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Discuss Lab Questions M = mRT PV
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Electronic Structure
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Electrons do not orbit nucleii, but move randomly in space around the nucleus.
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Orbital The space in which the electrons (e - ) are likely to be found Max 2 e - per orbital
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Electron Configuration A description of the electrons in an atom
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Rule of Electron configuration Number: energy level (row #) Letter: energy sublevel (area) Superscript: # of e - in sublevel d electrons: 1 level < row # f electrons: 2 levels < row # Include all filled sublevels
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Energy Levels Corresponds to row # 1 - 7 Related to size
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Energy Sublevels Corresponds to an area on the periodic table = nodes in orbitals s, p, d, f
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s - electrons Columns 1A & 2A Spherical orbitals
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p - electrons Col. 3A - 8A or 13 - 18 Dumbbell shaped orbital 3 orbitals per sublevel 1 node
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d - electrons Cols 3B - 2B or 3 - 12 Transition area (2 nodes) Double dumbbell shaped 5 orbitals in sublevel
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f - electrons Lower removed area Triple dumbbell shaped 7 orbitals per sublevel 3 nodes
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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5s - 4s - 3s - 2s - 1s - 5p - - - 4p - - - 3p - - - 2p - - - 4d - - - - - 3d - - - - -
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Ground State All electrons are in their lowest possible energy state
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Excited State One or more electrons are not in their lowest possible energy state
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Degenerate Orbitals Orbitals at the same energy level
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Write The ECs for: F Rb Tc As
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Write the ECs for: SnPt IMn +2
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Chromium & Copper are Kinky
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EC for Transition El. 4s 2 3d 1 4s 2 3d 6 4s 2 3d 2 4s 2 3d 7 4s 2 3d 3 4s 2 3d 8 4s 1 3d 5 4s 1 3d 10 4s 2 3d 5 4s 2 3d 10
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All Transition elements have either 1 or 2 electrons in their outermost energy level
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All inner-transition elements have two electrons in their outermost energy level
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Write the ECs for: ZnAu Al +3 Fe +3
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Valence Electrons Electrons in the outer most energy level Electrons involved in chemical reactions
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Octet Rule 8 electrons in the outer level is stable elements attempt to get eight electrons in their outer level
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Electron Dot Diagram Represents the valence electrons in an atom Maximum 4 pairs drawn on an imaginary square around the symbol
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Chromium & Copper Are Kinky
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Transition Dot Diagrams Kinky ones have a single All the rest have a pair
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Inner Transition Dot Diagrams All have a pair
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Wave Formula v or c = f c = speed of light = wavelength or f = frequency
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Calculate the wavelength of your favorite radio station FM in MHz AM in kHz
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Plank’s Formula E = hf = hc/ E = energy h = Plank’s Constant
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Calculate the energy of a photon from your favorite radio station:
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Calculate the energy of uv light at 221 nm:
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DeBroglie’s Formula = h/mv
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Calculate the wavelength of a 221 g baseball thrown at 15 m/s:
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Calculate the energy and mass of a photon of IR light at 1.326 m:
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Spectrum The unique set of waves absorbed or emitted by a substance
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Absorption Spectrum The unique set of wavelengths absorbed by a substance Atomic Absorption Sp
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Emission Spectrum The unique set of wavelengths emitted by a substance Atomic Emission Sp
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Atomic Absorption Spectrum Dark-line Spectrum
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Atomic Emission Spectrum Bright-line Spectrum http://chemistry.bd.psu.edu/ jircitano/periodic4.html
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Spectroscopy The study of a substance under continuous excitation energy
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