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Photonics Activities within Solid State Lab
a) Sensors for Biomedical Applications b) Electroluminescence of FeSi2 in Si c) Polymer Light Emitting Diodes Department of Electronic Engineering The Chinese University of Hong Kong
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Academic units & industrial partners in support of photonic sensor R&D in CUHK
EE – optoelectronics, guided-wave devices, biomedical electronics, signal processing, device fabrication Biochemistry and Medicine – application area identification, supporting facilities, biomolecule selection, bio-material supply, field trials Photonic Sensor R&D ACAE – Centre for Micro and Nano Systems, MEMS, micro-fluidics, device modeling Physics – laser optics, optical diagnostic facilities, novel materials E-Care Company Ltd. (wireless healthcare devices) Automatic Mfg. Ltd. (high volume device manufacturing) Photonics Instruments (equipment R&D) Hong Kong Healthcare Services Ltd. (sales and marketing) Hong Kong Health Digit Co. Ltd. (diagnostic equipment) Chan & Hau Medical Laboratories (medical services) Industrial Partners
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Micro-Photonic Sensors for Biomedical Applications
CUHK’s photonics technologies and techniques Surface Plasmon Resonance, Integrated Optics (Prof. Aaron Ho, EE) Optical Fibre Phosphorescence (Prof. Dennis Lo, Phys) Biomolecules to be detected Application Examples: Health care diagnostics Environmental monitoring Food and drink industries Drug R&D Agriculture Antigen/antibody Oxygen Toxins Carcinogens body fluids/blood/urine DNA, genomic fingerprints Virus, cells, bacteria Pollutants Food ingredients 1 1
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Surface Plasmon Resonance Biosensors
Metal q k sp Surface Plasmon Wave Lowest Reflectivity
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Differential Phase SPR Sensor
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Biomolecule detection response curve
-50 50 100 150 200 250 300 350 400 450 3.7ug/ml 37ug/ml 110ug/ml BSA Antibody into flow cell =>specific binding PBS Non-BSA Antibody Into flow cell =>No binding differential phase (degrees) time (sec.) Reaction curve of BSA (bovine serum albumin) with non-BSA antibody with different concentrations of BSA antibody
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Sensitivity limit of our SPR system
Phase change caused by varying concentration of glycerin/water mixture (Au surface) 20 40 60 80 100 120 140 160 2 4 6 8 10 Concentration of glycerin (%) Relative phase change (degree) Time (min) glycerin (%) refractive index Relative phase change (°) 1.3330 0.25 1.3333 21.75 0.5 1.3336 32.59 1 1.3342 57.53 2 1.3353 89.32 4 1.3400 112.59 8 1.3424 135.69 Sensitivity limit of our system: Au surface: 1.38 x 10-7 RIU (Refractive Index Unit) Au/Ag surface: 5.48 x 10-8 RIU
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Sensitivity Comparison Between Systems
Sensing Principle BIAcore 3000 (prism-based SPR) IBIS (vibrating mirror SPR) Plasmoon (broad-range SPR) SPREETA (prism-based SPR) IASys (resonant mirror) Refractive index range - Limit of detection (RIU) *3 × 10-7 2 × 10-6 6 × 10-6 3 × 10-7 >1 × 10-6 Sensitivity limit of our system: Au surface: 1.38 x 10-7 RIU (Refractive Index Unit) Au/Ag surface: 5.48 x 10-8 RIU
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Structural and optical properties of FeSi2 nano-crystal embedded in Si synthesized by MEVVA implantation PL spectra measured at 80K for two samples with different strain states. A simple structure of LED device containing FeSi2 nano-crystal 0.7 0.8 0.9 1.0 1.1 1.2 5000 10000 15000 20000 PL Intensity ( m w) Photo energy (eV) High strain low strain 2μm FZ n-Si 0.5μm 2 nm + - bias+ FeSi2 p+ Si SiO2 ITO Al
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Application of Low Level Birefringence Detection System for Stress Measurement in Semiconductor Materials and Structures Photoelasticity (PE) method for stress analysis By measuring the change in the state of polarization of light after passing through the sample, information on the stresses in the sample can be obtained Low Level Birefringence Detection (LLBD) system A high sensitive PE technique by using Photoelastic Modulation technique. The sensitivity of current LLBD system is: 0.02º
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Distribution of residual stress in the 2- inch bare (100) GaAs wafer
Application of Low Level Birefringence Detection System for Stress Measurement in Semiconductor Materials and Structures tS iO2= 1.3 m tSi = 380 m SiO2 x Distribution of residual stress in the 2- inch bare (100) GaAs wafer (11 0) Unit: 107 dyne/cm2 Si y Plot of distribution of stress induced birefringence in silicon substrate under SiO2 film edge
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OLED project team members
Project Director: Prof. K. Y. Wong Dept. of Physics Prof. H. F. Chow Dept. of Chemistry Prof. S. K. Hark Dept. of Physics Prof. W. M. Lau Dept. of Physics Prof. H. C. Ong Dept. of Physics Dr. K. W. Wong Dept. of Physics Prof. S. P. Wong Dept. of Electronic Engineering Prof. J. B. Xu Dept. of Electronic Engineering
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CUHK’s areas of interest in PLED
Comprehensive in-house material characterization facilities (Physics and EE Depts.) to conduct research on: a) Interface characterization and engineering b) Degradation mechanisms and improvement Development of new materials (Chemistry Dept.) Device fabrication and technology transfer through collaboration with industry (Varitronix) and other local institutions (HKUST, HKBU) ITF project in collaboration with Varitronix Ltd. (HK $ 4M)
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Existing facility for PLED preparation and characterization
XPS, Auger, STM/AFM, SEM, TEM/EELS
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“Green” PLED cell based
PLEDs fabricated “Green” PLED cell based on PFO co-polymer from DOW Chemicals “Blue” PLED cell based on PFO from Prof. H. F. Chow
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END Our team is composed of Prof. Wilson whose expertise is on ion implantation and ion beam analysis, Prof. Wong whose expertise is on ion implantation and thin film technology, for myself my expertise is on scanning probe microscopy and its applications to thin films and devices. Also there are about 5 research staff and 10 postgraduates constantly.
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