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Astrophysics Yr 2 Session 6 Astronomical Spectroscopy
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Types of spectra
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The spectral sequence for stars… …a temperature sequence.
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Z Andromedae spectrum
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The Orion Nebula & its spectrum
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Stellar spectra with calibration spectra. Measuring spectral line wavelengths
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The Doppler effect
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Energy levels in atoms Principal quantum number n Angular momentum quantum no. l l = 0,1,2,…n-1
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Energy levels in atoms = 0,+1/-1, +2/-2 …+l/-l. Magnetic quantum number m Spin quantum number s = +½ or -½ Spin up Spin down Pauli Exclusion Principle: n, l, m, s unique to each electron in an atom. For given n: All l, m,s sublevels full → Closed shell = 2n 2 electrons
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Energy of an energy level Convention
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Energy of an energy level
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Electron transitions
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Excitation & ionisation Collisional/thermal – close encounters with other atoms or free electrons Photo ionisation/excitation – absorption of photon. For excitation photon energy = energy level difference. For ionisation photon energy> energy of level. Opposite processes – de-excitation & recombination.
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Ionisation terminology A HII region
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Selection rules for transitions q.m. – conservation of angular momentum l quantum number must change by +/-1 s must not change Rules obeyed → permitted transition Rules broken → forbidden transition
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Spectral series e.g. Balmer series - hydrogen
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Sodium (& alkali metals) n = 1, 2; closed shells Spectrum produced by n = 3 electron; Transitions involve n = 4, 5 etc. E +½ - E -½ 6Å
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Sodium term diagram 5889 5895
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Complex atoms E.g. Helium; 2 electrons → 2 possibilities. 1.One electron stays in n = 1 level. Transitions involve only 2 nd electron & higher levels; → Helium singlet series. 2.Both electrons in higher levels; both take part in transitions; → Helium triplet series.
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L-S Coupling Electric & spin magnetic fields of electrons interact Greater interaction for higher l values. Spin combinations can enhance, diminish or have no net effect on levels. e.g. two electrons → 3 possibilities – Triplet series.
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Line profiles A spectral line is produced by a vast population of atoms
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Saturated lines
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Line strength – equivalent width
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Line broadening mechanisms
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Natural broadening Heisenberg Uncertainty Principle; E t ħ – levels are fuzzy
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Naturally broadened (Lorentz) profile t shorter for higher levels → E larger → line broader
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Thermal broadening Distribution of radial velocities; Normal or Gaussian v Dop = standard deviation or variance of radial velocity In terms of wavelength (see notes): Dop = stdv of wavelength distribution. = - 0
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Real spectrum; Measure full width of line profile at half peak intensity; Full Width Half Maximum; FWHM At line centre (max/min intensity for emission/absorption line) At ½ max/min intensity i.e. f(0) f(½)FWHM
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Take natural log of both sides:
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Synthetic thermally broadened H line
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Pressure broadening Can distinguish between giant & dwarf stars
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Gas motions; e.g. accretion disc
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Symbiotic star RX Persei H line
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P Cygni
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The Balmer Jump HI ionisation energy from n = 2 level = 3.4eV. → 3647
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Molecular spectra
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A Planetary nebula 1 light year
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Stellar remnant NGC7207 & its spectrum Forbidden lines due to doubly ionised oxygen
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Next time: Stellar structure & energy sources
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