1. Environmental Sciences: Towards a Sustainable Future Chapter 17 Water: Pollution and Prevention

2. MISSISSIPPI WATERSHED Introduction:

3. Mississippi River The Mississippi river and its tributaries encompass 40% of the US land mass. Eventually delivers water to the Gulf of Mexico. As tributaries travel through agricultural land they carry fertilizer runoff to the Mississippi then to the Gulf.

4. Dead zone Nitrogen carried to the marine waters causes eutrophication. Eutrophication causes an area of depleted oxygen (dead zone) This was noticed by biologists in 1974 who thought it to be similar to the occurrence at Chesapeake Bay which has seasonal hypoxia (depleted oxygen/dead zone) but later became aware of the connection between nitrogen and the hypoxia.

5. Gulf Fisheries With the dead zone expanding, the Gulf fishing industry was eventually affected. $2.8 billion enterprise Gained national attention and eventually congress passed the Harmful Algal Bloom and Hypoxia Research and Control Act.

6. Two key strategies The two key strategies to mitigating the problem are: Reduce nitrogen loads to streams and rivers in the Mississippi basin by using less fertilizer and thereby reducing farm runoff. Restoring and promoting nitrogen retention and denitrification processes in the basin.

7. Dead zones around the world: Since 1960 the number of dead zones has doubled every decade. Worldwide, over 200 dead zones are now known according to the UN environment program.

8. Pollution EPA defines Pollution: “the presence of a substance in the environment that because of its chemical composition or quantity prevents the functioning of natural processes and produces undesirable environmental and health effects.”

9. How does it get there: Pollutants are almost always the byproducts of otherwise worthy activities… Planting crops, creating comfortable homes, providing energy and transportation, and manufacturing products.

10. Figure 17-2 page 439

11. Pollution Categories Air Particulates Acid-forming compounds Photochemical smog CO2 CFC’s

12. Pollution Categories Water and land Nutrient oversupply Solid wastes Toxic chemicals Pesticides/herbicides Nuclear waste

13. Controlling pollution The general strategies to making sure that pollution will not jeopardize current and future generations: Identify the pollutants Identify the source Clean up the environment already impacted Develop and implement pollution control Develop and implement alternative means of meeting the need that do not produce the pollution.

14. Point source pollution: Involves discharge of substances from factories, sewage systems, power plants, underground coal mines and oil wells. Relatively easy to identify. Easier to regulate.

15. Nonpoint source pollution Scattered over broad areas such as runoff, storm water drainage, atmospheric deposition. Harder to identify source Harder to regulate

16. Point and Nonpoint Sources of Pollution

17. Strategies to control water pollution: Reduce or remove the source Treat the water before it is released so as to remove pollutants or convert them to harmless forms. Water treatment is the best option for point source Source reduction can be employed for both point and non point and is the best option for non point.

18. Types of Water Pollutants Pathogens Organic Wastes Chemical Sediments Nutrients

19. Pathogens Disease-causing bacteria, viruses and other parasitic organisms (Table 17.1) Safety measures purification of public water supply sanitary collection/treatment of sewage sanitary practices when processing food

20. Modern medicine Beside modern medicine, the following have been important factors in controlling waterborne disease: Purification and disinfection of public water supplies Sanitary collection and treatment of human and animal wastes Maintenance of sanitary standards in all facilities in which food is processed or prepared Instruction in personal and domestic hygiene

21. Good health Good health is primarily a result of prevention of disease through public-health measures.

22. Millennium Development Goal Seven To cut in half the amount of people living without sustainable access to safe drinking water and basic sanitation by the year 2015.

23. Cholera Outbreaks Peru, 1990. Several thousand people died due to a cholera outbreak caused by unsanitary conditions. Sudan, 2006 Civil unrest lead to disruption of sanitation practices, several thousand sick, 500 dead from cholera.

24. DO Dissolved oxygen The amount of oxygen that water can hold in solution is very limited. In cold water dissolved oxygen can reach 10 ppm and even less in warm water.

25. Organic Wastes Dissolved oxygen (DO) in the water is depleted during decomposition of organic wastes. Water quality test. Biochemical oxygen demand (BOD): measure of the amount of organic material. As BOD increases, dissolved oxygen decreases. If the system goes anaerobic, only bacteria can live.

26. Chemical Pollutants Inorganic chemicals Heavy metals, acids, road salts Organic chemicals Petroleum, pesticides, detergents

27. Biomagnification Pollutants are concentrated as they pass up the food chain

28. Pollution: Sediments on Stream Ecology Loss of hiding-resting places for small fish. Attached aquatic organisms scoured from the rocks and sand. Poor light penetration

29. Nutrients and aquatic plants Nitrogen and phosphorus Fresh water affected more by phosphorus Salt water affected more by nitrogen Many of these nutrients are found in water only because of human activity.

30. NRWQC National Recommended Water Quality Criteria EPA lists 167 chemicals and substances as criteria pollutants. Identifies pollutants and then recommends concentrations for fresh, salt, and human consumption (fish and shel fish consumption).

