1. HIRDLS Ozone V003 (v2.04.09) Characteristics B. Nardi, C. Randall, V.L. Harvey & HIRDLS Team HIRDLS Science Meeting Boulder, Jan 30, 2008

2. 1 km OZONESONDE Profile Comparisons 1 km Fine vertical scale features are resolved. At highly variable early-spring high latitude, effect of sampling different air-masses is accentuated: smallest scales do not match. High latitude Mid-latitude Low latitude

3. 1 km MLO [19.5 o N, 156 o W] TMF [34.5 o N, 118 o W] OZONE Lidar Profile Comparisons 1 km

4. OZONE Lidar comparisons – Statistical Differences Mauna Loa Observatory [19.5 o N, 156 o W]Table Mountain Facility [34.5 o N, 118 o W] HIRDLS bias is generally low, 5-10%, except region ~ 5-25 hPa, 5-10% high bias.

5. OZONESONDE Comparisons – Statistical Differences

6. INTEX-B AROTAL Lidar Tight coincidence criteria (50km, 3hrs) shows low bias of <5%, except region 50-80 hPa, where it’s <10%.

7. MLS v2.2 Zonal Mean 2006Jul 2006Oct 2006Feb2006May O 3 Percent Diff (%) Pressure (hPa) Pressure surfaces 1 hPa 3 hPa 51 hPa 100 hPa O 3 Percent Diff (%) 31 hPa 10 hPa Latitude

8. Anticyclone border HIRDLS v2.04.09 MLS v2.2 Polar Vortex border

9. Shown is the ozone standard deviation in different equivalent latitude and potential temperature bins. Results are in terms of percentage of mean VMR (black lines, 10%; white lines, 100%). This variability includes both the atmospheric variability and the random error of the HIRDLS data. The atmospheric variability is a minimum in summer, so the variability in high latitude summer is an upper bound of the HIRDLS precision. This is estimated at 2-8% between 500-2000K (1-50 hPa). Ozone Estimated Precision (v2.04.09) December 22June 20 ~50 km, ~1 hPa -- ~15 km, ~120hPa --

10. SUMMARY 1.An estimate of the HIRDLS ozone precision is 5-10% between 1-50 hPa, based on the variability of HIRDLS measurements in regions of minimum geophysical variability 2.HIRDLS ozone is reliable between 1 hPa – 100 hPa at mid and high latitudes and between 1 – 50 hPa at low latitudes. 3.HIRDLS ozone accuracy is better than 10% between 1 - 30 hPa (HIRDLS biased generally low). Some lidars and sondes indicate better accuracy: 5% between 2 - 10 hPa, and between 30-40 hPa, respectively. 4.A region of slightly positive 5% HIRDLS bias exists in a limited pressure range within 10- 30 hPa at nearly all latitudes; this is observed by comparisons with sondes (SHADOZ, WAVES), lidars (MLO, TMF) and satellites (ACE, MLS). 5.At low latitudes a high HIRDLS bias begins at ~50 hPa and increases rapidly with increasing pressure. This may be caused by spikes indirectly related to the presence of clouds. 6.Ozonesonde and lidar profile comparisons give a strong indication that HIRDLS is capable of detecting fine vertical structure in the ozone field on the order of 1 to 2 km. 7.HIRDLS is capable of resolving low ozone pocket features associated with anticyclones in the highly variable northern winter high latitudes.

