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PHASE CHANGES
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Kinetic Theory Kinetic = motion
Particles in a gas are considered to be hard, small spheres with an insignificant volume. The motion of particles in a gas is rapid, constant, and random.
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All collisions between particles in a gas are perfectly elastic.
Particles in a gas only interact when they collide.
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Temperature (in kelvins, K) is directly proportional to the average kinetic energy of the particles of a substance. Objects expand when heated because of increased vibrational motion.
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Gas pressure is caused by the collisions of particles with an object (wall).
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Atmospheric pressure results from the weight of air above an object.
Higher altitudes have less atmospheric pressure.
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Standard atmospheric pressure is:
1 atm = kPa = 760 mm Hg A barometer measures atmospheric pressure.
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Liquids Condensed states of matter – solids and liquids
In liquids KE is high enough for molecules to flow and take the shape of their container.
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Intermolecular attractions give liquids a definite volume.
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Evaporation – changing from liquid to vapor at the surface - cooling process
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Condensation – warming process
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Vapor pressure – pressure in a bubble
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Boiling point – temperature at which the vapor pressure equals external pressure on the liquid
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Gas Stoichiometry 1 mol of a gas at standard temperature and pressure (STP) = 22.4 L
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Volume – Volume Problems
2NO + O2 2NO2 How many liters of nitrogen dioxide are produced when 34 L of O2 react?
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What cancels?
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Volume – Moles Problems
2NO + O2 2NO2 How many moles of nitrogen dioxide are produced when 34 L of O2 react?
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Solids Phase Changes The general properties of solids reflect the orderly arrangement and fixed locations of their particles. Crystal - regular geometric arrangement
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Allotropes - (diamond, graphite) 2 or more different molecular forms of the same element in the same physical state
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Amorphous - no geometric pattern
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Phase changes Sublimation - solid to vapor Vaporization - liquid to vapor (evaporation or boiling) Solidification - liquid to solid Melting - solid to liquid
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A) 0.016C, 0.61 kPa B) S, L, V C) 100C; 0C
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Ch 13 Review Notes Atmospheric pressure affects the boiling point of a liquid.
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STP – standard temperature and pressure - 0C and 1 atm
1 atm = 760 mm Hg so…
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Absolute zero = 0 K is the temperature the motion of particles theoretically ceases.
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Triple point – conditions ( temperature & pressure) at which solid, liquid, and vapor (gas) can exist in equilibrium.
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Solids are more dense than liquids and gases.
Sublimation can occur because solids have a vapor pressure.
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