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Published byGrace Campbell Modified over 8 years ago
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Molybdenum Alloys In contrast to the other bcc refractory metals – molybdenum is a relatively abundant material in the Earth’s crust – and reasonable quantities of fine grained material can be prepared by consumable electrode melting – or by powder metallurgy followed by sintering.
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Molybdenum Alloys Mo and W form a continuous series of solid solutions and the resultant solution strengthening increases the degree of strain hardening that can be obtained by cold work Ti and Zr are added to form a fine dispersion of carbides in order to restrict the recrystallization of Mo – so that strain hardening can be retained to higher temperatures Mo-5Re and Mo-41Re alloys have been developed for improved high-temperature strength but such alloys are not regarded as cost effective at the present time – as Re is a relatively scarce and expensive metal
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Microstructure of Mo Alloys Fine grained structure of Mo prepared by powder metallurgy and sintering
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Effect of Temperature on UTS of Mo Alloys As the basis of dispersive strengthening is the retention of cold work – the advantages of dispersive phase alloying disappear above the recrystallization temperature of 1000-1300 o C – when pure Mo is just as strong Key 1 = TZM cold worked 2 = Pure Mo cold worked 3 = TZM recrystallized 4 = Pure Mo recrystallized
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