11. Odds & Ends 1. At mid and high latitude HIRDLS ozone may be reliable to several hundred hPa in the absence of local cloud features. Systematic bias is unknown due to lack of statistics; 2. The lower boundary for usable tropical lower stratospheric ozone may be extended earthward (~68 hPa) by using the HIRDLS 12.1 micron extinction parameter to screen data. 3. Negative values of retrieved total error ("O3Precision") indicate a >50% contribution to the error from a priori sources, and thus a strong a priori influence in the result. This is typically not an issue with tropical lower stratospheric ozone. 4. Upcoming release has increased vertical range, spaceward of 1 hPa, and at the earthward limit as well. The low bias is somewhat lessened, especially in the lower stratosphere. 5. A priority for future ozone improvements is in diminishing the effects of clouds in the ozone retrieval and screening remaining cloud at low latitudes. HIRDLS Data Quality Document (Updated version to be posted very soon) 5.2 Ozone SpeciesOzone (O3) Data Field Name: O3 Useful Range: 1hPa – 100+ hPa Vertical Resolution: 1.2 - 2 km Contact: Bruno Nardi Email:nardi@ucar.edunardi@ucar.edu Validation Paper: Nardi et al., Initial Validation of Ozone Measurements from the High Resolution Dynamic Limb Sounder (HIRDLS), in review, J. Geophys. Res., 2007

13. HIRDLS Data Quality Document 5.2 Ozone SpeciesOzone (O3) Data Field Name: O3 Useful Range: 1hPa – 100+ hPa Vertical Resolution: 1.2 - 2 km Contact: Bruno Nardi Email:nardi@ucar.edunardi@ucar.edu Validation Paper: Nardi et al., Initial Validation of Ozone Measurements from the High Resolution Dynamic Limb Sounder (HIRDLS), in review, J. Geophys. Res., 2007

14. ACE-FTS (satellite solar occultation) ACE satellite comparisons since May 2006 show agreement to within ~10% between 3 - 25 hPa in the NH (left) and between 1 - 50 hPa in the SH (right), with HIRDLS biased generally low.

15. Figure 5.2.4. A single orbit curtain plot comparison with MLS (Left: MLS; Middle: HIRDLS; Right: Difference) indicates HIRDLS is tends to be 10% lower earthward of ~30 hPa and is generally 10% high above ~1hPa and rapidly increases. HIRDLS ozone tends to be slightly lower than MLS, especially in the (night-time) descending node (RHS of panels).

16. Mean Difference 1 σ of Differences Individual Differences.... ….. Figure 5.2.1. Ozone difference between 97 SHADOZ Network (low latitude) ozonesonde profiles and 1042 coincident HIRDLS profiles, in terms of mixing ratio, left and in terms of percent (of sonde values), right. Shown are the mean difference (solid blue), the standard deviation (dashed blue) and the individual differences (black dots) from which these are derived. SHADOZ Network

17. Figure 5.2.2. Ozone difference between 73 MLO lidar profiles and the 659 coincident HIRDLS profiles, in terms of mixing ratio, left, and percent (of sonde values), right. MLO lidar

18. Figure 5.2.3. ACE satellite solar occultation comparisons since May 2006 show agreement to within ~10% (bottom) between 3 - 25 hPa in the Northern Hemisphere (left) and between 1 - 100 hPa in the Southern Hemisphere (right), with HIRDLS biased generally low. ACE satellite

19. Figure 5.2.5. Mercator representations of the ozone percent difference between HIRDLS and collocated MLS (v2.2) for 2006-July-15, at pressure levels, 1 hPa, 3 hPa, 10 hPa, 31 hPa, 51 hPa and 100 hPa, as indicated over each sub-plot. The ozone fields for this day are relatively quiescent. Clearly illustrated in this and the previous figure is that in the tropics earthward of ~60 hPa HIRDLS ozone tends to be very high with respect to MLS. This is probably related to the presence of high cloud-tops. MLS (v2.2)

20. Figure 5.2.6 Comparisons of HIRDLS profiles with: ozonesonde profile from La Reunion Island (left), and with MLO lidar profiles (right).

21. Anticyclone border HIRDLS v2.04.09 MLS v2.2 Polar Vortex border Ozone

22. Figure 5.2.7. An estimate of the HIRDLS ozone precision based on ozone variability in equivalent latitude bins. High precision estimates at winter-hemisphere high latitudes (LHS of top plots; RHS of bottom plots) may be indicative of the breakdown of the estimate rather than of an actual deterioration of HIRDLS precision.