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Single Replacement Reactions: A +BC  AC + B

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1 Single Replacement Reactions: A +BC  AC + B
An element takes the place of another element in a compound. It could be a metal taking the place of another metal or hydrogen or a halogen taking the place of another halogen. Mg(s) + FeSO4(aq)  Cl2(g) + KBr(aq)  Fe(s) + MgSO4 (aq)  Br2 (aq) + KCl(aq)  MgSO4 (aq) + Fe(s) Magnesium is more active than Iron and KCl(aq) + Br2 (aq) Chlorine is more active than Bromine! N.R. N.R.

2 Activity Series: Activity Decreases F Activity Cl Decreases Br I
For metals: Lithium Li Cs Rb K Ba Sr Ca Na La Mg Be Al Mn Zn Cr Fe Cd Co Ni Sn Pb H Cesium Rubidium Activity Series: Potassium Barium Strontium For halogens: Activity Decreases Calcium Sodium Activity Decreases F Cl Br I Fluorine Lanthanum Magnesium Chlorine Beryllium Bromine Aluminum Iodine Manganese Zinc H Cu Hg Ag Pt Au Hydrogen Chromium Iron Copper Cadmium Mercury Cobalt Silver Nickel Tin Platinum Lead Gold Hydrogen

3 Double Replacement Reactions :
AB +CD  AD + CB It is a reaction between two ionic compounds in which the ions switch positions: The positive of the first combines with the negative of the second and the positive of the second with the negative of the first. MgCO3(s) + FeSO4(aq)  BaCl2(aq) + KBr(aq)  Fe(NO3)3(aq)+Ca3(PO4)2(s) CuBr2 (aq) + KCl(aq)  MgSO4 (aq) + FeCO3 (s) 2 BaBr2(aq) + KCl(aq) 2 2 Ca(NO3)2(aq)+ FePO3(s) 3 2 2 CuCl2 (aq) + KBr(aq) 2

4 Double-replacement reactions
One of the types of double-replacement reactions is when a precipitate is formed. When a precipitate is formed, the compound will be either insoluble or slightly soluble. An example of this type of reaction is: Pb(NO3)2(aq) + 2KI (aq) --> PbI2(s) + 2KNO3 (aq) When one of the products is a gas, double-replacement reactions also occur. For example: FeS(s) + 2HCl(aq) --> H2S(g) + FeCl2(aq) An example of a double-replacement reaction where water is one of the products is: HCl(aq)+ NaOH(aq) --> NaCl (aq) + H2O(l) This is a neutralization reaction: Acid + Base = Salt + Water

5 Combustion of a hydrocarbon: Hydrocarbon+O2(g)C O2(g)+H2O(g)
When a substance combines with oxygen releasing a large amount of energy in the form of light and heat, it is a combustion reaction. An example of a combustion reaction is: C3H8 + 5O2 --> 3CO2 + 4H2O + +

6 Decomposition Reactions: ABC…  A +B +C …
Decomposition: the breaking down of a compound into one or more substances. (usually energy is required) EXAMPLES: CO2 (g) ----- C(s) + O2(g) Fe2O3 (s)- 4Fe(s) + 3O2 (g) Generalizations: A binary compound decomposes into two elements. A hydroxide of the metal decomposes into an oxide of the metal and water. A ternary salt decomposes into an oxide of the metal and an oxide of the non metal. A ternary or oxoacid decomposes into the oxide of a non metal and water .


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