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Published byGyles Eric Watkins Modified over 9 years ago
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Kinetics The study of the mechanisms of a reaction and the rates of reaction.
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Factors that effect Rate of Reaction (R of R) Collision Theory Anything that will increase the number of and frequency of the collisions More effective collisions
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Factors that Effect Rates of Reactions (T,A,P,S,C,N) Temperature -(Average Kinetic Energy=motion) Inc. Temperature = Increase R of R Amount Increase Amount (concentration) = Increase R of R Pressure (g only) - Inc Pressure = increase R of R Surface Area – Inc. S.A. = Inc. R of R Nature of Reactants (Ionics > Covalents) Due to their reactivity and the number of bonds needed to break
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Catalyst – anything that is added that will increase the R of R If present will increase the R of R How? By providing an alternative pathway for the Reaction by effecting 3 things 1. E a of the Forward catalyzed Reaction 2. E a of the Reverse Catlayzed Reaction 3. PE of the Activated complex
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Two Kinds of Reactions Endothermic Absorb Energy Heat + AB A +B Heat is a reactant Break Bonds + H Exothermic Release Energy A + B AB + Heat Heat is a product = Stability Bond formation - H
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(Most Effective Collisions)
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1. PE of the Reactants 2. PE of the Products 3. PE of the Activated Complex (Most Effective Collisions) 4. E a =Activation Energy of forward Rxn 1. (The minimum amount of energy needed to start a reaction to completion) 5. E a of the Reverse Rxn 1. NOTE: Endo > Exo therefore Exo is more spontaneous 6. H (Heat of Reaction- Enthalpy) 1. H = H products – H reactants + H = Endothermic 1. - H = Exothermic
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Entropy S Entropy is defined as the degree of randomness, disorder, chaos (s) – (l) – (aq) – (g)
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