1. Some thoughts on long-term trends in NO 2, NO X and NO 2 :NO X ratios David Muir IAQM 1 July 2010

2. Outline. Long term trends - 199? to December 2009 Urban Background sites- London Bloomsbury, - Leeds Centre. Roadside sites - Camden Kerbside, - Bury Roadside, - Haringey Roadside, - Marylebone Road, - Bath Roadside, - Glasgow Kerbside.

3. 19931994199519961997199819992000200120022003200420052006200720082009 0 0.2 0.4 0.6 0.8 1 Ratio London Bloomsbury NO 2 :NO X Missing data

4. 199319941995199619971998199920002001200220032004200520062007200820092010 -100 0 100 200 300 400 London Bloomsbury NO 2 :NO X Missing data

5. 199319941995199619971998199920002001200220032004200520062007200820092010 -40 -30 -20 -10 0 10 London Bloomsbury NO 2 Missing data

6. 199319941995199619971998199920002001200220032004200520062007200820092010 -200 -150 -100 -50 0 50 London Bloomsbury NO X Missing data

7. 199319941995199619971998199920002001200220032004200520062007200820092010 -80 -70 -60 -50 -40 -30 -20 -10 0 10 London Bloomsbury NO Missing data

8. 19941995199619971998199920002001200220032004200520062007200820092010 -100 0 100 200 300 400 500 Leeds Centre NO 2 :NO X

9. 19941995199619971998199920002001200220032004200520062007200820092010 -60 -50 -40 -30 -20 -10 0 10 Leeds Centre NO 2

10. 19971998199920002001200220032004200520062007200820092010 -100 0 100 200 300 400 500 600 Camden Kerbside NO 2 :NO X Missing data

11. 19971998199920002001200220032004200520062007200820092010 -10 -5 0 5 10 15 Camden Kerbside NO 2 Missing data

12. 19971998199920002001200220032004200520062007200820092010 -500 -400 -300 -200 -100 0 100 Camden Kerbside NO X Missing data

13. 19971998199920002001200220032004200520062007200820092010 -100 0 100 200 300 400 500 600 700 Bury Roadside NO 2 :NO X

14. 19971998199920002001200220032004200520062007200820092010 -20 -15 -10 -5 0 5 Bury Roadside NO 2

15. 19971998199920002001200220032004200520062007200820092010 -50 -40 -30 -20 -10 0 10 Haringey Roadside NO 2

16. 1998199920002001200220032004200520062007200820092010 -20 -10 0 10 20 30 London Marylebone Road NO 2

17. 1998199920002001200220032004200520062007200820092010 -15 -10 -5 0 5 Bath Roadside NO 2

18. 1998199920002001200220032004200520062007200820092010 0 1 2 3 4 5 6 7 8 Glasgow Kerbside NO 2

19. Conclusions/Questions. 1. The NO 2 :NO X ratio increased at a number of (maybe all) urban sites between 1998 & 1999. 2. At Urban Background sites [NO 2 ] has remained steady following earlier decreases. 3. At some Roadside sites [NO 2 ] has also remained steady following earlier decreases, but…. 4. At other Roadside sites [NO 2 ] has increased since about 2003. WHY???

20. Conclusions/Questions. 5. One possibility is that the sites where no significant increase has found are further away from the road or are upwind of road. 6. Another, and more realistic possibility, is that the sites where there have been increases in [NO 2 ] are located on roads with congested, slow-moving traffic. 7. Finally, and perhaps most important, do Euro standards and emissions factors even BEGIN to address this issue?