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Discuss Lab Questions M = mRT PV. Electronic Structure.

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Presentation on theme: "Discuss Lab Questions M = mRT PV. Electronic Structure."— Presentation transcript:

1 Discuss Lab Questions M = mRT PV

2 Electronic Structure

3 Electrons do not orbit nucleii, but move randomly in space around the nucleus.

4 Orbital The space in which the electrons (e - ) are likely to be found Max 2 e - per orbital

5 Electron Configuration A description of the electrons in an atom

6 Rule of Electron configuration Number: energy level (row #) Letter: energy sublevel (area) Superscript: # of e - in sublevel d electrons: 1 level < row # f electrons: 2 levels < row # Include all filled sublevels

7 Energy Levels Corresponds to row # 1 - 7 Related to size

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9 Energy Sublevels Corresponds to an area on the periodic table = nodes in orbitals s, p, d, f

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11 s - electrons Columns 1A & 2A Spherical orbitals

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13 p - electrons Col. 3A - 8A or 13 - 18 Dumbbell shaped orbital 3 orbitals per sublevel 1 node

14 d - electrons Cols 3B - 2B or 3 - 12 Transition area (2 nodes) Double dumbbell shaped 5 orbitals in sublevel

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16 f - electrons Lower removed area Triple dumbbell shaped 7 orbitals per sublevel 3 nodes

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18 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

19 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

20 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

21 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

22 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

23 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

24 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

25 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

26 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

27 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

28 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

29 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

30 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

31 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

32 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

33 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

34 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

35 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

36 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

37 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

38 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

39 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

40 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

41 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

42 5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -

43 Ground State All electrons are in their lowest possible energy state

44 Excited State One or more electrons are not in their lowest possible energy state

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46 Degenerate Orbitals Orbitals at the same energy level

47 Write The ECs for: F Rb Tc As

48 Write the ECs for: SnPt IMn +2

49 Chromium & Copper are Kinky

50 EC for Transition El. 4s 2 3d 1 4s 2 3d 6 4s 2 3d 2 4s 2 3d 7 4s 2 3d 3 4s 2 3d 8 4s 1 3d 5 4s 1 3d 10 4s 2 3d 5 4s 2 3d 10

51 All Transition elements have either 1 or 2 electrons in their outermost energy level

52 All inner-transition elements have two electrons in their outermost energy level

53 Write the ECs for: ZnAu Al +3 Fe +3

54 Valence Electrons Electrons in the outer most energy level Electrons involved in chemical reactions

55 Octet Rule 8 electrons in the outer level is stable elements attempt to get eight electrons in their outer level

56 Electron Dot Diagram Represents the valence electrons in an atom Maximum 4 pairs drawn on an imaginary square around the symbol

57 Chromium & Copper Are Kinky

58 Transition Dot Diagrams Kinky ones have a single All the rest have a pair

59 Inner Transition Dot Diagrams All have a pair

60 Wave Formula v or c =  f c = speed of light = wavelength or f = frequency

61 Calculate the wavelength of your favorite radio station FM in MHz AM in kHz

62 Plank’s Formula E = hf = hc/ E = energy h = Plank’s Constant

63 Calculate the energy of a photon from your favorite radio station:

64 Calculate the energy of uv light at 221 nm:

65 DeBroglie’s Formula = h/mv

66 Calculate the wavelength of a 221 g baseball thrown at 15 m/s:

67 Calculate the energy and mass of a photon of IR light at 1.326  m:

68 Spectrum The unique set of waves absorbed or emitted by a substance

69 Absorption Spectrum The unique set of wavelengths absorbed by a substance Atomic Absorption Sp

70 Emission Spectrum The unique set of wavelengths emitted by a substance Atomic Emission Sp

71 Atomic Absorption Spectrum Dark-line Spectrum

72 Atomic Emission Spectrum Bright-line Spectrum http://chemistry.bd.psu.edu/ jircitano/periodic4.html

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75 Spectroscopy The study of a substance under continuous excitation energy

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