nucleus + +
Hydrogen-3
(tritium nucleus)
Neutron
Fig. 2-10, p. 42

42. Nuclear Changes: Radioactive Decay
Natural radioactive decay: unstable isotopes spontaneously emit fast moving chunks of matter (alpha or beta particles), high-energy radiation (gamma rays), or both at a fixed rate.
Radiation is commonly used in energy production and medical applications.
The rate of decay is expressed as a half-life (the time needed for one-half of the nuclei to decay to form a different isotope).

43. Matter: Types of Pollutants
Factors that determine the severity of a pollutant’s effects: chemical nature, concentration, and persistence.
Pollutants are classified based on their persistence:
Degradable pollutants- can be broken down
Biodegradable pollutants- e.g. human sewage
Slowly degradable pollutants- e.g. most plastics; chlorinated hydrocarbons like DDT
Nondegradable (a.k.a. persistent) pollutants- e.g. lead, mercury, arsenic

44. ENERGY Energy is the ability to do work and transfer heat.
Kinetic energy –
energy in motion
heat, electromagnetic radiation
Potential energy –
stored for possible use
batteries, glucose molecules, any food, water behind a dam

45. Electromagnetic Spectrum
Many different forms of electromagnetic radiation exist, each having a different wavelength and energy content.
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46. Sun Ionizing radiation Nonionizing radiation Cosmic rays Gamma Rays
Far
ultra-
violet
waves
Near
ultra-
violet
waves
Near
infrared
waves
Far
infrared
waves
Cosmic
rays
Gamma
Rays
X rays
Visible
Waves
Micro-
waves TV
waves
Radio
Waves
Figure 2.11
The electromagnetic spectrum: the range of electromagnetic waves, which differ in wavelength (distance between successive peaks or troughs) and energy content.
High energy, short
Wavelength
Wavelength in meters
(not to scale)
Low energy, long
Wavelength

47. Electromagnetic Spectrum
Organisms vary in their ability to sense different parts of the spectrum.
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48. Energy emitted from sun (kcal/cm2/min)
Visible
Figure 2.12
Solar capital: the spectrum of electromagnetic radiation released by the sun consists mostly of visible light.
Infrared
Ultraviolet
Wavelength (micrometers)
Fig. 2-12, p. 43

49. Source of Energy Energy Tasks Relative Energy Quality (usefulness)
Electricity
Very high temperature heat
(greater than 2,500°C)
Nuclear fission (uranium)
Nuclear fusion (deuterium)
Concentrated sunlight
High-velocity wind
Very high-temperature heat (greater than 2,500°C) for industrial processes and producing electricity to run electrical devices (lights, motors)
High-temperature heat
(1,000–2,500°C)
Hydrogen gas
Natural gas
Gasoline
Coal
Food
Mechanical motion to move
vehicles and other things)
High-temperature heat
(1,000–2,500°C) for
industrial processes and
producing electricity
Normal sunlight
Moderate-velocity wind
High-velocity water flow
Concentrated geothermal energy
Moderate-temperature heat
(100–1,000°C)
Wood and crop wastes
Moderate-temperature heat
(100–1,000°C) for
industrial processes, cooking, producing
steam, electricity, and
hot water
Figure 2.13
Natural capital: categories of the qualities of different sources of energy. High-quality energy is concentrated and has great ability to perform useful work. Low-quality energy is dispersed and has little ability to do useful work. To avoid unnecessary energy waste, you should match the quality of an energy source with the quality of energy needed to perform a task.
Dispersed geothermal energy
Low-temperature heat
(100°C or lower)
Low-temperature heat
(100°C or less) for
space heating
Fig. 2-13, p. 44

50. ENERGY LAWS: TWO RULES WE CANNOT BREAK
The first law of thermodynamics: we cannot create or destroy energy (a.k.a. Law of Conservation of Energy)
We can change energy from one form to another.
burning Cheeto: Chemical→ thermal & electromagnetic
The second law of thermodynamics: energy quality always decreases (a.k.a. Law of Entropy)
When energy changes from one form to another, it is always degraded to a more dispersed form.
Energy efficiency is a measure of how much useful work is accomplished before it changes to its next form.

51. Mechanical energy (moving, thinking, living)
Second Law of Thermodynamics
Mechanical energy (moving, thinking, living)
Chemical
energy
(photosynthesis)
Chemical
energy
(food)
Solar
energy
Waste
Heat
Waste
Heat
Waste
Heat
Waste
Heat
Figure 2.14
The second law of thermodynamics in action in living systems. Each time energy changes from one form to another, some of the initial input of high-quality energy is degraded, usually to low-quality heat that is dispersed into the environment.
Fig. 2-14, p. 45

52. SUSTAINABILITY AND MATTER AND ENERGY LAWS
Unsustainable High-Throughput Economies: Working in Straight Lines
Converts resources to goods in a manner that promotes waste and pollution.
Next

53. Throughputs Inputs Outputs
System
Throughputs
Inputs
(from environment)
Outputs
(into environment)
High-quality energy
Unsustainable
high-waste
economy
Low-quality energy (heat)
Matter
Waste and pollution
Figure 2.15
The high-throughput economies of most developed countries rely on continually increasing the rates of energy and matter flow. This practice produces valuable goods and services but also converts high-quality matter and energy resources into waste, pollution, and low-quality heat.
Fig. 2-15, p. 46

54. Energy Inputs Throughputs Outputs Energy resources Heat Matter
Waste and
pollution
Economy
Figure 2.10
Inputs, throughput, and outputs of an economic system. Such systems depend on inputs of matter and energy resources and outputs of waste and heat to the environment. Such a system can become unsustainable if the throughput of matter and energy resources exceeds the ability of the earth’s natural capital to provide the required resource inputs or the ability of the environment to assimilate or dilute the resulting heat, pollution, and environmental degradation.
Goods and
services
Information
Fig. 2-10, p. 44

55. Sustainable Low-Throughput Economies: Learning from Nature
Matter-Recycling-and-Reuse Economies: Working in Circles
Mimics nature by recycling and reusing, thus reducing pollutants and waste.
It is not sustainable for growing populations.
Why not?
Only sustainable if population stabilizes (ZPG)!

56. Figure 2.11
Positive feedback loop. Decreasing vegetation in a valley causes increasing erosion and nutrient losses, which in turn causes more vegetation to die, which allows for more erosion and nutrient losses. The system receives feedback that continues the process of deforestation.
Fig. 2-11, p. 45

57. Figure 2.12
Negative feedback loop. When a house being heated by a furnace gets to a certain temperature, its thermostat is set to turn off the furnace, and the house begins to cool instead of continuing to get warmer. When the house temperature drops below the set point, this information is fed back, and the furnace is turned on and runs until the desired temperature is reached. The system receives feedback that reverses the process of heating or cooling.
Fig. 2-12, p. 45

58. Data Analysis
Marine scientists from the U.S. state of Maryland have produced the following two graphs as part of a report on the current health of the Chesapeake Bay. They are pleased with the recovery of the striped bass population but are concerned about the decline of the blue crab population, because blue crabs are consumed by mature striped bass. Their hypothesis is that as the population of striped bass increases, the population of blue crab decreases.
p. 49

59. Data Analysis
Marine scientists from the U.S. state of Maryland have produced the following two graphs as part of a report on the current health of the Chesapeake Bay. They are pleased with the recovery of the striped bass population but are concerned about the decline of the blue crab population, because blue crabs are consumed by mature striped bass. Their hypothesis is that as the population of striped bass increases, the population of blue crab decreases.
p. 49