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Published byJoshua Dorsey Modified over 9 years ago
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Atomic and Molecular Masses This is so wrong. Bohr model? More like I’m bored of seeing this incorrect model.
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Let’s Start With 1 Mole of 12 C 12 C chosen semi-arbitrarily Each 12 C atom has 6 protons, 6 neutrons, and 6 electrons. Therefore, 1 mole of 12 C has: 6 moles of protons, 6 moles of neutrons, and 6 moles of electrons.
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Let’s Start With 1 Mole of 12 C But a mole is chosen so that 1 mole of protons weighs 1 g (electrons are too small to make any difference). So our 1 mole of 12 C has: 6 grams of protons, 6 grams of neutrons, and ~0 grams of electrons. Therefore, 1 mole of 12 C weighs….12 grams! (Keanu moment)
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This is the Point of Moles! Avogadro’s number is actually chosen so that this will be true. 1 mole of any element has a mass, in grams, equal to its atomic mass. 1 mole of 63 Cu weighs 63 g.1 mole of 79 Br weighs 79 g 1 mole of 14 C weighs 14 getc. These all have the same NUMBER OF ATOMS—one mole. Because some are heavier than others, the masses are different.
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This is the Point of Moles! Each of these beakers is 1 mole (6.022*10 23 ) atoms. Because the masses and densities are different, there are very different masses and volumes in each beaker. If we had the same mass of each element, the number of atoms would be different instead.
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Real Samples Actual samples of elements come as a mix of isotopes. For example, any natural sample has the following mix: 12 C = 98.9% 13 C = 1.1% 14 C = essentially zero, but you can see it’s there because it’s radioactive Therefore, the weighted average of carbon’s mass is 0.989*12 + 0.011*13 = 12.011 (which is the atomic mass on the periodic table) 1 mole of 12 C weighs exactly 12 grams, 1 mole of any naturally-occurring mix of carbon will weigh 12.011 grams This makes sense—a few of those carbon atoms are a little bit heavier. (if we had a really small sample, we might get all 12 C by chance, but our sample sizes will always be in the gajillions)
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Using Atomic Masses
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Two Different Conversion Factors Number of Atoms Moles Grams Avogadro’s Number. Same no matter what the element is Atomic Mass. Different value for each element.
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Putting Them Together
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You Can Do It All Together
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Molecular/Formula Weights Take a simple compound: H 2 O 1 mole of water has 2 moles of hydrogen atoms, and 1 mole of oxygen atoms Each mole of hydrogen atoms weighs 1.008 g, and each mole of oxygen atoms weighs 15.999 g. Therefore, 1 mole of water weighs 2*1.008 + 15.999 = 18.015 g (the sum of the atomic masses) This is the molecular weight (or molecular mass, or molar mass). For an ionic compound, this would be the formula weight (same thing, but not molecular since there are no molecules). You use it just like atomic mass: to convert between grams and moles
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Summary 1 mole of an element weighs its atomic mass in grams Because real samples have mixed isotopes, you use the average mass from the periodic table. This is a conversion factor for going from moles to grams, or grams to moles. For compounds, the molecular/formula weight is just the sum of the elements' atomic masses.
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