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Acids Lesson 1 Acid and Base Properties
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Taste sour Change litmus paper red React with metals such as Mg and Zn to make H 2 Are electrolytes that conduct electricity Neutralize bases Properties of Acids
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Taste bitter Change litmus paper blue Feel slippery Are electrolytes that conduct electricity Neutralize acids Properties of Bases
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Arrhenius acid HCl Arrhenius base NaOH Na + + OH - H + + Cl - produces H + in solutionChemistry 11 produces OH - in solutionChemistry 11
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H+H+ Bronsted Acid H+H+ HCl + H 2 O Bronsted Base NH 3 + H 2 O ⇄ A proton donor A proton acceptor Chemistry 12 H 3 O + + Cl - NH 4 + + OH - weak strong
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H+H+ H+H+ Write a Bronsted reaction for the base HCO 3 - base acid base HCO 3 - ⇄ H 2 CO 3 + OH - + H 2 O weak Conjugate acid base pairs differ by one proton H + HCO 3 - and H 2 CO 3 H 2 O and OH -
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5. H + is the same as H 3 O + 4. Bronsted acids donate a proton to water to form H 3 O + 3. Arrhenius acids dissociate in water to form H + 2. Bronsted bases accept a proton from water to produce OH - 1. Arrhenius bases dissociate in water to produce OH - Note
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H + is another way to show H 3 O +. Hydronium ion H3O+H3O+ H + + H 2 O ⇋ + H+H+ H2OH2O
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NH 4 + NH 3 Fe(H 2 O) 6 3+ OH - HCO 3 - HPO 4 2- PO 4 3- HPO 4 2- H 2 PO 4 - H 2 CO 3 H2OH2O One more H + 1 less H + Conjugate BaseConjugate Acid C 6 H 5 COOHC 6 H 5 COO - C 6 H 5 OHC6H5O-C6H5O- Fe(H 2 O) 5 (OH) 2+ Look on page 6
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Strong Acids Weak Acids
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HCl + H 2 O H 3 O + + Cl - Use a “ ” and not “ ⇄ ” Have very large Ka’s. Produce large amounts of H 3 O +. Are good conductors. Completely ionize in water Left side Acid Chart top six Strong Acids
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Weak Acids Left side of the Acid Chart below the top six. Do not completely ionize in water. Are poor conductors. Produce small amounts of H 3 O +. Have small Ka’s. Use a “ ⇄ ” and not “ ” HF + H 2 O ⇄ H 3 O + + F - Ka=[H 3 O + ][F - ] =3.5 x 10 -4 from page 6 [HF] Water is not included because it is a pure liquid! Its concentration is constant !
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You can also write: HF ⇌ H + + F - Ka= [H + ][F - ] =3.5 x 10 -4 [HF]
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HF + OH - F - + H 2 O (l) HF + K + + OH - K + + F - + H 2 O (l) HF + KOH KF+H 2 O (l) Do not break up weak acids or bases! H + + OH - H 2 O (l) H + + Cl - + Na + + OH - Na + + Cl - + H 2 O (l) HCl + NaOH NaCl+H 2 O (l) Writing Ionic Equations: Formula, Complete, and Net. HF is a weak acid
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