1. Drill: Name the following + 2 isomers FF OH

2. Name: SH I F O H

3. Addition Reactions

4. Reactions in which more atoms are added to an alkene or alkyne

5. Halogenation Reactions in which halogens are added to an alkene or alkyne

6. Halogens Elements from column 7A or column 17 F, Cl, Br, & I

7. Halogenation C=C + X-Y -C-C- X Y

8. Halogenation C=C + IBr H-C-C-H I Br H H H H H

9. Predict Product C=C + ICl H H CH 3 H

10. Drill: Draw the reactants, then predict, draw, & name the products when Cl 2 is added to trans-2-pentene:

11. CH 3 CH CH 2 CH 3 Cl

12. CH 3 CH CH 2 CH 3 Cl

13. CH 3 CH CH 2 CH 3 Cl

14. CH 3 CH CH 2 CH 3 Cl Pentyl-2,3-dichloride

15. Hydrohalogenation Reactions in which hydrogenhalides are added to an alkene or alkyne

16. Hydrohalogenation C=C + H-X -C-C- H X

17. Hydrohalogenation C=C + HCl  H-C-C-H H Cl H H H H H

18. Markovnikov’s Rule The major products get the “H” on the atom in the DB that already has more “Hs”

19. Predict & Name Products when HF is added to:

20. Halogen Rxns: Predict the products for each of the examples: 2-methyl-2-butene + HI Propene + HF

21. Organic HW Draw the reactant, then predict & name the major & minor products when HCl is added to 1- pentene.

22. Drill: Draw the reactant, then predict & name their products when excess HCl is added to 1-pentyne

23. Hydration An addition reaction where water is added to an alkene or alkyne

24. Hydration C=C + H 2 O C-C HOH H+H+

25. Predict & Name Reactants & Products C=CC=C H H H H + H 2 O HOCl Heat

26. Ethanol C H OH H H H

27. Predict & Name Reactants & Products C=CC=C CH 3 H H H + H 2 O acid heat

28. C H OH Major Product CH 3 H H C H CH 3 H HO H Minor Product

29. Hydrogenation An addition reaction where hydrogen is added to an alkene or alkyne

30. Hydrogenation C=C + H 2 H-C-C-H H H H H H cat

31. Predict the Product + H-H Pd

32. Name:

33. Organic HW Draw the reactant, then predict & name the major & minor products when HOH in acid is added to 1-pentene.

34. Drill: Draw the organic reactants, & draw & name the major products when 3 equivalences of HF is added to penta-1-ene-3-yne

35. Collect HW

36. Substitution Reactions Reactions that look as if they should be addition, but substitution occurs instead.

37. Substitution Rxns Reactions in which a halogen replaces a hydrogen on an arene (benzene ring)

38. H X-X cat

39. X + HX

40. H Br-Br cat

41. Br + HBr

42. Hydrocarbon polymerization is the foundation of the plastics industry.

43. Monomer Molecules that can combine in repeating units creating a polymer

44. Polymer Large molecules made up of repeating units of single molecules

45. Naming Polymers The polymer is named after the monomer from which it’s made: polymonomer

46. Polymerization The act of making polymers out of monomers

47. Polymerization Reactions

48. C C C C C C Catalyst is added to start rxn, DB breaks & connects to nearest C & the process continues

49. C C C C C C or (-C C-) n

50. Typical Monomers Single molecules in which repeating units make up molecules or polymers

51. Ethene (Ethylene) C=CC=C H H H H

52. Polyethylene (-CH 2 -CH 2 -) n

53. Propene (Propylene) C=CC=C H H H CH 3

54. Polypropylene CH 3 (-CH 2 -CH-) n

55. Chloroethene or Vinyl chloride C=CC=C H H H Cl

56. Polyvinyl chloride (PVC) Cl (-CH 2 -CH-) n

57. Tetrafluoroethene C=CC=C F F F F

58. Teflon (-CF 2 -CF 2 -) n

59. Isoprene C=CC=C C=CC=C CH 3 H H H H H

60. Polymers of rubber (-H 2 C-C CH-CH 2 -) n CH 3

61. Isoprenes

63. Rubber Polymer

64. Styrene C=C H HH

65. Polystyrene (CH-CH 2 -) n

66. + +

69. + + Predict & Name the Product

70. Polycyclopropylethylene