1. Drill: Draw & name 5 isomers of C 5 H 8

2. Review Drill & Test

3. Functional Groups

4. Draw & Name Isomers of: C 4 H 6

5. Functional Groups Chemically active part of an organic compound

6. Functional Groups Anything other than singularly bonded carbon & hydrogen in an organic compound

7. Functional Groups The name of any organic compound ends with the suffix for the most important functional group

8. Terminology R- represents the part of the organic compound you are not referring to

9. Terminology R-OH -OH is the functional group R- anything else

10. Alkene C=C

11. Alkyne C=C

12. Halides R-X X = F, Cl, Br, or I haloalkane alkylhalide

13. Halides Cl 2-chlorobutane 2-butylchloride

14. Ethers R 1 -O-R 2 alkylalkylether alkoxyalkane

15. Ethers CH 3 CH 2 -O-CH 3 Methylethylether methoxyethane

16. Hydroxyl Group C OH

17. Alcohols R-OH hydroxyalkane alkanol

18. Alcohols CH 3 -CH 2 -OH hydroxyethane ethanol

19. Carbonyl Group C=O

20. Ketones O R-C-R Oxy or ketoalkane alkanone

21. Ketones O 3-pentanone 3-oxypentane

22. Aldehyde O R-C-H alkanal alkanaldehyde

23. Aldehydes O hexanal hexanaldehyde H

24. Name the following: OHCl CHCH H 3 C CH 2 CH 3

25. Name the following: OHCl CHCH H 3 C CH 2 CH 3

26. 4-chloro-2-pentanol OHCl CHCH H 3 C CH 2 CH 3

27. Drill: Name the following: OHO

28. Carboxyl Group C=O HO

29. Carboxylic Acid O R-C-OH Alkanoic Acid

30. Carboxylic Acid O CH 3 -CH 2 -C-OH Propanoic Acid

31. Drill: Draw & name 5 isomers of: OH

32. Functional Isomers: Isomers with different functional groups: The suffix changes

33. Propanone Propanaldehyde O O H

34. Positional Isomers: Isomer’s functional group in a new location The # before the main chain name changes

35. 2-propanol 1-propanol OH

36. Name the following: CH 3 -CH 2 -CH 2 -OH CH 3 -CH 2 -O- CH 2 -CH 3 O CH 3 -CH 2 -C-CH 2 -CH 3

37. Name the following: O O C C H 3 C CH OH OH

38. Name the following: O O C C H 3 C CH OH OH

39. 2-hydroxy-3-ketobutanoic acid O O C C H 3 C CH OH OH

40. Name the following: O CH 3 -CH 2 -CH 2 -C-OH O CH 3 -CH 2 -C-H

41. Carboxyl Derivatives C=O O

42. Esters O R 1 -C-O-R 2 Alkylalkanoate

43. Esters O CH 3 -CH 2 -CH 2 -C-O-CH 3 methylbutanoate

44. Anhydrides O O R 1 -C-O-C-R 2 Alkanoicalkanoic anhydride

45. O O O Butanoicpropanoic anhydride

46. Draw the following: 2-hydroxypentanal Methylpropylether Trichloroethanoic acid Ethylbutanoate Aceticformic anhydride

47. Drill: Draw & Name 5 isomers of: C3H6O2C3H6O2

48. Name, then & Draw & name a Functional Isomer of: O OH C C C C C C C

49. O C C C C C C C

50. 3-hydroxy-5- methylhexanoic acid O OH C C C C C C C

51. 2,3-dihydroxy-5- methylhexanal(dehyde) O H C C C C C C OH C

52. 1,3-dihydroxy-5- methyl-2-hexanone O OH C C C C C C C

53. Name & Draw 1 Positional Isomer of: O OH C C C C C C C

54. O C C C C C C C 2-hydroxy-5- methylhexanoic acid

55. Name & Draw 1 Structural Isomer of: O OH C C C C C C C

56. 3-hydroxyheptanoic acid O OH C C C C C C C

57. Name & Draw 1 Optical Isomer of: O OH C C C C C C C

58. To draw an optical isomer, draw the mirror image of an assymetric compound

59. O OH C C C C C C C 3-hydroxy-5- methylhexanoic acid

60. C C C C C C HO O OH C 3-hydroxy-5- methylhexanoic acid

