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PHYSICAL PROPERTIES OF MATTER Phases of Matter
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A. Phases of matter = solids (s), liquids (l), gas (g) B. Phase depends on: 1. Temperature 2. Pressure (force)
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C.A change in phase is accompanied by: * an absorption of energy = ENDOTHERMIC OR * a release of energy = EXOTHERMIC
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D. The phase is characterized by: * The type of motion of the particles * The distance between the particles
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3 Types of Motion include: 1. vibrational – back and forth motion 2. rotational – spin on axis 3. translational – moves from one positon to another; travels over a distance
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Properties of Solids, Liquids, & Gases 1.SOLIDS:* Particles are aligned in a geometric pattern * Particles are in a fixed position * Small distance or space between particles * Vibrational movement ONLY * Solids have definite shape & volume
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2.LIQUIDS: * some space between particles * Particles are NOT aligned in a fixed position * motion = vibrational & rotational particles FLOW or roll over * HAS definite volume * NO definite shape
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3. GASES: * Large distance between particles Particles are spaced far apart! * contain all 3 types of motion: Vibrational, Rotational, & Translational * NO definite shape * NO definite volume
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ENTROPY= THE DEGREE OF RANDOMNESS OR DISORDER As energy is absorbed (ENDOTHERMIC) solids liquids gases Entropy INCREASES
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As Energy is released (EXOTHERMIC): GAS LIQUID SOLID Entropy DECREASES
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PHASE CHANGE DIAGRAM A graph that plots temperature vs. heat at constant rate. Heat can be added (Endothermic or Heating Curve) OR Heat can be released (Exothermic or Cooling Curve)
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HEATING CURVE – ENDOTHERMIC ENTROPY INCREASES
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COOLING CURVE – EXOTHERMIC ENTROPY DECREASES
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Terms to know: 1.Endothermic = heat is absorbed * Entropy increases * melting = s l * vaporization = l g * sublimation = s g * Heat of Fusion = heat needed to melt ice (s l) * Heat of Vaporization = heat needed to vaporize water to steam ( l g)
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Endothermic Phase Changes: ICE to WATER to STEAM Entropy INCREASES
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2. Exothermic = Heat is released * Entropy Decreases * Freezing: l s (solidification) * Condensation: g l * Heat of solidification = amount of heat needed to be released to change a liquid to a solid * Heat of condensation = amount of heat needed to be released to change a gas to a liquid
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Mathematical Equations: Q = m x Hf use when melting or freezing Q = m x Hv use when vaporizing or condensing REFERENCE TABLE B: Heat of Vaporization = 2260 J/g Heat of Fusion = 334 J/g
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