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Solubility Chapter 15.1 B
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Vocabulary Word Solubility: the maximum amount of solute that dissolves in a given amount of solvent at a specific temperature and pressure
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Solubility Every solute has a characteristic solubility
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Solvation Particles of solvent collide with particles of solute dissolving As more and more solute dissolves, some of the dissolved solute particles collide with the remaining crystalline solute crystallization
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Solvation As long as dissolving rate > crystallization rate more solute will continue to dissolve (unsaturated solution) Eventually dissolving rate = crystallization rate (dynamic equilibrium: saturated solution)
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Factors Affecting Solubility
Solubility is how much solute will dissolve (NOT how fast it dissolves) Temperature Pressure
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Temperature Effects Many substances are more soluble at higher temperature More sugar or salt will dissolve in hot liquid than in cold liquid
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Temperature Effects Gases are less soluble at higher temperatures
As the temperature increases the kinetic energy increases. This allows gas particles to escape to the atmosphere
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Temperature Effects
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Supersaturated Solutions
Since solubility of some solids increases with temperature: Allows the formation of supersaturated solutions Make a saturated solution at an elevated temperature Cool slowly
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Vocabulary Word Supersaturated solution: a solution that contains more dissolved solute than a saturated solution at the same temperature.
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Supersaturated Solutions
Are unstable Add a seed of solute crystallization
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Supersaturated Solutions
Are unstable Will crystallize on scratches of the container Will crystallize if tapped or stirred
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Examples of Supersaturated solutions
Cloud seeding: silver iodine is spread in the atmosphere to cause water particles in supersaturated air to condense and rain to fall
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Examples of Supersaturated solutions
Mineral springs have salt crystals along the edge
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Examples of Supersaturated solutions
Rock candy is made using a supersaturated solution of sugar water
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Pressure Effects on Solubility
Solubility of gaseous solutes increase with increasing pressure (the soft drink won’t go flat as quickly if the lid is kept on)
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Pressure Effects on Solubility
Soft drinks are carbonated at high pressure When the cap is unscrewed, gas escapes
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Spangler Video Clip supersaturated solutions:
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Vocabulary Word Henry’s law: the solubility of a gas in a liquid is proportional to the pressure of the gas above the liquid S1 = S2 solubility at pressure 1 P1 P2 solubility at pressure 2
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Henry’s Law Is used to determine the solubility at different pressures
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