1. Chapter 1- CHEN 313: Chemical Engineering Materials Course Objective... Introduce fundamental concepts in Chem. Eng. Materials You will learn about: material structure how structure dictates properties how processing can change structure This course will help you to: use materials properly realize new design opportunities with materials a

2. Chapter 1- Lecturer: Dr. Perla B. Balbuena Time: MWF 1:50-2:40 pm Location: CHEN 102 Activities: Present new material Announce reading and homework Take exams* *Make-ups given only for emergencies. *Discuss potential conflicts beforehand. b LECTURES

3. Chapter 1- Teaching Assistant will grade your homework Name Diego Cristancho Office ____ JEB Tel. X-XXXX E-mail Diego.cristancho@chemail.tamu.edu d TEACHING ASSISTANTS

4. Chapter 1- Activities: Discuss homework, exams Discuss lectures, book After class each Wednesday** **Contact Dr Balbuena by e-mail for other times e OFFICE HOURS

5. Chapter 1- other books Required text: Fundamentals of Materials Science and Engineering: An Integrated Approach 2 nd Edition W.D. Callister, Jr., John Wiley and Sons, Inc. (2005). Both book and accompanying CD-ROM are useful. Other Materials: papers f COURSE MATERIAL

6. Chapter 1- Midterm # 1 16.67 % Midterm #2 16.67% Tentatively scheduled for: 3/19, 7-9 pm Midterm #3 16.67% Tentatively scheduled for: 4/16, 7-9 pm Final 25% Scheduled for: 5/8, 3:30-5:30 pm g GRADING Tentatively scheduled for:2/12, 7-9 pm Homework, class participation: 10% Projects 15 %

7. Chapter 1- KEEP TO THE READING /HOMEWORK CYCLE MONTUE class WEDTHUFRI Hmk is assigned Hmk is due h THE WEEKLY “CYCLE” class

8. Chapter 1- Materials are... engineered structures...not blackboxes! Structure...has many dimensions... Structural featureDimension (m) atomic bonding missing/extra atoms crystals (ordered atoms) second phase particles crystal texturing < 10 -10 10 -10 10 -8 -10 10 -8 -10 -4 > 10 -6 1 CHAPTER 1: MATERIALS SCIENCE & ENGINEERING

9. Chapter 1- Introduction Materials Science. Investigation of the relationships between the structures and properties of materials –How do the arrangement of a materials components (e.g. atoms, etc.) influence its properties (e.g. does it conduct electrons or not)? Materials Engineering. Designing the structure of a material so that it has desired properties. The design is based on the structure-property relationships derived by the Materials Scientist

10. Chapter 1- Introduction Another view of this course: –Macroscopic versus microscopic Engineers typically are interested in macroscopic properties (e.g. heat capacities, viscosity, fracture strength, etc.) Scientists often describe things in microscopic terms (e.g. bond strength, orbital theory, etc.) However, recent trends tend to mix both approaches: Engineers and Scientists both look at micro and macroscopic properties and try to understand the connection between them –In this class I am going to, whenever possible, show the interrelationship between microscopic and macroscopic properties

11. Chapter 1- Introduction Processing/Structure/Properties/Performance –They are interrelated! ProcessingStructureProperties Performance Figure 1.1 As engineers you are probably more tuned into processing and performance However, how processing influences the structure is critical Why? This will influence the material properties, which of course affect its performance!

12. Chapter 1- Introduction What do I mean by structure? –Structure is related to the arrangement of a material’s components This could be on any length scale Atomic, nano-, micro-, macro- –All of these length scales matter! Types of Carbon (just plain old carbon!) Diamond GraphiteC 60 - FullereneCarbon nanotubes

13. Chapter 1- Introduction Properties –How the material behaves in terms of the kind and magnitude of response to an imposed stimulus –What are the stimuli? Temperature Magnetic field Electric field –Important point: material properties are typically defined independent of material shape and size! Why? –However… what about nanosize objects?

14. Chapter 1- Introduction Properties –For the purposes of this course we will group properties into six categories Mechanical Electrical Thermal Magnetic Optical Deteriorative

15. Chapter 1- Introduction PropertyExample (Physics)Example Properties MechanicalRate of material deformation to an applied load Elastic modulus ElectricalResponse of material to an applied electrical field Electrical conductivity ThermalMaterial expansion/contraction with change in temperature Heat capacity, thermal conductivity MagneticResponse of a material to an applied magnetic field Magnetic susceptibility OpticalResponse of material to electromagnetic radiation Refractive index DeteriorativeRate of decomposition of material (often in presence of acid, etc.) Corrosion rate

16. Chapter 1- Introduction Processing  Structure   Properties Same material – aluminum oxide. Depending on structure (which is influenced by processing) materials are transparent, translucent, opaque

17. Chapter 1- Introduction Classification of Materials –In materials science there have typically been three categories of materials Metals Ceramics Polymers –I will also use this convention; in addition there are several others that are variants (or combinations) of the three Composites Semiconductors Biomaterials

18. Chapter 1- Introduction Metals –Defining characteristic of a metal High number of delocalized electrons –What does this mean? -- The electrons (outer valence e - ’s of the various atoms) are not bound to particular atoms –Impact delocalization has on properties? Metals are: »Good conductors of heat and electricity »Not transparent to visible light »Mechanically they are strong, yet deformable Examples – silver, gold, platinum, copper

19. Chapter 1-

20. Introduction Ceramics –“Between” metallic and nonmetallic compounds Oxides, nitrides, and carbides These materials are typically insulators of heat and electricity More resistant to high temperature (e.g. high melting points) and harsh environments (e.g. pH) than metals Mechanically – ceramics are hard but brittle Examples: silica (glass), alumina, silicon nitride

