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The Gas Laws A Tutorial on the Behavior of Gases.
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Kinetic Molecular Theory of Gases Gases consist of small particles that are in constant random motion and are separated by great distances from one another. The individual particles occupy a negligible volume.
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Collisions with walls of container are elastic and exert a measurable pressure. Particles do not interact with one another. Average kinetic energy is directly proportional to the Kelvin (absolute) temperature. Kinetic Molecular Theory of Gases
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P – Pressure V – Volume n – Moles R – Gas Constant T – Kelvin Temperature Abbreviations
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Units of Pressure atm - atmospheres mm Hg - millimeters of mercury torr – same as mm Hg Pa - Pascal kPa - kiloPascal
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1.00 atm = 760 mm Hg = 101.3 kPa = 101,300 Pa Converting Pressures
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Units of Temperature K - Kelvin °C - degrees Celsius °F - degrees Fahrenheit
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( C x 1.8) + 32 = F Converting Temperatures ( F - 32)/1.8 = C C + 273 = K
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Standard Conditions STP: Standard Temperature and Pressure Temperature: 273 K = 0.0 °C Pressure: 1.00 atm = 760 mm Hg
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Boyles Law
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Boyle’s Law: the volume of a fixed mass of gas varies inversely with the pressure at constant temperature. Mathematically, it is expressed as PV = k Where k is a constant, V is volume and P is pressure. Robert Boyle (1627-1691)
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A gas occupies 12.3 liters at a pressure of 400 mm Hg. What is the volume when the pressure is increased to 600 mm Hg and the temperature remains constant? Sample Boyle’s Law Problem P1V1 = P2V2 #1
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Answer #1
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Sample Boyle’s Law Problem P1V1 = P2V2 #2 A container has volume of 13,240 L has a pressure of 4.78 atm. If the pressure inside the container becomes 260 atm, what would the new volume be?
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A sample of neon occupies 105.0 L at a pressure of 190 kPa. At constant temperature, what is the volume of the neon when the pressure is increased to 631 kPa? Sample Boyle’s Law Problem P1V1 = P2V2 #3
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