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Units
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Calculations
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Energy
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Vocab
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Temperature
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Grab Bag
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What is the SI unit for temperature?
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Kelvin
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What is the unit for molar heat capacity?
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J/K∙mol
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What is the unit for n?
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mol
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What is the unit of energy? Write the word and symbol on the board.
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Joules, J
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What is the unit for molar enthalpy?
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J/mol
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What is the generic equation for changing Celsius into Kelvin.
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° C + 273= K
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Use this equation if you are finding the change in heat for 25g of water.
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q =nC∆T
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Use this equation if you are finding the molar enthalpy change and do not have the amount in moles.
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∆ H=C∆T
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What is the generic equation for finding the change in enthalpy for a reaction using Enthalpies of Formation?
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∆H= ∆H° f products- ∆H° f reactants
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Calculate the change in enthalpy when forming aluminum oxide. 2Al(s) + 3H 2 O(l)→ Al 2 O 3 (s) + 3H 2 (g) ∆H f H2O = -285.8 kJ/mol ∆H f Al2O3 = -1676.0 kJ/mol
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-1676.0- (3x-285.8)= -818.6kJ/mol
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If the energy change in a reaction is negative the reaction is __________.
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Exothermic
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When ∆H is positive, the reaction is __________.
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Endothermic
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What is the only way we measure energy?
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With a thermometer
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Calculate the molar enthalpy change of N 2 (g) when it is heated from 90.0°C to 100.°C. The molar heat capacity of nitrogen is 29.1 J/K∙mol. Don’t forget to round to the correct sig figs.
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291 J/mol
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Calculate ∆H for this reaction: 3Fe 2 O 3 (s) → 6Fe(s) + 4.5O 2 (s) 3Fe 2 O 3 (s)→2Fe 3 O 4 (s) + 1/2O 2 (s) ∆H=-316kJ/mol 3Fe(s) + 2O 2 (g) → Fe 3 O 4 (s) ∆H=-201kJ/mol.
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86kJ/mol
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Define molar heat capacity. Hint: think about the units
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The amount of energy required to raise 1 mole of a substance 1K.
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Define extensive property.
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A property that depends on the amount of substance, like heat.
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Define intensive property. Is heat or temperature intensive?
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A property that is independent of the amount of substance, like temperature.
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Define heat.
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The energy transferred between two objects of different temperatures.
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Define Hess’s Law.
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The change in enthalpy for a reaction is equal to the sum of the individual enthalpy changes.
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Define temperature.
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The average kinetic energy of the particles in an object.
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Convert 17°C to Kelvin.
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17°C + 273= 315K
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Correctly write the standard thermodynamic temperature in Celsius and Kelvin on the board. This is the temp that the reactants are at for all heat measurements
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25°C and 298K (no degree symbol for K)
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What is ∆T in Kelvin if an object is cooled from 50°C to 30°C.
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20K
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What is the generic equation when solving for ∆T in this equation: q=nC∆T?
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∆T = q/nC
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Write the symbol(s) for “the change in temperature” on the board.
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∆T
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How many sig figs does the following measurements have? a. 4500J b. 350.J c. 111.0J
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a. 4500J= 2 b. 350.J = 3 c. 111.0J = 4
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What do all the variables in q=nC∆T represent?
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q= heat n= moles C= molar heat capacity ∆T = temperature
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This chapter is about Thermodynamics, it is the study of _______ changes.
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energy
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Explain why a balloon with 50mL of water in it won’t pop when a flame is held to it.
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Because the molar heat capacity of water is high (which means it takes a lot of energy to heat water). and the energy from the flame is transferred to the water before the balloon.
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