21. Chapter 1- Introduction Polymers –Plastics and rubber materials Macromolecules – generally formed from carbon, nitrogen, and hydrogen (there are polymers that contain metals) Usually have low densities Can be extremely flexible Not stable at high temperatures typically Examples: polyethylene, polystyrene, polyamide (Nylon®)

22. Chapter 1- Introduction Composites –Exactly what it sounds like: a new material that consists of more than one component Fiberglass – glass fibers embedded in a polymeric matrix Idea – get desirable features of each material component Complicated though – does not always work out as well as you’d like

23. Chapter 1- Introduction Semiconductors –Materials with electrical properties intermediate of a metal (good conductor) and a ceramic (good insulator) –Silicon is the essential example – computer chips Key to use of semiconductors is the extremely precise control of dopant atoms that are used to manipulate the conducting properties

24. Chapter 1- Introduction Biomaterials –Use of the above materials in life science applications –Key point: the material must not lead to an adverse physiological reaction –Hip implants are the big success story here

25. Chapter 1- ex: hardness vs structure of steel Properties depend on structure Data obtained from Figs. 10.21(a) and 10.23 with 4wt%C composition, and from Fig. 11.13 and associated discussion, Callister 6e. Micrographs adapted from (a) Fig. 10.10; (b) Fig. 9.27;(c) Fig. 10.24; and (d) Fig. 10.12, Callister 6e. ex: structure vs cooling rate of steel Processing can change structure 2 Structure, Processing, & Properties Hardness (BHN)

26. Chapter 1- 1. Pick ApplicationDetermine required Properties 2. Properties Identify candidate Material(s) 3. Material Identify required Processing Processing: changes structure and overall shape ex: casting, sintering, vapor deposition, doping forming, joining, annealing. Properties: mechanical, electrical, thermal, magnetic, optical, deteriorative. Material: structure, composition. 3 The Materials Selection Process

27. Chapter 1- Electrical Resistivity of Copper: Adding “impurity” atoms to Cu increases resistivity. Deforming Cu increases resistivity. 4 Adapted from Fig. 18.8, Callister 6e. (Fig. 18.8 adapted from: J.O. Linde, Ann Physik 5, 219 (1932); and C.A. Wert and R.M. Thomson, Physics of Solids, 2nd edition, McGraw-Hill Company, New York, 1970.) ELECTRICAL

28. Chapter 1- Space Shuttle Tiles: --Silica fiber insulation offers low heat conduction. Thermal Conductivity of Copper: --It decreases when you add zinc! 5 Fig. 19.0, Callister 6e. (Courtesy of Lockheed Missiles and Space Company, Inc.) Adapted from Fig. 19.4W, Callister 6e. (Courtesy of Lockheed Aerospace Ceramics Systems, Sunnyvale, CA) (Note: "W" denotes fig. is on CD-ROM.) Adapted from Fig. 19.4, Callister 6e. (Fig. 19.4 is adapted from Metals Handbook: Properties and Selection: Nonferrous alloys and Pure Metals, Vol. 2, 9th ed., H. Baker, (Managing Editor), American Society for Metals, 1979, p. 315.) THERMAL

29. Chapter 1- Magnetic Permeability vs. Composition: --Adding 3 atomic % Si makes Fe a better recording medium! Adapted from C.R. Barrett, W.D. Nix, and A.S. Tetelman, The Principles of Engineering Materials, Fig. 1-7(a), p. 9, 1973.Electronically reproduced by permission of Pearson Education, Inc., Upper Saddle River, New Jersey. 6 Fig. 20.18, Callister 6e. (Fig. 20.18 is from J.U. Lemke, MRS Bulletin, Vol. XV, No. 3, p. 31, 1990.) Magnetic Storage: --Recording medium is magnetized by recording head. MAGNETIC

30. Chapter 1- Transmittance: --Aluminum oxide may be transparent, translucent, or opaque depending on the material structure. 7 Adapted from Fig. 1.2, Callister 6e. (Specimen preparation, P.A. Lessing; photo by J. Telford.) single crystal polycrystal: low porosity polycrystal: high porosity OPTICAL

31. Chapter 1- Stress & Saltwater... --causes cracks! Heat treatment: slows crack speed in salt water! 4m4m --material: 7150-T651 Al "alloy" (Zn,Cu,Mg,Zr) Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation and Fracture Mechanics of Engineering Materials" (4th ed.), p. 505, John Wiley and Sons, 1996. (Original source: Markus O. Speidel, Brown Boveri Co.) 8 Adapted from Fig. 17.0, Callister 6e. (Fig. 17.0 is from Marine Corrosion, Causes, and Prevention, John Wiley and Sons, Inc., 1975.) Adapted from Fig. 11.24, Callister 6e. (Fig. 11.24 provided courtesy of G.H. Narayanan and A.G. Miller, Boeing Commercial Airplane Company.) DETERIORATIVE

32. Chapter 1- Use the right material for the job. Understand the relation between properties, structure, and processing. Recognize new design opportunities offered by materials selection. Course Goals: 9 SUMMARY

33. Chapter 1- Reading: Chapter 1. Class notes are in: http://che.tamu.edu/people/facultyhttp://che.tamu.edu/people/faculty/ Click on Balbuena, then on Research Page, then on Teaching: 313 Materials HW # 1: due Friday, January 26: Problems 2.2, 2.3, 2.4, 2.5, 2.8, 2.13, 2.15, 2.18, 2.22, and 2.12 0 ANNOUNCEMENTS