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Ch. 10.1 – Chemical Reactions II. Balancing Equations read: (p. 278 – 283)
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A. Words to Skeletons First Read the statement and underline all reactants and products first. “Iron and chlorine react to produce iron(III) chloride.” Write a word equation, then a skeleton: iron(s) + chlorine(g) → iron(III) chloride(s) Fe(s) + Cl 2 (g) → FeCl 3 (s)
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B. Balancing Steps 1.Write the unbalanced skeleton equation. Check formulas; look for diatomic elements. 2.Count atoms on each side. 3. Never change a formula; add coefficients to make #s equal. Coefficient subscript = # of atoms 4.Reduce coefficients to lowest possible ratio, if necessary. 5. Double check atom balance!!! YOU MUST OBEY THE LAW.
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C. Helpful Tips n Balance one element at a time, working left to right except for H and O. Save H for next to last, and O until last. n Update ALL atom counts after adding a coefficient. NEVER change a formula. n Balance polyatomic ions as single units if they appear on both sides “1 SO 4 ” instead of “1 S” and “4 O”
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D. Law of Conservation of Mass Fe(s) + Cl 2 (g) → FeCl 3 (s) 2 2 3
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D. Law of Conservation of Mass Fe(s) + Cl 2 (g) → FeCl 3 (s) 2 2 3 Fe = 1 Cl = 2 Fe = 1 Cl = 3 X 2 = 2 = 6 X 2 = 2 X 3 = 6 Atoms are placed in “boxes” to ensure the formula is not changed; the number of “boxes” can change, but not the insides of the boxes.
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Potassium chromate reacts with lead(II) nitrate to produce potassium nitrate and solid lead(II) chromate. The reaction occurs in water. Write a skeleton equation with correct formulas. D. Law of Conservation of Mass K 1+ (CrO 4 ) 2- + Pb 2+ (NO 3 ) 1- → K 1+ (NO 3 ) 1- + Pb 2+ (CrO 4 ) 2- K 2 CrO 4 (aq) + Pb(NO 3 ) 2 (aq) → KNO 3 (aq) + PbCrO 4 (s)
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K = 2 CrO 4 = 1 Pb = 1 NO 3 = 2 K = 1 NO 3 = 1 Pb = 1 CrO 4 = 1 x 2 = 2 = 2 2 2 K 1 1 CrO 4 1 1 Pb 1 2 NO 3 1 / 2222 /
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Al + CuCl 2 Cu + AlCl 3 Al Cu Cl 1 1 1 1 2 3 2 3 6 3 33 2 E. Balancing Example Aluminum and copper(II) chloride react to form copper and aluminum chloride. 2 2 6
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