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Chapter 21 Neutralization Neutralization Reactions Salts in Solution
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Common Indicators IndicatorColor ChangepH Range Methyl RedRed - Yellow4.3 – 6.2 Phenol RedYellow - Red6.9 – 8.2 Alizarin YellowYellow - Pink10.0 – 12.0 PhenolpthaleinClear - Pink8.0 -10 Congo RedBlue - Red3.0 – 5.2 Bromothymol BlueYellow - Blue6.0 – 7.5
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Acid-Base Reactions Acid + Base Salt + Water Salt – Compounds made up of anions from an acid and cations from a base
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Neutralization Reaction Strong Acid + Strong Base Salt and Water The number of hydronium ions must equal the number of hydroxide ions A reaction of a weak acid and weak base do not usually produce neutral solutions
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Salts Ammonium Sulfate – Fertilizer Calcium Chloride – Road Salt Potassium Chloride – Sodium Free Salt Substitute Silver Nitrate - Cauterizing Agent Sodium Hydrogen Carbonate - Antacid
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Titration Process of adding a known amount of a solution of known concentration to determine the concentration of another solution End Point – the point where the indicator changes color
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Ch 21.2 Salts in Solution Salt Hydrolysis Buffers Common Ion Effect
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Salt Hydrolysis Reaction of a strong acid and a weak base or a strong base and a weak acid The salt may be acidic or basic, not neutral (strong acid – strong base reaction) CH 3 COO - (aq) + H 2 O (l) CH 3 COOH (aq) + OH - (aq) Hydrolysis – splits a hydrogen off a water molecule
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Summary Strong Acid + Strong Base Neutral Solution Strong Acid + Weak Base Acidic Solution Weak Acid + Strong Base Basic Solution
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Buffer The pH remains relatively constant with the addition of small amounts of acid or base Made up of a solution of a weak acid and its salt or a weak base and its salt
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Human Blood Two main buffers to keep pH 7.35-7.45 – Carbonic acid-hydrogen carbonate buffer system – Dihydrogen phosphate – monohydrogen phosphate buffer system
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Common Ion Effect The lowering of solubility of a substance by the addition of a common ion
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