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Energy and Nanotechnology Part Deux
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Importance of Energy Storage Solar PVs are great! But what about at night? Power mobile devices / cars Lighter, more efficient –Batteries –Supercapacitors Energy Usage –LEDs –Thermal Insulation –Lightweight Materials
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Energy Storage Needs Energy (J) Power (W =J/s)
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Batteries Chemical energy -> electrical energy http://www.qrg.northwestern.edu/pr ojects/vss/docs/power/2-how-do- batteries-work.html http://www.hk-phy.org/energy/commercial/cell_is01_e.html
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Li-Ion Batteries Li + has high energy density Rechargeable Safety concerns
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Nano LIBs Silicon can replace graphite as electrode Nano-structuring allows for expansion http://www.kurzweilai.net/new-paper-like-material-for-lithium-ion-batteries-could-boost-electric-vehicle-range
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Liquid Metal Battery Different metal densities separate easily http://phys.org/news/2013-11-ambri-liquid-metal-battery-prototype.html
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Flow Batteries Separate power and energy Easy to recharge Safe Complicated Consumes energy
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Nano-Flow Battery Nanoparticles of Li-Battery Material nanoFlowcell – Q-eSportslimousine http://www.technologyreview.com/article/425107/go-with-the-flow/ http://www.anl.gov/sites/anl.gov/files/es_nanoelectrofuels-broch-genl.pdf
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Supercapacitors
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Capacitor/Graphene Capacitor Capacitor -> dielectric Supercapcitor -> Helmholtz Double layer
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Energy Efficiency Lighting Thermal Energy Automotive/Aerospace
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LED Like a photovoltaic but in reverse More efficient than incandescent bulb Needs to be energy efficient to make
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LED displays
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Physics Nobel Prize IR LEDs – GaAs 1960s Visible LEDs – doped GaP 1960s Blue LEDs – GaN 1980s – 1990s – MOVPD – Doping – Activate dopants http://www.nobelprize.org/nobel_prizes /physics/laureates/2014/advanced- physicsprize2014.pdf
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QD LEDs Made possible by efficient blue LED Tune color better than traditional materials More efficient http://www.nanosysinc.com/what-we- do/quantum-dots/
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Applications Displays – QD Vision – Nanosys Lighting – Pacific Light Technologies
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Organic LEDs Polymer or small molecule Solution processable Expensive to make http://education.mrsec.wisc.edu/background/LED/
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Escaping Light http://www.princeton.edu/main/news/archive/S41/14/79S63/index.xml?section=top stories Plasmonic cavity with subwavelength hole-array Made using nanoimprint lithography
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Thermal Energy Thermal management – High thermal conductivity – CarbAl Insulation – Low thermal conductivity – Aerogels
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Lighter/Stronger Materials Nanostructured bulk materials Polymer nanocomposites Carbon nanotechnology Polymer Journal (2012) 44, 334–339 http://www.azonano.com/article.aspx?ArticleID=3103
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