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2/14/11 – “C” day Objective: To assess the concepts of ionic and covalent bonding. Do Now: What property of water is determined by its shape? How do water molecules behave?
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2/15/11 – “D” day Objective: Introduce the concept of chemical reactions. Do Now: Balance the following: P 4 + O 2 P 4 O 6 Today: 1.Check in HW 2.Check Answers 3.More Balancing Equations
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2/16/11 – “E” day Objective: To apply law of conservation of mass to chemical reactions. Do Now: What is the law of conservation of mass? Today: 1.Collect 11.1 Guided Read 2.Chemical Reaction Notes 3.Reaction in a Bag Lab
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Chemical reactions When one or more reactants are changed into one or more products, a chemical reaction has occurred. The atoms do not change, but are rearranged.
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Chemical reactions The changing of substances into other substances by the breaking of old bonds and the formation of new bonds
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Terms to remember The number in front of a substance is called the coefficient The coefficient multiplies everything in the substance
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Terms to remember Subscript – the number under an element – for example the 2 in O 2 The subscript tells how many of that type of atom is in a compound
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Practice How many of each type of atom are there in 2 Al2(SO4)3? 4 Al 6S 24 O
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Chemical reaction- example Adding HCl to Zn http://www.youtube.com/watch?v =HxiW2iPUZiw&feature=related http://www.youtube.com/watch?v =HxiW2iPUZiw&feature=related How many safety mistakes can you find?
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Mistakes Goggles? Gloves? – Really strong HCl Poor judgment – comment about holding balloon in teeth Fire/explosion
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Zn + HCl What happened? How can you tell that a chemical reaction occurred?
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Chemical reaction HCl + Zn → ZnCl2 + H2 The atoms in the products are the same atoms that were in the reactants, they are just arranged differently.
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Nomenclature HCl + Zn → ZnCl2 + H2 Reactants → Products Reactants react to produce products
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LAW OF CONSERVATION OF MATTER number and type number and type → READ as an = sign HCl + Zn → ZnCl 2 + H 2 Are there the same number of atoms of each type on each side of the → ?
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Balancing equations HCl + Zn → ZnCl 2 + H 2 Step 1: Count the number of each type of atom on each side H Cl Zn
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Balancing equations HCl + Zn → ZnCl2 + H2 Step 2: compare numbers, what needs to be changed to make them the same H1→2H1→2 Cl1 → 2 Zn 1 → 1
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Balancing equations 2HCl + Zn → ZnCl2 + H2 Step 3: compare numbers, is it balanced now? H2→2H2→2 Cl2 → 2 Zn1 → 1
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Chemical Reaction 2 H2 + O2 → H2O Is this balanced? How would you balance it?
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Chemical Reaction 2 2H2 + O2 → 2H2O
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Diatomic molecules 7 elements, most of which we will use all the time, exist in nature as diatomic molecules, which means they only exist as a molecule of 2 atoms bonded together
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Diatomic molecules H 2, N 2, O 2, F 2, Cl 2, Br 2 and I 2 Notice that all but H2 form a 7 on the periodic table. You need to know these.
