1. Drill: Give the molecular formula & the condensed, skeletal, and complete structures of a hydrocarbon with the same # of carbons as the # of letters in your first name.

2. Branched Alkanes

3. Any hydrogen in a hydrocarbon chain can be substituted with another hydrocarbon group

4. H H H H-C-C-C-H H H H propane

6. H H H H-C-C-C-H H CH 3 H _____ propane

7. Alkyl Groups The hydrocarbon group that replaces the H is called an alkyl group Suffix: -yl: hydrocarbon group

8. Alkyl Groups 1 =methyl6 = hexyl 2 =ethyl7 =heptyl 3 =propyl8 =octyl 4 =butyl9 =nonyl 5 =pentyl 10 =decyl

9. Branched Chains When an alkane chain gets another hydrocarbon group substituted onto it Branches: alkyl groups or sidechains

10. Drill: Draw C 8 H 18 using 4 different methods.

11. Branched Chains C C C C C C C C C C

12. Naming Branched Chains

13. Drill: Name Each: H 3 C-CH 2 -CH 3 C-C-C-C-C

14. 1) Find the longest continuous carbon chain & name it as the main chain. The final name will end with the naming of the main chain

15. CHexane C C C

16. 2) Number each carbon in the chain; so that, the side chains will be connected to the lowest possible numbers on the carbons

17. CHexane C 1 C 2 C 3 C 4 C 5 C 6 C C C

18. 3) Name the side chains or substituted groups, & precede them with the # of the carbon they are connected to & a dash

19. C 2-methyl C 1 C 2 C 3 C 4 C 5 C 6 C C C 2-methyl 4-ethyl

20. 4) If identical groups appear more than once, use prefixes: di for 2, tri for 3, tetra for 4, penta for 5, etc Examples: dimethyl, tripropyl, etc

21. C 2,2-dimethyl C 1 C 2 C 3 C 4 C 5 C 6 C C C 4-ethyl

22. 5) Name the sidechains or groups in alphabetical order, but ignore the prefixes when doing so ·Examples: ethyl comes before dimethyl, e < m

23. 6) Separate numbers with commas, use hyphens between words & numbers, and write the alkanes as one word ·Example: dimethylhexane

24. C C C C C C C C C C 4-ethyl-2,2-dimethylhexane

25. Name the organic compound on the board

26. Drill: Name CH 3 CH 2 H 3 C-CH-CH 2 -CH-CH-CH 3 CH 3 CH 2 CH 3

27. Student Practice Problems

28. H 3 C-CH 2 CH 2 -CH 2 -CH 3 CH 2 -CH-CH-CH 2 -CH-CH 2 -CH 3 CH 2 -CH 2 -CH 3 1)

29. H 3 C-CH 2 CH 2 -CH 2 -CH 3 CH 3 -CH-CH-CH 2 -CH-CH 2 -CH 3 CH 2 -CH 2 -CH 3 1)

30. H 3 C-CH 2 CH 2 -CH 2 -CH 3 CH 3 -CH-CH-CH 2 -CH-CH 2 -CH 3 CH 2 -CH 2 -CH 3 1)

31. H 3 C-CH 2 CH 2 -CH 2 -CH 3 CH 3 -CH-CH-CH 2 -CH-CH 2 -CH 3 CH 2 -CH 2 -CH 3 6-ethyl-3-methyl-4-propylnonane 1)

32. C C-C C-C-C C-C-C C C C C 2)

33. C C-C C-C-C C-C-C C C C C 2)

34. C C-C C-C-C C-C-C C C C C 2)

35. C C-C C-C-C C-C-C C C C C 3,4-diethyl- 2-methyloctane 2)

36. 3)

39. 3-ethyl-2,5,7-trimethyl-4,6-dipropyldecane 3)

40. Deriving Structures from Names Draw the main chain first –Look to the name ending Draw the branches –Look to the # & group name

