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Published byOphelia Hicks Modified over 8 years ago
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When elements are arranged in order of increasing atomic #, elements with similar properties appear at regular intervals.
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B.Coulomb’s Law Coulomb’s Law lets us calculate the FORCE between two ELECTRIC CHARGES.
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An electron is attracted to the nucleus because of the positively charged center. The closer the electron is to the nucleus, the more positive charge it feels. The Shielding Principle- electrons on the interior “full” orbitals shield the outer electrons from the nucleus. They hide the positive charge from the outer electrons
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As you add protons, you add positive charge. If you increase the positive charge, you increase the force You also increase the distance which reduces the force
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1. Effective Nuclear charge justifies trends across a period 2. Increased distance justifies trends down a group
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Atomic Radius size of atom © 1998 LOGAL
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Atomic Radius Li Ar Ne K Na
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Atomic Radius yIncreases to the LEFT and DOWN
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Why larger going down? Higher energy levels have larger orbitals Shielding - core e - block the attraction between the nucleus and the valence e - Why smaller to the right? Increased effective nuclear charge without additional shielding pulls e - in tighter
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z First Ionization Energy Energy required to remove one e - from a neutral atom. © 1998 LOGAL
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First Ionization Energy K Na Li Ar Ne He
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First Ionization Energy yIncreases UP and to the RIGHT
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Why opposite of atomic radius? In small atoms, e - are close to the nucleus where the attraction is stronger Why small jumps within each group? Stable e - configurations don’t want to lose e -
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Successive Ionization Energies yMg1st I.E.736 kJ 2nd I.E.1,445 kJ Core e - 3rd I.E.7,730 kJ yLarge jump in I.E. occurs when a CORE e - is removed.
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yAl1st I.E.577 kJ 2nd I.E.1,815 kJ 3rd I.E.2,740 kJ Core e - 4th I.E.11,600 kJ Successive Ionization Energies yLarge jump in I.E. occurs when a CORE e - is removed.
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Melting/Boiling Point yHighest in the middle of a period.
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Ionic Radius yCations (+) xlose e - xsmaller © 2002 Prentice-Hall, Inc. yAnions (–) xgain e - xlarger
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Attraction an atom has for a shared pair of electrons. higher e - neg atom - lower e - neg atom +
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Increases up and to the right.
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Which atom has the larger radius? yBeorBa yCaorBr Ba Ca
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Which atom has the higher 1st I.E.? yNorBi yBaorNe N Ne
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Which atom has the higher melting/boiling point? yLiorC yCrorKr C Cr
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Which particle has the larger radius? ySorS 2- yAlorAl 3+ S 2- Al
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