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Published byCorey Henderson Modified over 9 years ago
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Water Solutions of Acids Universal Indicator is yellow Turn phenolphthalein colorless Turn litmus paper red React with metals to give off hydrogen gas Taste Sour
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Water Solutions of Bases Taste bitter and feel slippery Do not react with metals Conduct electricity Turn litmus paper blue Turn phenolphthalein pink Universal Indicator is blue
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Svante Arrhenius
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Svante Arrhenius: Acids form hydronium ions in water while bases form hydroxide ions. Hydronium ions: [H 3 O + ] (H + combined with H 2 O) Hydroxide ions: [OH ]
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Hydronium Ion
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Water Molecule O H H
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Hydronium Ion O H H H + + + + H3OH3O
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Water Molecules Hydronium Ion
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Water polarity
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Water Molecule Oxygen Hydrogen +
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Water Water Molecule Oxygen Atom Hydrogen Atom +
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H H O
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Hydrogen Bond Hydrogen Bonding
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Hydrogen Bonding H 2 O
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Water Molecules Hydronium Ion + +
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NO 3 Nitric Acid in water HNO 3 + H 2 O NO 3 + H 3 O + H3O+H3O+
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Svante Arrhenius: Acids form hydronium ions in water while bases form Hydronium ions: [H 3 O + ] (H + combined with H 2 O) Hydroxide ions: [OH ] hydroxide ions
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Hydroxide Ion O H + OH
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OH Sodium Hydroxide in water NaOH + H 2 O Na + + OH + H 2 O Na +
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Hydrated Al +3 H2OH2O H2OH2O H2OH2O H2OH2O H2OH2O H2OH2O
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Strong Acid Weak Acid Neutral Strong Base Weak Base
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O O O O S HH
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O O O N H
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O O O N NO 3 Nitrate Ion
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Cu + 4 HNO 3 Cu(NO 3 ) 2 + 2 NO 2 + 2 H 2 O
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The brown gas is NO 2
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The green material is Cu(NO 3 ) 2
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Nitric Acid is an oxidizing acid
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Acid and Base Strength Acid strength depends on the number of hydronium ions formed per mole of acid. HNO 3 is a strong acid and HF is a weak acid. The ionization of hydrofluoric is more reversible the HNO 3 ionization. HF + H 2 O F + H 3 O + HNO 3 + H 2 O NO 3 + H 3 O + reversible
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Hydronium Ion Nitrate Ion 100 % Ionized Strong Acid HNO 3
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Fluoride Ion HF Hydronium Ion Weak Acid HF Reversible
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Cl H
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100 % Ionized Strong Acid
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100 % Ionized Strong Acid
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O O C H Bond
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O O C C H H H H CH 3 COOH
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Acid and Base Strength Acid strength depends on the number of hydronium ions formed per mole of acid. HCl is a strong acid and acetic acid is a weak acid. The ionization of acetic acid is more reversible the HCl ionization. CH 3 COOH + H 2 O CH 3 COO + H 3 O + HCl + H 2 O Cl + H 3 O + weak acid strong acid
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Iodide Ion Hydronium Ion 100 % ionization Strong Acid HI
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100 % ionization Strong Base
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Johannes Brønsted
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Johannes Brønsted: Definition based on what happens during an acid base reaction and is not limited to aqueous solutions. Brønsted Base A substance that accepts an H + ion (proton) from another substance Brønsted Acid A substance that donates an H + ion (proton) to another substance
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Acid – A substance that produces hydrogen ions in water solution. HCl H + + Cl Acids and Bases Base – A substance that produces hydroxide ions in water solution. NaOH Na + + OH An acid is a proton donor. A base is a proton acceptor. Brønsted states
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Conjugate Acid – A particle obtained after a base has gained a proton. Conjugate Base – A particle remaining after an acid has donated a proton. Conjugate Acid and Conjugate Base Brønsted Used The Acid-Base Reaction To Define The
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NH 3 + HCl NH 4 + + Cl Conjugate Acid and Conjugate Base Base Can Accept a Proton Acid Can Donate a Proton Conjugate Acid Has Accepted A Proton Conjugate Base Has Donated A Proton The Proton Is Gone !
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Conjugate Acid and Conjugate Base Acid Conjugate Acid Base Conjugate Base HNO 3 + H 2 O H 3 O + + NO 3
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HCN + SO 4 2 HSO 4 + CN Conjugate Acid and Conjugate Base Acid Conjugate Acid Base Conjugate Base
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Base Acid Conjugate Acid Conjugate Base
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