1. King Abdulaziz University Chemical and Materials Engineering Department Chapter 2 ATOMIC STRUCTURE AND INTERATOMIC BONDING Session I

2. King Abdulaziz University Chemical and Materials Engineering Department Atomic Structure (Fundamental Concepts)  Atoms = nucleus (protons and neutrons) + electrons  Charges: Electrons and protons have negative and positive charges of the same magnitude, 1.6 × 10 -19 C. Neutrons are electrically neutral.  Masses: Protons and Neutrons have the same mass, 1.67 × 10 -27 kg. Mass of an electron is much smaller, 9.11 × 10 -31 kg and can be neglected in calculation of atomic mass.  # protons gives chemical identification of the element  # protons = atomic number (Z)  # neutrons defines isotope number  The atomic mass (A) = mass of protons + mass of neutrons

3. King Abdulaziz University Chemical and Materials Engineering Department  The atomic mass unit (amu) is often used to express atomic weight. 1 amu is defined as 1/12 of the atomic mass of the most common isotope of carbon atom that has 6 protons (Z = 6) and six neutrons (N = 6). M proton ≈ M neutron = 1.66 x 10 -24 g = 1 amu. The atomic mass of the 12 C atom is 12 amu.  The atomic weight of an element = weighted average of the atomic masses of the atoms naturally occurring isotopes. Atomic weight of carbon is 12.011 amu.

4. King Abdulaziz University Chemical and Materials Engineering Department  A mole is the amount of matter that has a mass in grams equal to the atomic mass in amu of the atoms (A mole of carbon has a mass of 12 grams).  The number of atoms in a mole is called the Avogadro’s number, N av = 6.023 × 10 23. N av = 1 gram/1 amu. e.g. Atomic weight of iron = 55.85 amu/atom = 55.85 g/mol

5. King Abdulaziz University Chemical and Materials Engineering Department Electrons in Atoms (atomic models) Quantum Mechanics: Understanding the behavior of electrons in atoms and crystalline solids. Bohr Atomic Model: Electrons are assumed to revolve around the atomic nucleus in discrete orbitals. Position of any particular electron is more or less well defined in terms of its orbital

6. King Abdulaziz University Chemical and Materials Engineering Department Wave-mechanical model  Electron exhibits both wavelike and particle-like behavior.  Electron no longer considered as moving in a discrete orbital, rather, position is considered to be the probability of an electron is being at various locations around the nucleus. Bohr Wave-mechanical

7. King Abdulaziz University Chemical and Materials Engineering Department Quantum numbers Size ShapeNumber of energy states Principal quantum number (n) Second quantum number (l) Third quantum number (m l ) Fourth quantum number (m s ) Spatial Orientation

8. King Abdulaziz University Chemical and Materials Engineering Department Relative energy representation of the electrons for the various shells and subshells Schematic representation of the filled and lowest unfilled energy states for a Sodium atom

9. King Abdulaziz University Chemical and Materials Engineering Department Electronic Configuration Pauli exclusion principle  Each electron state can hold no more than two electrons, which must have opposite spins.  s, p, d, and f subshells may each accommodate total of 2,6,10,and 14 electrons.

10. King Abdulaziz University Chemical and Materials Engineering Department Periodic Table

11. King Abdulaziz University Chemical and Materials Engineering Department  Elements in the same column (Elemental Group) share similar properties. Group number indicates the number of electrons available for bonding.  0: Inert gases (He, Ne, Ar...) have filled subshells: chem. Inactive  IA: Alkali metals (Li, Na, K…) have one electron in outermost occupied s subshell - eager to give up electron – chem. Active  VIIA: Halogens (F, Cl,Br...) missing one electron in outermost occupied p shell - want to gain electron - chem. Active.

12. King Abdulaziz University Chemical and Materials Engineering Department Electronegativity

13. King Abdulaziz University Chemical and Materials Engineering Department  Electronegativity - a measure of how willing atoms are to accept electrons.  Subshells with one electron – low electro negativity.  Subshells with one missing electron–high electro negativity.  Electronegativity increases from left to right.  Metals are electropositive – they can give up their few valence electrons to become positively charged ions.