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Nuclear Chemistry “Bravo” Test 1954 – 15,000 kilotons
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Radioactivity and Nuclear Energy Objective: To learn the types of radioactive decay Objective: To learn to write nuclear equations that describes radioactive decay Objective: To learn how one element may be changed into another by particle bombardment
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What makes an atom radioactive? Radioactivity: the spontaneous decomposition of a nucleus to form another nucleus and produce one or more particles. -the neutrons act as glue holding the nucleus together -the heavier the atom, the more likely it is to be radioactive -if the number of protons in the nucleus exceeds 83, then the nuclide is radioactive
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Types of Radioactive Decay alpha production ( He): helium nucleus beta production ( e): gamma ray production ( ): alpha production ( He): helium nucleus beta production ( e): gamma ray production ( ):
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Specifying Isotopes 5 X A Z X = the symbol of the element A = mass number (protons + neutrons) Z = the atomic number (number of protons)
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Nuclear Symbols Element symbol Mass number, A (p + + n o ) Atomic number, Z (number of p + )
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Key to Understanding Nuclear Reactions In nuclear reactions, both the atomic number Z and the mass number A must be conserved
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Balancing Nuclear Equations 226 = 4 + ____ 222 88 = 2 + ___ 86 Atomic number 86 is radon, Rn Rn
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Alpha Decay Alpha production ( ): an alpha particle is a helium nucleus Alpha decay is limited to heavy, radioactive nuclei
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Alpha (α) Decay E1E1 P+N P P-2 + He 4 2 E2E2 P+N -4 an alpha particle (helium nucleus) is produced
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Alpha Radiation Limited to VERY large nucleii.
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Example of Alpha Decay Ra 222 88 86 + He 4 2 Rn Radium 222 decays by α particle production to Radon 218 218
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Beta Decay Beta production ( ): A beta particle is an electron ejected from the nucleus Beta emission converts a neutron to a proton
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Beta (β) Decay Beta emission converts a neutron to a proton E1E1 P+N P P+1 + e 0 E2E2 P+N
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Beta Radiation Converts a neutron into a proton.
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Example of Beta Decay Notice the mass of the beta particle is zero; it is so small that is must be neglected. C 14 6 7 + e 0 N 14
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Example of Beta Decay Th 234 90 91 + e 0 Pa 234 Thorium 234 decays by β particle production to Protactinium 234 (notice: no change in mass number A, and an increase of 1 in atomic number Z)
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Gamma Ray Production Gamma ray production ( ): Gamma rays are high energy photons produced in association with other forms of decay. Gamma rays are massless and do not, by themselves, change the nucleus
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Gamma Ray Production Gamma ray production ( ): Gamma rays are high energy photons produced in association with other forms of decay. Gamma rays are massless and do not, by themselves, change the nucleus
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Positron Production Positron emission: Positrons are the anti- particle of the electron Positron emission converts a proton to a neutron
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Positron Production E1E1 P+N P P-1 + e 0 1 E2E2 P+N Positron emission converts a proton to a neutron
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Electron Capture Electron capture: (inner-orbital electron is captured by the nucleus) Electron capture converts a proton to a neutron
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Types of Radiation
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Nuclear Stability Decay will occur in such a way as to return a nucleus to the band (line) of stability. The most stable nuclide is Iron-56 If Z > 83, the nuclide is radioactive
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A Decay Series A radioactive nucleus reaches a stable state by a series of steps Graphic – Wikimedia Commons User Tosaka
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