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Naming and Formula Writing
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Chemical Formulas molecular: indicates the numbers of each atom in a compound C 6 H 12 O 6 notation with numbers & symbols to show composition of a compound
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empirical: gives simplest whole- number ratio of atoms of elements CH 2 O
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structural: indicates how the atoms are bonded to each other
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Molecules monatomic: single atoms of the same element Ex: He, Ne, Kr, Xe, Rn (noble gases) (the 1 subscript is understood) diatomic: two atoms of the same element Ex: H 2, O 2, N 2, Br 2 more than two atoms of the same element Ex: P 4 & S 8 two or more atoms of different elements Ex: H 2 O, NH 4, CO 2
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Charges on all the atoms that make up a compound must add up to zero
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Crisscross method for writing the formulas of binary ionic compounds the charge of each ion becomes the subscript for the other ion (without + / - signs) use simplest whole-number subscripts Ex: calcium bromide Ca +2 + Br -1 CaBr 2 *same with polyatomic ions, but put polyatomic ion in parentheses Ex: calcium hydroxide Ca +2 + OH -1 Ca(OH) 2
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Some ions can exist with different charges (Fe +2 or Fe +3 ) remember that charges must = zero look at name to figure out charge Ex: iron II chloride Fe? + Cl -1 FeCl 2
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Practice Strontium oxidecalcium sulfide Potassium carbonatelead (II) sulfate Magnesium sulfidecopper (I) chlorate Strontium nitrate dihydrogen monosulfide phosphorus pentachloridecalcium chloride Sodium sulfiderubidium sulfide Iron (III) chlorate
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Rules for Naming Compounds Basic Rule: 1)Name the first element in the compound 2)Name the second element by changing the ending of the name to –ide OR if the compound is made up of more than 2 elements, you have a polyatomic ion and you will use the polyatomic ion’s name with no changes
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Naming a Metal and a Nonmetal Basic rule—no changes Ex: NaClsodium chloride CaSO 4 calcium sulfate
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Naming Compounds with transition metals Basic rule with one change: –Find the charge of the transition metal (the charge of a transition metal can change) –Write the charge after the transition metal’s name (in Roman numerals) Ex Co I 2 cobalt (II) iodide Fe(ClO 3 ) 3 iron (III) chlorate
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Naming 2 nonmetals Basic rule with one change: –Look at the number of atoms for the second nonmetal and select the correct prefix to add to the name: PrefixMeaning mono- 1 di- 2 tri- 3 tetra- 4 penta- 5 hexa- 6
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2 nonmetals (continued): Ex CO carbon monoxide CO 2 carbon dioxide If the 1 st element in the compound has more than one atom, a prefix must be added to the first element’s name also 2 nd elment always gets a prefix, 1 st element only gets a prefix if more than one atom Ex P 2 S 3 diphosphorus trisulfide N 2 O 5 dinitrogen pentoxide Usually you won’t have 2 vowels together –Exceptions: di-, tri-, tetra-, & penta- iodide and oxide
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Practice CaSNiCl MgCl 2 SiCl 4 Zn(NO 3 ) 2 K 2 CO 3 Hg(C 2 H 3 O 2 ) 3 Li 2 SO 4 LiBrPCl 5 H 2 OPbSO 4 SrOCF 4 Ag(CrO 4 ) 2 CS 2
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