31. Drinking water standards Drinking water standards are stricter. Drinking water standards and health advisory: set of tables updated periodically. Covering 94 contaminates Under authority of SWDA (safe water drinking act)

32. NPDES National pollution discharge elimination system Addresses point sources and issues permits that regulate discharges from waste water treatment plants and industrial sources.

33. TMDL Total maximum daily load Evaluates all sources of pollutants entering a body of water, espaecially non-point sources, according to the water’s ability to assimilate the pollutant.

34. WASTEWATER MANAGEMENT AND TREATMENT Lesson 17.2

35. History of waste removal Before late 1800’s: wastes were disposed of in the outdoor privy (or behind the nearest bush) Frequently contaminated drinking water. Late 1800’s excrements disposed of in the already existent storm water drains. Floods and over flow sent wastes floating in the streets. 1900 the first waste water treatment facilities were built. Gradually storm and waste water pipes were separated. Storm drains are not sewers

36. Sewers Most sewer bound materials are 99.9% water, 0.1% waste. The pollutants of waste water are divided into four categories: Debris and grit Rags, plastic bags, course sand and gravel Particulate organic matter Fecal matter, food wastes, toilet paper Colloidal and dissolved organic matter Bacteria, urine, soaps Dissolved inorganic matter. Nitrogen, phosphorus

37. Waste water treatment facility 1.Preliminary treatment screening of debris and settling of grit 2.Primary treatment Water moves slowly through tanks, organic matter settles and is removed (raw sludge). 3.Secondary treatment Live organisms break down organic matter to CO2, mineral nutrients, and water.

38. Activated sludge system: Oxygen is added to the secondary- treatment system through an air- bubbling system. A mixture of debris eating organisms (activated sludge) is added to the water and is vigorously aerated. Organisms reduce the biomass of the organic materials.

39. BNR Biological Nutrient Removal A secondary activated-sludge system added to remove nutrients and oxidize detritus. (added because of cultural- eutrophication). Because this water is actually purer than the body of water that it enters, it will dilute the pollutants in the body of water, improving the quality.

40. Raw Sludge Gray, foul smelling, syrupy liquid with a water content of 97%-98%. Pathogens are certain to be present. Biologically hazardous However, as a nutrient-rich organic material, it has the potential to be a good fertilizer if it is treated to kill pathogens. Anaerobic digestion Composting Pasteurization Unclear which will prove to be best and most cost effective

41. Anaerobic digestion Bacteria feed on detritus in the absence of oxygen. Sludge digesters turn the organic matter into CO 2, methane, and water. Biogas (2/3 methane gas product) The leftover 1/3 makes a good organic fertilizer.

42. Composting Used to treat sewage sludge. Raw sludge mixed with wood chips or some other water absorbing material. It is then placed in long rows (windrows)that allow air to circulate. A machine turns the material, bacteria and other decomposers break it down turning it into an excellent humus-like material.

43. Pasteurization Heated sufficiently to kill pathogens. The product, a dry odorless organic pellet. Used as organic fertilizer.

44. Alternative Treatment Systems Individual septic systems Wastewater effluent irrigation Reconstructed wetland systems Beaumont, TX The waterless toilet

45. Septic Tank Treatment Aerobic digestion of solids in septic tank. Flow of liquids into drain field for evaporation, infiltration, or irrigation.

46. Suggestions for maintenance 1. Use caution when disposing of materials down the drain. Can fill up or clog system. 2. Have system inspected regularly 3. Considering disabling garbage disposals 4. Keep heavy equipment off your field

47. EUTROPHICATION Lesson 17.3

48. What is eutrophication?

49. Aquatic Plant Life Benthic plants Emergent vegetation Submerged aquatic vegetation (SAV’s) Phytoplankton Green filamentous and single cell Bluegreen single cell Diatoms single cell

50. Nutrient Enrichment Oligotrophic: nutrient-poor water Eutrophic: nutrient-rich water What kind of plants would dominate in oligotrophic and eutrophic conditions?

51. Eutrophication As nutrients are added from pollution, an oligotrophic condition rapidly becomes eutrophic. Oligotrophic Eutrophic

52. Eutrophic or Oligotrophic? High dissolved O 2 Deep light penetration High phytoplankton

53. Eutrophic or Oligotrophic? Turbid waters High species diversity Good recreational qualities High detritus decomposition

54. Eutrophic or Oligotrophic? Low bacteria decomposition Benthic plants Warm water High nutrient concentration BOD High sediments

55. Natural Vs. Cultural Eutrophication Natural eutrophication aquatic succession occurs over several hundreds of years Cultural eutrophication driven by human activities occurs rapidly

56. Combating Eutrophication Attack the symptoms Chemical treatment Aeration Harvesting aquatic weeds Drawing water down

57. Combating Eutrophication Getting at root cause Controlling point sources Controlling nonpoint sources

58. Collecting Ponds

59. Biological Nutrient Removal Activated sludge: 3 zones Conversion of NH 4 to NO 3 NO 3 converted to N gas and released PO 4 taken up by bacteria and released with excess sludge

60. Biological Nutrient Removal