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Practice balancing equations Worksheets
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Types of reactions Chemical reactions can be classified into 5 different types: Synthesis Decomposition Single replacement Double replacement Combustion
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Synthesis reactions Reactants: either 2 elements OR 2 compounds Product: MUST be a compound USUALLY combination is 2 reactants 1 product A + B → AB
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Synthesis reactions Examples N 2 + 3H 2 2NH 3 2H 2 + O 2 2H 2 O
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Decomposition The opposite of synthesis One reactant making 2 or more products AB → A + B 2 KClO 3 2KCl + 3O 2 2Ag 2 O 4Ag + O 2
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Single Replacement one atom takes the place of another atom in a compound A + BC B + AC A has replaced B in this reaction
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Single Replacement Examples 2NaCl + F 2 2NaF + Cl 2 Na + H 2 O NaOH + H 2 K + MgBr 2 KBr + Mg
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Double Replacement When (usually) ions in 2 compounds switch places to form 2 new compounds. AB + CD → AD + BC Remember, positive charge (metal) is always written first
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Examples CaCl 2 + Na 2 SO 4 → CaSO 4 + 2 NaCl FeCl 2 + K 2 S FeS + 2KCl
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Combustion Reactants: Carbon and Hydrogen containing compound reacting with oxygen Product: Carbon dioxide and water C x H y + O 2 CO 2 + H 2 O
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Combustion Examples CH 4 +3O 2 → CO 2 + 2 H 2 O C 3 H 8 + 5O 2 3CO 2 + 4H 2 O
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Types of reactions Demonstration Lab
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Types of reactions Types of chemical reactions IF WS
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Synthesis – Predicting products and balancing Two or more reactants one product Examples: Na + Cl 2 2Na + Cl 2 2NaCl
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Synthesis – Predicting products and balancing Rb + Cl 2 Rb + Cl 2 RbCl 2Rb + Cl 2 2RbCl K + Cl 2 K + Cl 2 KCl not balanced 2K + Cl 2 2KCl
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Decomposition one reactant two or more products Exact opposite of a synthesis reaction
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Decomposition Seltzer water (carbonic acid) decomposes to produce carbon dioxide and water: H 2 CO 3 CO 2 + H 2 O Decomposition: one reactant, two (or more products)
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Decomposition
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Often decomposition requires adding energy. If you add electricity to water, can make it decompose: H 2 O → H 2 + O 2 2H 2 O → 2H 2 + O 2
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Single replacement reactions A + BC → B +AC Two metals and one nonmetal OR AB + C →AC + B Two nonmetals and one metal
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Single replacement
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Single Replacement Examples of two metals and one nonmetal Al + CuCl 2 AlCl 3 + Cu Balance: 2Al + 3CuCl 2 2AlCl 3 + 3Cu
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Single Replacement Examples of two nonmetals and one metal Mg + HCl MgCl 2 + H 2 Balance Mg + 2HCl MgCl 2 + H 2
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Try these SR reactions Use the following steps: Identify which reactants are switching places Determine neutral ratio for new compound Draw reaction arrow and complete reaction 1.MgBr 2 and Cl 2 2. KI and F 2
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Answers 1. Magnesium Bromide and Chlorine MgBr 2 + Cl 2. Bromine and Chlorine ==> MgCl 2 + Br 2 2. Potassium Iodide and Fluorine 2KI + F 2 Iodine and Fluorine ==> 2KF + I 2
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Double Replacement AB + CD → AD + BC Involves the exchange of positive cations Gas, precipitate or water is produced
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DR - remember positive ions are always written first when listing the product METALS are positive ions and NON-METALS are negative ions a positive must join with a negative
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Double Replacement Double replacement reactions usually involve 2 solutions that when mixed give a precipitate (solid). Example: KBr + AgNO 3 KBr + AgNO 3 AgBr(s) + KNO 3 balanced Ppt formed
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Double replacement – acid and base A special kind of double replacement reaction is when an acid (H) is mixed with a base (OH). Example: HNO 3 + LiOH HNO 3 + LiOH LiNO 3 + H 2 O balanced Water formed
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Double Replacement How to predict products: ID cations Switch them! Write proper formulas Balance
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Putting it all together: Predicting Products and Balancing Determine the type of reaction: synthesis, decomposition, s/d replacement, or combustion Make sure elements present on left are present on right Make sure all charges are net zero Balance equation.
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Will the reaction occur? Will a metal replace another in a single replacement reaction? Table called an activity series ranks metals from most active to least active.
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Will the reaction occur? More active metals will form compounds. A + BC → B + AC Reaction occurs only if A is more reactive than B
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What do you notice about these metals? Why do you think jewelry is made using copper, silver, gold and platinum?
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Activity of metals lab
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Will the reaction occur? In double replacement reactions, the reaction will occur if one of the products forms a precipitate, a gas or water.
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