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CHAPTER 11 CHEMISTRY
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STOICHIOMETRY Review stoichiometry
CH4(g) + 2O2(g) --> 2H2O(g) + CO2(g) If you had 5.0 moles of oxygen how many moles would you get of carbon dioxide? If you had 85 g of methane how many moles of water would you form? For every 5.0 grams of water how many grams of carbon dioxide would you have? If you have 45 g of oxygen how many molecules of carbon dioxide would you form?
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LIMITING REACTANTS When one reactant has been completely used to form the product, and you still have some of the other reactant left over. 2Na(s) + 2H2O(l) ---> 2NaOH(aq) + H2(g) If 90.0 g of sodium is dropped into 80.0 g water, how many grams of H2 would be produced? What is the limiting reactant? How much of the other reactant was left over? 90.0gNa /2.0 g H2 / 46.0 g Na 3.90 g H2 80.0 gH2O / 2.0 g H2 / 36.0 g H2O 4.44 g H2 Sodium has to be the limiting reactant 90.0gNa / 36.0 g H2O = / 46.0g Na 70.4 so subtract = 9.6 g H2O left over
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PERCENT YIELD If you did an experiment where you start with 2.45 g Fe.
Fe(s) + CuSO4(aq) --> FeSO4(aq) + Cu(s) How much copper did you form if you got a 73.4% yield? Actual yield X 100 = % yield Theoretical yield 2.45 g Fe / 63.5 g Cu = / 55.8 g Fe 2.79 g Cu X X 100 = 73.4% X = 73.4/100 X 2.79 X = 2.05 g Cu
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MASS TO ENERGY Compare the heat of reaction for the displacement of g of sodium chloride from sodium bromide by chlorine Cl2(g) + 2 NaBr(aq) --> 2NaCl(aq) + Br2(l) ΔH = kJ Part of the product so you can use it in as a coefficient 0.0663g NaCl / 1 mol NaCl / kJ = / 58.5 g NaCl / 2 mol kJ
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