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Chapter 10 – The Mole The most important concept in chemistry
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The mole The term ‘mole’ comes from the word ‘molecule’. The concept of the mole was created by Amadeo Avogadro.
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The mole Avogadro was trying to develop a system for counting atoms using the volume of gas. He calculated that there are 6.02 x 10 23 gas particles in a container that has a volume of 22.4 L
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The Mole The mole lets us perform calculations involving the mass of atoms or molecules, the # of particles, or the volume that the particles occupy.
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The Mole
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Molar Mass – The molar mass of a compound or diatomic molecule is calculate by adding all of the elements that make up the compound. – The molar mass of O 2 is (16.00 grams) x 2 = 32.oo grams / mole
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The Mole Calculate the molar mass of; – NaCl – Al 2 O 3 – Ca(C 2 H 3 O 2 ) 2
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The Mole Converting mass to moles – Use Dimensional Analysis – Use the molar mass as a conversion factor to cancel out grams and convert into moles. – Convert 10.0 grams of hydrogen gas into moles.
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The Mole Converting moles to mass; – Use the molar mass as a conversion factor to cancel out moles and convert into grams. – Convert 0.030 moles of LiF into grams.
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The Mole Using the mole to convert into # of particles; – Since 1 mole = 6.02 x 10 23 particles, we can use it as a conversion factor to cancel out units. – Convert 0.10 moles of iron atoms into number of atoms.
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The Mole Molar Volume Conversions – Avogadro calculated that the volume of 1 mole of gas particles would occupy a volume of 22.4L. That is, 1 mole of a gas = 22.4 L (@ STP)
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The Mole Calculate the volume of 0.85 moles of Argon gas.
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The Mole Calculate the mass of 3.0 L of carbon dioxide (@ STP).
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The Mole Mixed example problems; – Calculate the number of atoms in 0.45 moles of carbon. – Calculate the mass of 30.00 moles of methane (CH 4 ).
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The Mole Multistep mole conversion problems; – Calculate the volume of 10.0 grams of CO 2 at STP. – How many atoms would a 1.00 gram sample of tin contain.
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The Mole Empirical Formulas – – Chemical formula where the ratio of atoms are reduced. Molecular FormulaEmprical Formula H 2 O 2 (hydrogen peroxide)HO N 2 O 4 (dinitrogen tetroxide)NO 2 C 6 H 12 O 6 (glucose)CH 2 O
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The Mole Empirical Formulas – – The molar mass of the molecular formula will always be a whole number larger than the empirical formula. – But for some compounds, the empirical formula and molecular formula can be the same. H2O
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The Mole Empirical formula problems; – A compound is 79.85 % carbon and 20.18 % hydrogen by mass. Calculate the empirical formula and molecular formula of the compound. This compound has molar mass of 30.08 g / mol.
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The Mole A compound is 30.45 % nitrogen and 69.55 % oxygen by mass. Calculate the empirical and molecular formula of this compound. The compound has a molar mass of 138.03 g / mol.
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