2. Mitigating Insecticide Runoff from RIFA Treatments Kean S. Goh and Dave Kim Environmental Monitoring & Pest Management Department of Pesticide Regulation 830 K Street, Sacramento, CA 95814 kgoh@cdpr.ca.gov (916)324-4072

3. Environmental Hazards “This pesticide is extremely toxic to fish and aquatic invertebrates."

4. Outline Introduction Insecticide Characteristics Environmental Conditions Pesticide Management Practices Prevention and Mitigation Measures Summary

5. Introduction RIFA treatments - large geographic area Surface water runoff potential Historical monitoring data Aquatic toxicity Runoff prevention and mitigation

6. Sampling Plan Insecticide Concentration –Offsite movement Dissipation study –Turf, Soil, Water Assessing Mitigations

9. Arroyo Trabuco

10. Offsite Movements (Definitions) Spray drift – primary, secondary Runoff –dissolved in water –adsorbed to soil particles and organic materials

11. The Insecticides Bifenthrin (Talstar®) Chlorpyrifos (Dursban®, Lorsban®) Diazinon Fenoxycarb (Award®) Hydramethylnon (Amdro®) Pyriproxyfen (Distance®)

12. Insecticide Characteristics Vapor Pressure (mm Hg) Water Solubility (ppm, mg/L) Soil Adsorption Coefficient (Koc) Field Dissipation (t 1/2, days)

13. Physico-Chemical Properties

14. Water Solubility (ppm)

15. Soil Adsorption Coefficient (x 1000)

16. Field Dissipation Half-Life (Days )

26. Aquatic Toxicity (LC 50 )

27. Aquatic Toxicity 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 Bifenthrin Chlorpyrifos Diazinon Fenoxycarb Hydramethylnon Pyriproxyfen R. Trout D. magna

28. Climatic Conditions Rainfall –duration, amount, and intensity –timing of rainfall after application –time to runoff after inception of rainfall

29. Soil Characteristics Texture Organic matter content Moisture content Surface compaction and crusting Slope Aggregation

30. Pesticide Management Practices Pesticide placement –soil, foliar applied, potting mix Erosion/runoff control Cropping patterns Irrigation management –duration, amount, intensity, and timing

31. Runoff Prevention & Mitigation Runoff survey Insecticide selection Application Containment Water recovery Buffer strip

32. Runoff Site Survey Terrain, water flow, –proximity to water bodies Storage area Mixing & loading area Wash area Application site

34. Insecticide Selection Efficacy Formulation Physico-chemical properties Dose (use rate) Aquatic toxicity

35. Application Label –Environmental Hazards –Use Directions Rate Timing – rain & irrigation Precision application –Calibration

36. Label: Environmental Hazards This pesticide is extremely toxic to fish and aquatic invertebrates. Do not apply directly to water. Drift and run-off from treated areas may be hazardous to aquatic organisms in neighboring areas. Do not contaminate water when disposing of equipment washwaters.

37. Label Recommendation “Do not apply if rain is expected within 12 hours”

38. Containment Rain shelter Containment of spills –storage area, mixing loading, wash pad Containment of runoff water Rinsate reuse, treatment Tailwater pond/bioswale

39. Water Recovery Re-circulating system Tailwater recovery –phytotoxicity (herbicide residues) –microbial degradation, photodegradation –hydrolysis

40. Buffer Strip Water soluble vs. adsorped Buffer area Vegetation strip –grass, cover crop Organic material strip

41. Summary Do Precision Application Timing of application to prevent rain washoff Control timing and amount of watering to prevent runoff Containment of runoff water Recapture tailwater and reuse of water Use buffer strips

42. Acknowledgment Calif. Dept. of Food & Agric. –Center for Analytical Chemistry –Pest Detection/Emergency Projects State Water Resource Control Board Dept. of Health Services Calif. Department of Fish & Game Co. Agric. Commissioners