1. CE 401 Climate Change Science and Engineering aerosols, carbon cycle 31 January 2012

2.  on Thursday, class will be held in Sloan 242b – bring flash drive and be sure you can log in via a CEE login HW 4 is due today HW 5 is posted on the web – due Tuesday 2/7/2012

3. team assignments for CE 401 for Thursday approved choice of paper due 21 February

4. any questions from last time? radiative forcing, aerosols (will finish today)

5. aerosols: physical properties interactions with the atmosphere – direct/indirect shapes and the models optical depth aerosol distributions types of aerosols and lifetimes

6. aerosols: solid particles or liquid particles suspended in the air size: few nanometers to microns in size: x100 - 1000 variation in size have major impacts on climate physical properties: shape, size, chemical composition particles at the small end play a large role in cloud physics condensation nuclei for clouds EPA regulates particles in the US PM10 and PM2.5 – CEE 341, 415 key aerosol groups: sulfates organic carbon black carbon nitrates mineral dust sea salt aerosols of clump together to form complex mixtures 90% of aerosols (by mass) are natural in origin about 10% of global aerosols are generated by human activity problems in dealing with aerosol effect: diversity in size, composition and origin; spatial and temporal variability; source; injection height aerosols removed primarily through cloud processing and wet and dry deposition

7. aerosol RF effects are categorized into direct and indirect effects: direct: mechanism by which aerosols directly scatter and absorb radiation  change in the radiative balance of the Earth system organic carbon, sulphate, nitrate, black carbon, dust, biomass burning indirect: mechanism by which aerosols modify the microphysical and hence the radiative properties, amount, and lifetimes of clouds size, shape, chemical composition, etc.

8. volcanic pollensea saltsoot fossil fuel combustion  SO 2 which reacts with H 2 O and gases to  sulfate aerosols biomass burning  organic carbon and black carbon transportation sector  prolific producer of aerosols aerosols are usually modeled as spherical in shape – do they look spherical?????? properties: shape, size, composition, chemistry, polarization, index of refraction, mass,

9. - aerosol optical depth is the fundamental measure of quantity and distribution of aerosols - absorbance is proportional to exp{-  } where  is the optical depth. AOD is a measure of incident light scattered or absorbed.   is prop to path length and extinction cross section 2003-2006 average AOD

10. global aerosol distribution. Yellow = coarse particles like dust, red = fine particles like smoke or air pollution. How do you compute light attenuation at a location from this picture??? MODIS data

13. MODIS 9 Oct 2010

14. average tropospheric aerosol lifetime at a week or less  can travel 1000’s of km

15. indirect effects of aerosols: cloud formation and cooling aerosols play a critical role in cloud formation natural aerosols are most important but human produced aerosols have a significant impact ship tracks – white clouds and map of cloud droplet size  where ship exhaust is mixed with cloud layer, droplets are smaller

16. measurements of aerosols from satellites and networks of instruments AERONET

17. NASA Global Hawk at Edwards AFB, CA you guys ought to get involved in atmospheric studies – it is one heck of a lot of fun!

18. outstanding issues in aerosol effects on climate change: composition optical absorption impacts on surface radiation and heating long term trends total RF

19. global carbon cycle importance carbon dioxide and methane how much remains in the atmosphere carbon exchange – the cycle – reservoirs and fluxes emissions

20. over millions of years, CO 2 is removed from the atmosphere through weathering of rocks and through burial in marine sediments of carbon fixed by marine plants burning fossil fuels returns carbon captured by plants in geologic history to the atmosphere current levels of CO 2 are nearly 50% higher than in the past 700k yrs during glacial periods, CO 2 removed from the atmosphere was stored in the oceans CO 2 prior to 1750 was about 280 ppm and had been stable for ~ 10k yrs since 1750 the amount of CO 2 in the atmosphere has increased ~ 40% from human activities fossil fuel combustion deforestation land use change biomass burning crop production conversion of grasslands to croplands

21. CO 2 and CH 4

22. CO 2 and CH 4 play major roles in the natural cycle of carbon large flows of carbon among the ocean, terrestrial biosphere and atmosphere stable for past 10k yrs terrestrial plants capture CO 2 from the atmosphere photosynthesis plant, soil, and animal respiration  carbon to atmosphere CO 2 is continuously exchanged between atmosphere and ocean CO 2 entering ocean waters  bicarbonate (HCO 3 - ) and carbonate (CO 3 2- ) ions residence time of dissolved inorganic carbon in surface ~ 10 yrs intermediate depths circulate on decades to centuries time scale abyssal depths mix on millennial time scales what are the fluxes of carbon between the atmosphere, biosphere, hydrosphere

23. HW 2 – change in annual CO2 in the atmosphere

26. source: IPCC 2007 The Climate System - very complicated

27. www.globalcarbonproject.org

35. compare these two figures  some idea of the errors involved in the fluxescompare these two figures  some idea of the errors involved in the fluxes