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applications of chemical equilibria
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living systems
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when the pressure of oxygen gas increases the equilibrium shifts to the right; when the acidity increases or the pressure of oxygen gas decreases the equilibrium shifts to the left.
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living systems The protons aid the freeing of oxygen molecules adsorbed on haemin-groups. In lungs the reverse process takes place. As a result of the high partial pressure of oxygen gas, the proton is released from the haemoglobin. This shifts the dissociation of H 2 CO 3 to the left releasing CO 2.
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living systems Carbon monoxide (CO) can adsorb on haemoglobin molecules even better than O 2.
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living systems
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industrial applications
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the synthesis gases enter the vessel, whereupon the pressure increases the gases are heated (T increases) N 2 and H 2 are passed over a catalyst bed the partial conversion of N 2 and H 2 to NH 3 takes place the liberated heat is removed (T and p decrease) the reaction mixture is further cooled to condense the ammonia (T and p decrease further) the ammonia is removed pressure is exerted on the non-reacted N 2 and H 2 and these gases are further used in the production of ammonia.
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industrial applications
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water purification
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Chlorine gas is normally poorly soluble in water, but it does more than just dissolve as it reacts extremely rapidly with water. This reaction, actually an auto-oxidation reaction, is an equilibrium reaction.
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cave equilibria
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Rain-water contains some H 2 CO 3 in addition to other acids. Above-ground and underground the seeping water becomes more and more enriched with CO 2, particularly when passing through humus-rich soils. This increases the partial pressure of CO 2 in the water.
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cave equilibria
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kitchen equilibria
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