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Comparison of sonoluminescence in Water and Sulfuric Acid Kh. Imani, M. Silatani, R. Rezaei - Nasirabad, A. Moshaii, R. Sadighi - Bonabi,

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Presentation on theme: "Comparison of sonoluminescence in Water and Sulfuric Acid Kh. Imani, M. Silatani, R. Rezaei - Nasirabad, A. Moshaii, R. Sadighi - Bonabi,"— Presentation transcript:

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2 Comparison of sonoluminescence in Water and Sulfuric Acid Kh. Imani, M. Silatani, R. Rezaei - Nasirabad, A. Moshaii, R. Sadighi - Bonabi,

3 History: 1934(MBSL) 1934 Bath Ultrasound by H. Frenzel &H. Schultes(MBSL) 1989(SBSL) 1989 F. Gaitan (SBSL) 2005( H2SO4) 2005 F. Flannigan & S. Suslick ( H2SO4)

4 : Applications: Sonochemistiy Sonofusion Sonodynamic therapy

5 Physical and SL properties of some liquids:

6 Why sulfuric acid ? Higher intensity Appearance of line emission in spectrum

7 Hydrodynamics model: Bubble dynamics: boundary condition of pressure and Van der waals equation of gas:

8 Chemical reaction:

9 14/17 Mass transfer at the bubble wall: The bubble contents is assumed to be: ( Nobel gas+H 2 O+ Reaction products )

10 Heat transfer at the bubble wall: Conductivity coefficient Heat Conduction :

11 Instability conditions of bubble: Shape Instability (Sh-S) Diffusion Instability (D-S) Bjerknes Instability (Bj.thr.)

12 Physical properties :

13 Simulation Results:

14 With regard to computed phase diagrams, we chose the junction point (Pa, R0) of D-S curve with other stability curves

15 Evolution of radius versus time in one cycle :

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17 Total Number of Particles:

18 Number of H 2 O:

19 Number of H 2 SO 4 :

20 Temperature:

21 Calculation Experimental A. A.Troia, et. al, Ultrasonic sonochemistry—13(2006-)278

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