41. Draw: 3,4-diethyl-2-methyloctane 2,3,5-trimethylhexane 5-butyl-3-ethyl-2,6,8- trimethyl-4-propyldecane

42. Draw: 5butyl-3-ethyl-2,6,8,9- tetramethyl-4,7- dipropyldecane

43. Drill: Name the following: C-C-C-C-C-C-C C-C-C C-C-C-C C-C-C

44. Draw the Following: 4,5-diethyl-3,4,5- trimethyloctane 3,3,4,4,5,5-hexaethylheptane

45. Isomers Compounds that have the same chemical formula, but different shapes

46. Types of Isomers Structural or skeletal Geometric or cis/trans Functional Positional Optical

47. Structural Isomers When there are differences in the carbon chains

48. Structural Isomers C-C-C-C-C C C-C-C-CC-C-C CC

49. Structural Isomers C-C-C-C-C C C-C-C-CC-C-C CC

50. Structural Isomers Pentane methyldimethyl butanepropane

51. Draw & name all the possible structural isomers for C 6 H 14

52. Draw & name all the possible structural isomers for C 8 H 18

53. Draw & name all the possible structural isomers for C 7 H 16

54. Drill: Draw & name all the possible structural isomers for C 6 H 14

55. This Week’s Schedule Lab Tomorrow Review Thursday Test Friday

56. Name: C-C-C C C-C-C-C-C-C-C C C-C

57. C-C-C C C-C-C-C-C-C-C C C-C

58. C-C-C C C-C-C-C-C-C-C C C-C

59. 3,5-diethyl-3,5- dimethyloctane

60. Draw the Following: 3,5-diethyl-2,4,6- trimethyloctane 5-butyl-3-ethyl-2,6,6,8- tetramethyl-4-propylnonane

61. Draw the condensed, complete, skeletal, & stick structures for: 3-ethyl-2,2- dimethylpentane

62. Draw & name all the possible structural isomers for C 9 H 20

63. Drill: Name & describe 5 organic prefixes & 4 organic suffixes

64. Test on Alkanes tomorrow

65. Review

66. Identify Organic terms Organic prefixes Organic suffixes

67. Organic Prefixes 1 =meth-6 = hex- 2 =eth-7 =hept- 3 =prop-8 =oct- 4 =but-9 =non- 5 =pent-10 =dec-

68. Name: H 3 C-CH-CH 2 -C-CH 2 -CH 3 CH 3 -CH 2 CH 3 CH 3 -CH 2

69. H 3 C-CH-CH 2 -C-CH 2 -CH 3 CH 3 -CH 2 CH 3 CH 3 -CH 2

70. H 3 C-CH-CH 2 -C-CH 2 -CH 3 CH 3 -CH 2 CH 3 CH 3 -CH 2

71. 3-ethyl-3,5-dimethylheptane H 3 C-CH-CH 2 -C-CH 2 -CH 3 CH 3 -CH 2 CH 3 CH 3 -CH 2

72. Name: C-C-C-C-C-C-C-C-C C-C C C CC

73. C-C-C-C-C-C-C-C-C C-C C C CC

74. C-C-C-C-C-C-C-C-C C-C C C CC

75. C-C-C-C-C-C-C-C-C C-C C C CC 6,7-diethyl-3,4,7-trimethyldecane

76. Name:

79. 5-ethyl-2,4,6,7- tetramethylnonane

80. Name:

83. 5-butyl-2,3,7,8-tetramethyl-6-propyldecane

84. Draw the complete structure of: 3-ethyl-2-methylpentane

85. Draw the condensed structure of: 3-ethyl-2,4,5-trimethylhexane

86. Draw a skeletal structure of: Octamethylhexane

87. Draw a stick structure of: 5-butyl-3-ethyl-2,4,6,8- tetramethyl-4-propyl decane

88. Draw & Name 10 isomers of: C 8 H 18

89. Draw an optical isomer of: C-C-C-C-C-C-C C C C