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Water Solutions of Acids Universal Indicator is yellow Turn phenolphthalein colorless Turn litmus paper red React with metals to give off hydrogen gas.

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Presentation on theme: "Water Solutions of Acids Universal Indicator is yellow Turn phenolphthalein colorless Turn litmus paper red React with metals to give off hydrogen gas."— Presentation transcript:

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3 Water Solutions of Acids Universal Indicator is yellow Turn phenolphthalein colorless Turn litmus paper red React with metals to give off hydrogen gas Taste Sour

4 Water Solutions of Bases Taste bitter and feel slippery Do not react with metals Conduct electricity Turn litmus paper blue Turn phenolphthalein pink Universal Indicator is blue

5 Svante Arrhenius

6 Svante Arrhenius: Acids form hydronium ions in water while bases form hydroxide ions. Hydronium ions: [H 3 O + ] (H + combined with H 2 O) Hydroxide ions: [OH  ]

7 Hydronium Ion

8 Water Molecule O H H

9 Hydronium Ion O H H H +   + + + H3OH3O

10 Water Molecules Hydronium Ion

11 Water polarity

12 Water Molecule Oxygen Hydrogen     +

13 Water Water Molecule Oxygen Atom Hydrogen Atom     +

14    H H O

15 Hydrogen Bond Hydrogen Bonding

16 Hydrogen Bonding H 2 O

17 Water Molecules Hydronium Ion           +    +

18 NO 3  Nitric Acid in water HNO 3 + H 2 O  NO 3  + H 3 O + H3O+H3O+

19 Svante Arrhenius: Acids form hydronium ions in water while bases form Hydronium ions: [H 3 O + ] (H + combined with H 2 O) Hydroxide ions: [OH  ] hydroxide ions

20 Hydroxide Ion O H   +  OH

21 OH  Sodium Hydroxide in water NaOH + H 2 O  Na + + OH  + H 2 O Na +

22 Hydrated Al +3 H2OH2O H2OH2O H2OH2O H2OH2O H2OH2O H2OH2O

23 Strong Acid Weak Acid Neutral Strong Base Weak Base

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25 O O O O S HH

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27 O O O N H

28 O O O N  NO 3  Nitrate Ion

29 Cu + 4 HNO 3  Cu(NO 3 ) 2 + 2 NO 2  + 2 H 2 O

30 The brown gas is NO 2

31 The green material is Cu(NO 3 ) 2

32 Nitric Acid is an oxidizing acid

33 Acid and Base Strength Acid strength depends on the number of hydronium ions formed per mole of acid. HNO 3 is a strong acid and HF is a weak acid. The ionization of hydrofluoric is more reversible the HNO 3 ionization. HF + H 2 O F  + H 3 O + HNO 3 + H 2 O NO 3  + H 3 O + reversible

34 Hydronium Ion Nitrate Ion 100 % Ionized Strong Acid HNO 3

35 Fluoride Ion HF Hydronium Ion Weak Acid HF Reversible

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37 Cl H

38 100 % Ionized Strong Acid

39 100 % Ionized Strong Acid

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42 O O C H Bond

43 O O C C H H H H CH 3 COOH

44 Acid and Base Strength Acid strength depends on the number of hydronium ions formed per mole of acid. HCl is a strong acid and acetic acid is a weak acid. The ionization of acetic acid is more reversible the HCl ionization. CH 3 COOH + H 2 O CH 3 COO  + H 3 O + HCl + H 2 O Cl  + H 3 O + weak acid strong acid

45 Iodide Ion Hydronium Ion 100 % ionization Strong Acid HI

46 100 % ionization Strong Base

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48 Johannes Brønsted

49 Johannes Brønsted: Definition based on what happens during an acid base reaction and is not limited to aqueous solutions. Brønsted Base A substance that accepts an H + ion (proton) from another substance Brønsted Acid A substance that donates an H + ion (proton) to another substance

50 Acid – A substance that produces hydrogen ions in water solution. HCl  H + + Cl  Acids and Bases Base – A substance that produces hydroxide ions in water solution. NaOH  Na + + OH  An acid is a proton donor. A base is a proton acceptor. Brønsted states 

51 Conjugate Acid – A particle obtained after a base has gained a proton. Conjugate Base – A particle remaining after an acid has donated a proton. Conjugate Acid and Conjugate Base Brønsted Used The Acid-Base Reaction To Define The

52 NH 3 + HCl  NH 4 + + Cl  Conjugate Acid and Conjugate Base Base Can Accept a Proton Acid Can Donate a Proton Conjugate Acid Has Accepted A Proton Conjugate Base Has Donated A Proton The Proton Is Gone !

53 Conjugate Acid and Conjugate Base Acid Conjugate Acid Base Conjugate Base HNO 3 + H 2 O  H 3 O + + NO 3 

54 HCN + SO 4  2  HSO 4  + CN  Conjugate Acid and Conjugate Base Acid Conjugate Acid Base Conjugate Base

55 Base Acid Conjugate Acid Conjugate Base

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