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LIPIDS Chapter 6
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Typical Fatty Acid Structure
H H H H H H H H H H H H H H H H H O H-C--C--C--C--C--C--C--C--C--C--C--C--C--C--C--C--C-C-OH H H H H H H H H H H H H H H H H H omega end alpha end (methyl group) (carboxyl group)
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Degrees of Saturation Saturated Unsaturated Monounsaturated
Polyunsaturated
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Saturated Fatty Acid Structure
H H H H H H H H H H H H H H H H H O H-C--C--C--C--C--C--C--C--C--C--C--C--C--C--C--C--C-C-OH H H H H H H H H H H H H H H H H H omega end alpha end All single bonds to hydrogen
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Monounsaturated Fatty Acid Structure
H H H H H H H H H H H H H H H O H-C--C--C--C--C--C--C--C--C=C--C--C--C--C--C--C--C--C-OH H H H H H H H H H H H H H H H H H omega end alpha end One double bond
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Polyunsaturated Fatty Acid Structure
H H H H H H H H H H H H H O H-C--C--C--C--C--C=C--C--C=C--C--C--C--C--C--C--C--C-OH H H H H H H H H H H H H H H H H H omega end alpha end > 2 double bonds
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Essential Fatty Acid Omega-3 (alpha-linolenic acid)
H H H H H H H H H H H H H H H H H O H-C--C--C=C--C--C =C--C--C=C--C--C--C--C--C--C--C--C-OH H H H H H H H H H H H omega end alpha end 1st double bond is located on the 3rd carbon from the omega end
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Essential Fatty Acid Omega-6 (alpha-linoleic acid)
H H H H H H H H H H H H H O H-C--C--C--C-- C--C =C--C--C=C--C--C--C--C--C--C--C--C-OH H H H H H H H H H H H H H H H H H omega end alpha end 1st double bond is located on the 6th carbon from the omega end
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Triglycerides + (Ester bond) H O H--C--O--C-- O H H H--C--OH O HO-C-R
R + H2O + R + H20 R + H20 (Ester bond) Glycerol FA’s Triglyceride + 3 H20
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Triglycerides + Fatty Acid esterification deesterfication H O H
H--C--O--C-- O H H H--C--OH Fatty Acid + Fatty Acid Fatty Acid esterification deesterfication
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Functions of Triglycerides
Provide energy Efficient storage of energy Insulation Protection Transport fat-soluble vitamins Satiety Flavor and texture
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Emulsification
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Cholesterol Content in Food
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Digestion of lipids
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Absorption of lipids
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Chylomicrons
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Transport of Lipids
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Transport of Lipids
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Transport of Lipids
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Atherosclerosis
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Cis and Trans Fatty Acid
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Hydrogenation Process
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Trans Fatty Acids in Foods
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