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Phase Changes and Thermochemistry
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Phase Changes Gas Solid Liquid Vaporization Deposition Sublimation
Condensation Freezing Liquid Solid Melting
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Endothermic: a process that absorbs heat.
Feels cold Melting Sublimation Vaporization Exothermic: a process that releases heat. Feels hot Freezing Deposition Condensation
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Energy Diagrams Endothermic Exothermic
Ea- Activation Energy: The energy required for a reaction to proceed.
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Catalyst Speeds up a reaction by lowering the activation energy.
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Molar Heats ∆Hvap – Molar Heat of Vaporization: The energy required to change 1 mol of substance from a liquid to a gas (or amount of heat that needs to be removed to change from a gas to a liquid) ∆Hfus – Molar Heat of Fusion: The energy required to change 1 mol of substance from a solid to a liquid (or amount of heat that needs to be removed to change from a liquid to a solid)
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Molar Heats of Water ∆Hvap(water)= 40.79 kJ/mol
∆Hfus(water)=6.009 kJ/mol If you have 32.0 grams of ice, how much heat would you need to change it to water? 32.0 g 1 mol kJ g mol = 10.7 kJ
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Molar Heats of Water How much energy would need to be released to condense g of steam to liquid water? 20.35 g mol kJ g 1 mol = kJ
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Molar Heats of Water If you wanted to release 52.8 kJ of energy, what mass of steam would you need to condense? 52.8 kJ 1 mol g kJ 1 mol = 23.3 g
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