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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Reviewing the Periodic Table Regions Representative elements: Groups 1A - 8A - filling s and p orbitals. Transition elements: Center of the table - filling d orbitals Lanthanides, Actinides: listed separately, on the bottom of the table - filling 4f and 5f Metalloids: separate metals from nonmetals
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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 2 Metallurgy... the process of obtaining a metal from its ore. This always involves reduction of the ions to the elemental metal (oxidation state = 0).
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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 3 Group 1A Oxides In the presence of ample oxygen, 4Li + O 2 2Li 2 O 2Na + O 2 Na 2 O 2 K + O 2 KO 2 Rb + O 2 RbO 2 Cs + O 2 CsO 2
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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 4 Hydrides... are binary compounds containing hydrogen. ionic hydrides: hydrogen + the most active metals (eg; LiH, CaH 2 ) covalent hydrides: hydrogen + other nonmetals (eg; H 2 O, CH 4, NH 3 ) metallic (interstitial) hydrides: transition metal crystals treated with H 2 gas.
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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 5 Ion Exchange Ca 2+ and Mg 2+ are often removed during ion exchange, releasing Na + into solution. Ion exchange resin: large molecules that have many ionic sites.
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Copyright©2000 by Houghton Mifflin Company. All rights reserved. 6 Inert Pair Effect The tendency for the heavier elements of Groups 3A and 4A to exhibit lower oxidation states as well as their expected oxidation states. Group 3A +1 and +3 oxidation states Group 4A +2 and +4 oxidation states
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