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Living organisms require energy to perform functions. They: Kidney cells: › to transports materials Digestive tract: › break macromolecules Heart: › to pump
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Metabolism : Anabolism : Catabolism : 4
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Energy : Energy can take many forms: mechanicalelectric current heat light All energy can be classified as: - kinetic energy : - potential energy : 5
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stored energy. › ___________________________________ 6
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Potential energy stored in chemical bonds can be transferred from one molecule to another by way of electrons. oxidation : reduction : redox reactions 8
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Energy of motion › ________________________________________ 9
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http://www.youtube.com/watch?v=Jnj8m c04r9E 10
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Study of heat and energy flow within chemical reactions 11
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First Law of Thermodynamics – For example: sunlight energy chemical energy photosynthesis 12
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Exercise to lose weight › produce heat and you sweat › heats the air around you. When you eat a pizza › energy from the chemical bonds in the bread, cheese, etc. is broken down › converted into ATP molecules through cellular respiration. 13
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_______________________________________ _______________________________________ The enthalpy change (ΔH) › amount of heat released or absorbed when a chemical reaction occurs at a constant pressure. › ΔH formation = _____________________________ 14
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Reactants: Activation energy (Ea): Transition state: Products: 15
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some of the reactant's potential energy is released into the surroundings as heat. enthalpy of the products is ____________________ energy is _____________ ΔH is ____________ 16
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http://cwx.prenhall.com/petrucci/mediali b/media_portfolio/text_images/019_THER MITE.MOV 17
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Second Law of Thermodynamics : entropy : The 2 nd Law of Thermodynamics states that entropy is always increasing. 22
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Free energy : -denoted by the symbol G (Gibb’s free energy) enthalpy : free energy = enthalpy – (entropy x temp.) G = H - TS 24
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Chemical reactions can create changes in free energy. When products contain more free energy than reactants G is positive. When reactants contain more free energy than products G is negative. 25
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Chemical reactions can be described by the transfer of energy that occurs: endergonic reaction : exergonic reaction : 26
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Most reactions require some energy to get started. activation energy : catalysts : 28
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C6H12O6 + O2 → CO2 + H2O + Energy (as ATP) ΔG = - 2870 kJ/mol of glucose release of energy an increase in entropy This reaction tends to proceed spontaneously. 30
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Photosynthesis Chemical Equation CO2 + H2O + Energy → C6H12O6 + O2 ΔG = + 2870 kJ/mol of glucose energy is absorbed a decrease in entropy This reaction does not proceed spontaneously as energy is needed to drive the reaction. 31
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ATP = adenosine triphosphate ATP structure: 32
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Adenosine Triphosphate (ATP) Section 9.1 P P A P
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Mono = One phosphate group Di = Two phosphate groups Tri = three phosphates groups Adenosine Triphosphate (ATP) Section 9.1 P P A P
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The battery of the cell Section 9.1
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When the bond between phosphates is broken: ATP ADP + P i energy is released ADP = adenosine diphosphate P i = inorganic phosphate This reaction is reversible. 37
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Section 1.3, p.68 1, 2, 5, 10, 11 40
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