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Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions.

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Presentation on theme: "Crystal Field Theory Molecular Orbital Theory: Donor- Acceptor Interactions."— Presentation transcript:

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5 Crystal Field Theory

6 Molecular Orbital Theory: Donor- Acceptor Interactions

7 Molecular Orbital Theory: Full ML 6

8 Molecular Orbital Theory: Simplified

9 Counting d-electron Configurations

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12 How do we predict/explain transition metal structures?

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17 Colors and Spectroscopy of Transition Metal Complexes

18 Sigma Interaction Strength Spectrochemical Series: I - < Br - < Cl -, F - < OH - < OH 2 < NH 3 < en < CN - < CO

19 Pi Donor Ligands: Mainly oxides and halides

20 Mn 2+ (aq) MnO 4 -

21 Pi Acceptor Ligands: CO, CN -, pyridine

22 Pi Acceptor Ligands and spectroscopy: CO, CN -, pyridine

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