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Module A-4 Molecular Electronics
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Bohr Atomic Model
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Hydrogen Emission Spectra Principal Quantum Number
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Principal Quantum Numbers Orbital Quantum Number l = 0 to l = (n–1)
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Quantum Energy States
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Principal Quantum Numbers
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Molecular Orbital Considerations H H-H H-H-H H-H-H-H (1s electrons) Li Li-Li Li-Li-Li Li-Li-Li-Li (2s electrons) (Li–Li = 2.67 A, H–H = 0.75 A)
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Molecular -Bonding and * Bonding States
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bonds Electrons in chemical bonds ( e.g. H-H and C-H bonds) are generally quite localized and non-co nducting. These bonds are bonds.Electrons in chemical bonds ( e.g. H-H and C-H bonds) are generally quite localized and non-co nducting. These bonds are bonds.
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Alkyl Chains and Aliphatic molecular Insulators type orbits lie in the molecular plane and are insulating
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Formulation of Large Molecular Chains
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Formation of Energy Bands from Constituent Atoms
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Energy Bands for metals, semiconductors and Insulators
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Bandgap vs. Chain Length Poly(thiophene)
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Saturation Effect All properties approach a saturation value.
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Bandgap vs. conjugation length Increased conjugation length smaller bandgap
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Genesis of Nanotechnology 00 Chemistry 96 Chemistry 86 Physics 56 Physics 97 chemistry (Mitre 96)
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Single Electron Transistors
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Molecular Break junction SET
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STM in Molecular Electronic Research Semiconducting
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