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Quiz 17 (3/26/14) 54 through 56. Provide the IUPAC name for each of the following structures: CH 3 54. CH 2 =CHCH 2 CHCH 2 CH 3 4-methyl-1-hexene 55. CH 2 CH 2 CH 3 4-propylcyclopentene 56. CH 3 CH 3 C = C cis-3,4-dimethyl-3-heptene CH 3 CH 2 CH 2 CH 2 CH 3 (Include cis/trans designation on #56)
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Quiz 18 (3/28/14) 57. Draw the structure of the product of the reaction: CH 3 CH=CH 2 + Cl 2 CH 3 CHClCH 2 Cl 58. Draw the structure of the product of the reaction: CH 3 -CH=CH-CH 3 + HBr CH 3 CH 2 CHBrCH 3 57. Draw the structure of the major product of the reaction: H 2 SO 4 CH 3 CH=CH 2 + H 2 OCH 3 CHOHCH 3 60.The hydrogenation of an alkene requires a catalyst. What is one of the metals that can be used as a catalyst in this type of reaction? Pt or Pd(Platinum or Palladium)
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Quiz 19 (3/31/14) 61. Draw the structure of: 1-bromo-2-ethylbenzene 62. Provide a correct name for this structure: 2-chlorophenol or 1-chloro-2-hydroxybenzene or o-chlorophenol 63. Which of the following represents m-xylene? A) B)C) D)
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Quiz 20 (4/2/14) 64. Classify the following alcohol as primary, secondary, or tertiary: 65. Provide the IUPAC name for the alcohol in question 64. 3-methyl-2-hexanol 66. Provide the IUPAC name for this molecule: 1,2-propanediol 67.What is the most important physical property of an alcohol? POLARITY! Secondary
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Quiz 21 (4/4/14) For problems 68 though 70, provide the correct structure of the product that is formed in each reaction: 68. 69. NO REACTION 70. [O] H 2 SO 4
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Quiz 22 (4/7/14) 71. Draw the structure of the major product when the alcohol: is dehydrated. 72. Name the following organic molecule: 73.Which of the following has the highest boiling point? A) Pentane (MW=72 amu) B) 1-butanol (MW = 74 amu) C) Diethyl ether (MW = 74 amu) Methyl propyl ether or Methoxy propane
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Quiz 23 (4/9/14) 74. Provide the IUPAC name for this molecule: 2-methoxypropane 74. Provide the IUPAC name for this molecule: Cl C CCCCC C 3-chloro-5-methylhexane 76. Is the molecule in question 75 considered to be primary, secondary, or tertiary?
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Quiz 24 (4/11/14) 77. An object or molecule that is not superimposable on its mirror image is said to be chiral. 78 and 79: A chiral center is any tetrahedral (geometric shape) carbon atom that is surrounded by four different groups. 80.How many chiral centers are in this molecule? ZERO – there are no tetrahedral carbons in benzene!
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