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Chemical Properties Determined by ▪ number of electrons ▪ positions of electrons
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Nuclear Properties Determined by ▪ Size of the nucleus ▪ Ratio between neutrons and protons
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Atomic Nuclei are either Stable ▪ Vast majority of atoms are stable Unstable ▪ Source of radiation ▪ Used in Nuclear Reactors ▪ Powers Nuclear Bombs
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Naturally Radioactive Nuclei Have an neutron/proton ratio that is abnormal Exist Outside Band of stability ▪ 1 neutron for every 1 proton (up to element 20) ▪ 1.5 neutrons for every 1 proton (elements from #20-#82) Have a very heavy nucleus ▪ All atoms with an atomic number past 82 are unstable
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Radioactive Isotopes Have unstable nuclei Exist outside the band of stability Emit several different types of radiation ▪ (to become stable nuclei)
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Emission of Radiation is one way for an unstable nucleus to become a stable one. Nuclear Radiation Is usually ▪ Alpha ▪ Beta ▪ Gamma
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Nuclear Radiation Alpha: He +2 charge: helium-4 nuclei, travel low speed, easily stopped Beta: e -1 charge: penetrate 100 times more than alpha Gamma: γ no charge, hi speed electromagnetic radiation of very short wavelengths, bursts of energy emitted from nucleus 4242 0 0000
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More Nuclear Radiation Positrons: e +1 charge: exact same properties as electron, with positive charge (form of anti-matter) Electron capture: e e- pulled into nucleus, causes p + to convert into n 0 Neutron bombardment: n 0 fired into nucleus, bumps p + out. (Used in nuclear reactors to start chain reaction) 0 +1 0
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All of these rxns began w/ an unstable nucleus which spontaneously emitted some form of radiation. Conversion of one element to another is called transmutation. It can also be induced by bombarding a stable nucleus with high energy , , or neutrons.
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Radioactive Decay Series: the series of nuclear reactions an unstable atom undergoes to become stable
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Starting atom: U-238 Ending atom: Pb-206 Why did we stop at Pb-206?
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Three most common series: U-238 Pb-206 U-235 Pb-207 Th-232 Pb-208 Why do they all stop at lead?
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Alpha emission: radium-226 decays emitting alpha particles Ra He + Rn 226 88 222 86 4242
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Alpha emission: Radon-222 decays emitting alpha particles Ra He + _______ 222 86 4242
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Beta emission: thorium-234 undergoes beta decay: Th e + Pa 234 90 234 91 0
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Beta emission: lead-214 undergoes beta decay: Pb e + __________ 214 82 0
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Gamma Radiation: No charge no particle change to nucleus no equation needed
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Positron emission: Phosphorus-32 emits a positron P e + + ________ 32 15 0 +1
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Neutron Bombardment: Nitrogen-14 is bombarded with neutrons N + n 0 p + + ________ 14 7 1010 1111
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1. alpha decay of Uranium-238 2. alpha decay of Barium-139 3. beta decay of Radon-222 4. beta decay of carbon-11
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5. Oxygen-15 undergoing positron emission 6. neutron bombardment of U-235
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The time it takes for half of a radioactive substance to decay Example: The half-life of strontium-90 is 28 years. If you started with 10 g of Sr-90, how much remains after 28 years? 56 years? 84 years? 112 years?
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http://phet.colorado.edu/sims/nuclear- physics/alpha-decay_en.jnlp http://phet.colorado.edu/sims/nuclear- physics/alpha-decay_en.jnlp
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Radium’s half-life = 1620 yrs. Starting with 40g of Ra, how much remains in 1620 yrs? 3240 yrs? 4860 yrs?
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The half-life of I-131 is 8 days. If only 1/8 th the original amt of this isotope of I remains, how old is the I-131 ?
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After 3 years only 1/64 th of the original mass of an element remained. What was its half life?
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Carbon in living organisms is a constant ratio of C-14 (radioactive) to C-12 (stable). When organism dies (stops breathing in C-14 from atmosphere), no fresh C-14 replaces the C-14 decaying in its tissues. C-14 has a half life of 5700 years.
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C-14 dating CANNOT be used to date objects that are more than about 50,000 yrs old. 1. after 8 half-lives the radioactivity is too low to be measured accurately (1/2) 8 = 1/256 th 2. can’t be sure that the ratio of C-14 to C-12 was the same long ago as it is now (depends on solar activity & ocean pH)
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An ancient wooden dish is found to contain 25 % of the amt of C-14 that is in a living tree. About how old is this dish? A museum mummy contains 1/8 th of the amt of C- 14 as a living Egyptian. How old is the mummy?
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