1. Department of Synchrotron Radiation Research Lund University http://www.sljus.lu.se

2. Lund Thousand year old Danish foundation Swedish since 1658

3. Lund University Founded in 1666 Today 40,000 students

4. The Department of Synchrotron Radiation Research Division of the Institute of Physics Research staff: 3 professors, 1 associate professor, 3 assistant professors, 2 postdocs, 6 PhD-students Primary research subjects: Surface physics and chemistry (metal surfaces and their interaction with adsorbates, surface oxides, organic adsobates on metals and oxides), semiconductor nano- structures, molecular physics Primary experimental techniques: Electron (and ion) spectroscopy, scanning tunnelling microscopy and spectroscopy, low-energy electron and x-ray diffraction, photoemission and low-energy electron microscopy

5. Swedish national synchrotron radiation facility MAX-lab

6. What kind of information can we obtain?

7. Geometric information I: Scanning tunnelling microscopy

8. Geometric information II: X-ray/electron diffraction O/Ag(111) – p(4x4) Schmid et al., PRL 96 (2006) 146102

9. Geometric information III: Photoelectron spectroscopy Ethylidyne (CH3CH) on Rh(111) The photoelectron diffraction shows that the molecule stands upright on the surface! Normal emission

10. Geometric information IV: X-ray absorption spectroscopy Dipole approximation:  l=1, e.g. 1s -> xp The absorption intensity depends on the orientation of the orbitals!

11. Geometric information V: LEEM/PEEM Sample on manipulator Sample at -5 to -30 kV Objective lens Contrast aperture Field aperture Stigmator, deflector Intermediate lens Projective lens Multichannel plate YAG-screen CCD camera Image plane Intermediate image plane Photons / Electrons Synchrotron radiation (XPEEM) UV lamp Mercury lamp, etc Electron gun PEEM pictures of pentacene on Si 1 layer2 layers3 layers

12. Chemical information I: PES From http://www-group.slac.stanford.edu/sms/xrayspectroscopy.html

13. Chemical information II: PES Rh(553) without and with oxygen

14. Electronic information: PES, XAS, STS C 60 / Al(111) Johansson et al., PRB 54 (1996) 13472

15. Reaction studies: PES 2x1 Chemisorbed O 9x9 Oxide Reduction of oxygen overlayers on Rh(111) by CO

16. Electron femtosecond dynamics: RPES

17. Future plans I High-pressure x-ray photoelectron spectroscopy instrument at MAX-lab (clearly within MONET lifetime, 1 to 2 years from now): ultimate goal maximum pressure around 25 Torr (achievable?), in situ combination of UHV and high pressure experiment Instrument development:

18. Future plans II Experiments in the near future: Comparitive STM study of large molecule deposition techniques: Nottingham spray deposition in situ passivation and ex situ molecule exchange in situ liquid droplet deposition using a pulse valve Deposition of carboxylated and non-carboxylated cyclodextrins Interaction of iron phthalocyanines/graphite with water (UHV) Organometallic architectures: L-cysteine and Au on TiO 2

19. Future plans III Projecs in the long run Metal-nitrogen complex architectures and their interaction with gases In situ study of the interaction of organic molecules with water