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Published byKaren Cecilia Anderson Modified over 9 years ago
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Section 5.4 pg. 215-219
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Standard Solution – solutions with precisely known concentrations Used in chemical analysis and to precisely control chemical reactions Precision equipment is required to measure mass of solute (electronic balances) and volume of solution (volumetric flask)
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Volumetric Flask – glass flask with a long, narrow neck used to prepare a highly precise volume of solution Precise to ±0.16 mL at 20°C (i.e. 100.0 mL volumetric flask is uncertain to less than 0.2 mL ) Graduated Cylinders – glass cylinder with regular markings used to measure a fairly precise volume of liquid or solution Erlenmeyer Flask – glass cone-shaped flask with a large flat bottom used to mix a solution sample during titration; markings only approximate volume Beaker – glass wide-body cylinder with regular markings used for transferring and storing solutions or solids, and containing reactions; markings are only approximate volumes precise to only ±5 mL
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Use conversion factors to determine the values for both the amount in moles and the mass of solid required. Because you are working with one substance, you do not need a balanced equation (No need for a mol ratio) Volume of the solution and its molar concentration are needed. Example: To prepare 250.0mL of 0.100 mol/L solution of sodium carbonate, the mass needed is: 0.2500 L x 0.100 mol x 105.99 g = 2.65 g 1 L 1 mol
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Pg. 216 #1, 2, and 4(a)
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Standard solutions – a solution with a concentration that is known with considerable certainty; a solution of accurate concentration Read over your procedure given Nelson Master 30
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Dilution – decreasing the concentration of a solution Usually accomplished by adding more solvent The number of moles of solute DOES NOT change when a solution is diluted (# of moles before = # of moles after) Dilution is especially important in manipulating the concentration of solutions in chemistry for better control of reactions Concentrated solution reactions can be too violent to be safe and/or too fast to observe Stock Solution – the initial starting solution from which samples are taken for a dilution; usually very high concentrations
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More Volumetric Glassware : Pipet – glass tube used to deliver very precise, small volumes of solution; requires a pipet bulb to fill the pipet Two Types: a)Graduated Pipet – graduation marks every 1% of the volume (i.e. 10 ml would be marked every 0.1 mL) -Can transfer any volume from 1 – 100% -Precise to ±0.1 mL b)Volumetric Pipet – bulge in the middle with one graduation marking -“TD” inscription means “to deliver” a certain volume -Transfers one specific volume (1 mL, 10 mL); precise ±0.02 mL ( most precise piece of glassware)
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We know that the number of moles does not change when diluting a solution, but the concentration and volume will. So we will use the dilution formula: C 1 V 1 = C 2 V 2 To use the dilution formula, you must make sure the units are consistent for both the c and v (i.e. both in mL or both in L) Example: How would you prepare 100 mL of 0.40 mol/L MgSO 4(aq) from a solution of 2.0 mol/l MgSO 4(aq) C 1 V 1 = C 2 V 2 (2.0mol/L) (V 1 ) = (0.40mol/L) (100mL) V 1 = 20 mL
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Pg. 218 6-8
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Standard solutions – a solution with a concentration that is known with considerable certainty; a solution of accurate concentration Read over your procedure Nelson Master 30 Practice PipettingPipetting
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