61. Draw: 2-phenylpropanoic acid 3-hydroxy-2-iodopentanal 2-cyclohexyl-3-octanone phenylbutanoate

62. Drill: Name: C C C C OH O C OCl

63. Drill: Draw the following: Butanoicpentanoic anhydride

64. Thiol R-SH Sulfhydrylalkane Mercaptoalkane Alkanethiol

65. SH 3-sulfhydrylpentane 3-mercaptopentane 3-pentanethiol

66. Sulfide R 1 -S-R 2 Alkylalkylsulfide Alkylalkylthioether

67. Sulfide S diethylsulfide diethylthioether

68. Disulfide R 1 -S-S-R 2 Alkylalkyldisulfide

69. Disulfide S-S methylphenyldisulfide C

70. Thioesters O R 1 -C-S-R 2 Alkylthioalkanoate

71. Thioesters O CH 3 -C-S-CH 3 Methylthioethanoate

72. Draw the Following: Methylthiobutanoate Methylphenyl ether Diphenyl thioether 2-propanethiol

73. Name: C C C C C OH O SH Cl

74. C C C C C OH O SH Cl

75. 3-chloro-2-mercaptopentanoic acid C C C C C OH O SH Cl

76. Drill: Name: C C C C O C O

77. Amine Group N:

78. Ammonia :NH 3

79. Ammonium NH 4 +

80. Primary Amines R-NH 2 Aminoalkane alkylamine

81. Primary Amines CH 3 -NH 2 Aminomethane methylamine

82. Secondary Amines R 2 R 1 -NH Alkylalkylamine

83. CH 3 CH 3 -CH 2 -NH methylethylamine

84. Tertiary Amines R 2 R 1 -N-R 3 Alkylalkylalkylami ne

85. CH 2 -CH 3 CH 3 -N: CH 2 -CH 2 -CH 3 methylethylpropylamine

86. Quaternary Amines R 2 R 1 -N-R 3 R 4 Tetraalkylammonium +

87. CH 3 CH 3 -N-CH 3 CH 2 -CH 2 -CH 3 trimethylpropylammonium +

88. CH 3 CH 3 -N-H CH 2 -CH 2 -CH 3 dimethylpropylammonium +

89. Amides O R 1 -C-NH 2 Alkanoamide

90. O C-C-C-C-C NH 2 Pentanoamide

91. Nitrile R-C=N Cyanoalkane Alkanonitrile

92. Nitrile CH 3 -C=N Cyanomethane Ethanonitrile

93. Name: C C C C C OH O F

94. Name: C C C C C OH O F

95. 3-fluoro-4- hydroxypentanoic acid C C C C C OH O F

96. Draw & name 10 isomers of: C 4 H 9 NO

97. Draw the following: 2-phenyl-1-propanol Butylethenyl ether

98. Draw the following: phenylthioacetate methylisopropylsulfide 2-mercaptobutanal

99. Name: C C C S C C O

100. C C C S C C O

101. propylthioacetate C C C S C C O

102. Name: SH O OH

103. Name: SH O OH

104. 3-hydroxy-5-mercapto-6- methyl-7-phenyloctanoic acid SH O OH

105. Draw & name 10 isomers of: C 4 H 8 SO 2

106. Drill: Name SH O H O

107. Name C N OH N H O H

108. Name C N OH N H O H

109. 4-cyano-2-hydroxy-3- methylhexanoamide C N OH N H O H

110. Drill: Name Cl OH O

111. Primary Amines R-NH 2 Aminoalkane alkylamine

112. Secondary Amines R 2 R 1 -NH Alkylalkylamine

113. Tertiary Amines R 2 R 1 -N-R 3 Alkylalkylalkylami ne

114. Quaternary Amines R 2 R 1 -N-R 3 R 4 Tetraalkylammonium +

115. Amides O R 1 -C-NH 2 Alkanoamide

116. Nitrile R-C=N Cyanoalkane Alkanonitrile

117. Name C N OH NH 2 O

118. Cyanate R-O-C=N Alkylcyanate

119. Cyanate O-C=N cyclohexylcyanate

120. Isocyanate R-N=C=O Alkylisocyanate

121. Isocyanate N=C=O 1-pentylisocyanate

122. Thiocyanate R-S-C=N Alkylthiocyanate

123. Thiocyanate S-C=N 2-propylthiocyanate

124. Isothiocyanate R-N=C=S Alkylisothiocyanate

125. Isothiocyanate CH 3 -N=C=S Methylisothiocyanate

126. Phosphates O R-O-P-O -1 O -1 Alkylphosphate

127. Phosphates O -O-P-O -1 O -1 Phenylphosphate

128. Diphosphates O O R-O-P-O-P-O -1 O -1 O -1 Alkyldiphosphate

129. Diphosphates O O CH 3 -O-P-O-P-O -1 O -1 O -1 Methyldiphosphate

130. Triphosphates O O O R-O-P-O-P-O-P-O -1 O -1 O -1 O -1 Alkyltriphosphate

