1. What is Chemistry??? the nature and properties of matter

2. homework review… What is chemistry?? Why is it considered a ‘central science’ ? macroscopic vs. microscopic –MACRO = BIG (you can see it) –MICRO = REALLY small (can’t see it with naked eye)

3. homework review… How is chemistry used in forensic science and crime scene analysis??

4. PHYSICAL EVIDENCE: matter and its forms Crime scenes secured by first officers on scene Evidence of a crime can exist in many forms: –Blood –Hair –Fibers –Gunshot residue

6. ANALYZING MATTER: chromotography Chromatography is a method for analyzing complex mixtures (such as ink) by separating them into the chemicals from which they are made. Chromatography is used to separate and identify all sorts of substances in police work. Drugs from narcotics to aspirin can be identified in urine and blood samples, often with the aid of chromatography.

7. LAB: analyzing ink composition QUESTION: what colors combine to form black ink? 1. Cut several coffee filters into long strips, one strip per pen. 2. Fold the end of each strip over then staple it to form a loop. 3. Place a dot of ink near the bottom of each strip. Use a pencil to identify which strip belongs to which pen.

9. 4. Use the pencil to suspend the strip in a small glass or container. 5. Carefully add water to the glass until it reaches the bottom of the paper strip just below the ink dot. Be sure the ink stays above the water and the paper stays in the water. 6. Allow the water to soak up the strip and watch what happens to the ink drop. 7. If the ink you are testing does not spread out, re-test it using rubbing alcohol.

10. 8. Repeat this process for each strip and compare your results. 9. Let the strips dry and tape them on a sheet of paper as a record of the different pen types.

11. This evidence (and EVERYTHING ELSE around it) is made up of matter. Matter is considered to be the physical material of the universe. In order to analyze evidence, you need to understand the properties of matter and the states in which it exists

12. - there are 3 basic states of matter: (remove heat) --------------------------------------------> <--------------------------------------------- (add heat)

13. Solid: orderly arrangement of particles, close together, fixed position Liquid: less orderly arrangement of particles, particles may move freely Gas: particles extremely chaotic (no order), VERY far apart! Add heat to move from solid to gas, remove heat to move from gas back to solid

14. Matter can be divided into 2 categories: -pure substance: uniform composition, cannot be separated into more than one component OR -mixture: 2 or more pure substances physically combined but NOT chemically bound together

15. pure substances can be divided AGAIN into two more categories: -elements: simplest form of a pure substance, made up of atoms OR -compounds: 2 or more elements chemically bonded together

16. Elements Aluminum (aluminum foil) Sodium (meth labs…volitile, must be kept under oil) Gold (jewelyry, etc)

17. Compounds Sodium chloride (salt) Arsenic and mercury (rat posion)

18. So what was happening in the lab?? Because molecules in ink and other mixtures have different characteristics (such as size and solubility), they travel at different speeds when pulled along a piece of paper by a solvent (in this case, water). For example, black ink contains several colors. When the water flows through a word written in black, the molecules of each one of the colors behave differently, resulting in a sort of “rainbow” effect.

19. Many common inks are water soluble and spread apart into the component dyes using water as a solvent. If the ink you are testing does not spread out using water, it may be “permanent” ink. In such cases, you will have to use a different solvent such as rubbing alcohol.