131. Triphosphates O O O -O-P-O-P-O-P-O -1 O -1 O -1 O -1 2-butyltriphosphate

132. Phosphodiester O CH 3 -CH 2 -O-P-O-CH 3 O -1 Methylethylphosphate

133. Carboxylic acid Carboxylic acid derivative Aldehyde Ketone Alcohol Amine Thiol

134. Drill: Draw & Name 5 isomers of: C 3 H 7 NO 2

135. Drill: Name: C O OH NH 2 OH Br

136. Organic HW Draw & Name 5 isomers of: C 3 H 6 SO

137. Drill: Draw & Name 5 Isomers of: C 4 H 7 NO

138. Lab: Today Review: Tomorrow Test : Wednesday

139. Name the following: C O NH 2 OH NCNC

140. Name the following: C O NH 2 OH NCNC

141. 3-cyano-2-hydroxy-7-methyl- 6-phenyloctanoamide C O NH 2 OH NCNC

142. Drill: Name the following: C O OH NHSH Cl

143. Name the following: C O OH NHSH Cl

144. 2-amino-3-chloro-4- mercapto-N,7-dimethyl-6- phenylnonanoic acid C O OH NHSH Cl

145. Test Tomorrow on Functional Groups

146. Name the following: O OHF

147. Name the following: O OHF

148. 3-fluoro-1-methoxy-4-methyl-2- cyclopropylhepta-5-yn-1-ol O OHF

149. Name the following: OO O PO 4 -2 OH

150. Name the following: OO O PO 4 -2 OH 2 1

151. 4-methyl-3-phenyl-2- phosphopentanoic-2- hydroxypropanoic anhydride OO O PO 4 -2 OH 2 1

152. Draw: 3-mercaptohexanoamide Methyl-2-hydroxythioacetate Para-iodophenylformic acid Phenylpropylamine 2-amino-3-ethyl-4-keto-N- methylhexanaldehyde

153. Draw & Name 10 isomers of: C 4 H 9 SNO

154. Draw & Name 10 isomers of: C 4 H 9 NO 2

155. Name the following: NH P 3 O 10 -4

156. Name the following: NH P 3 O 10 -4

157. 4-amino-6,7-dimethyl-N- phenyl-3-octyltriphosphate NH P 3 O 10 -4

158. Name the following: O SH O H

159. Name the following: O SH O H

160. 3-mercapto-6,7-dimethyl- 4-phenoxynonanal O SH O H

161. Drill: Name: OH NH 2 O OH NCNC

162. Name: OH NH 2 O OH NCNC

163. 3-amino-5-cyano-4- hydroxyhexanoic acid OH NH 2 O OH NCNC

164. Name the following: Br O O NCSNCS

165. Name the following: Br O O NCSNCS 1

166. propyl-4-bromo-3-cyclobutyl- 5-thiocyanatohexanoate Br O O NCSNCS 1

167. Name the following: O OHCl

168. Name the following: O OHCl

169. 3-chloro-2-cyclopropyl-4- methylpentanoic acid O OHCl

170. Drill: Name the following: O OF O

171. O OF O 1 2

172. Methyl-3-fluoro-2-keto-4- methylpentanoate O OF O 1 2

173. Name the following: S OOH NCNC

174. Name the following: S OOH NCNC 1 2

175. Ethyl-2-cyano-3- hydroxythiohexanoate S OOH NCNC 1 2

176. Draw the Following: 3-methyl-5-propyl- octanoamide Octylbutanoate

177. Draw the Following: Aceticpentanoic anhydride 2-cyano-3- mercaptohexanoic acid

178. Drill Draw & name 5 isomers of: C 4 H 7 NO

179. Draw: Benzoic acid

180. Draw: 4-hydroxy-N- methyl- benzoamide

181. Drill: Draw: 4-hydroxy-2- mercapto pentanoic acid

182. Review

183. C=C

184. O R C O R

185. R N C O

186. R-SH

187. R-NH 2

188. O R C OH

189. O C R R

190. R-OH

191. O O C C R O R

192. R C N

193. H :N R R

194. O R C NH 2

195. O R C H

196. R O C N

197. R 1 -O-R 2

198. R-I

199. R + R N R R

200. C=C

201. R + R NH R

202. R 1 -S-R 2

203. O R C S R

204. R S C N

205. O -2 O P O R O

206. R :N R R

207. R-S-S-R

208. R N C S

209. Drill: Name: OH O NH 2 SH

210. Name the compounds on the board

211. Draw the compounds on the board

212. Draw & Name 10 isomers of C 4 H 7 SNO

213. C 4 H 7 NO