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Potassium formate brine has been produced by Addcon in Norway since 1994 Production Site ADDCON NORDIC AS Storage tanks for raw materials
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Potassium formate production by Addcon The first and largest producer of potassium formate - Brine production capacity : 800,000 bbl/year - Non-caking powder capacity: 8,400 MT/year Direct production from HCOOH and KOH High purity product Large stocks on quayside location Fast service – by truck, rail and sea Supplier to the oil industry since 1994 50 % KOH 4,500 m 3 6,300 MT 94 % Formic acid 5,000 m 3 Feedstock storage tanks in Norway
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Cesium formate produced by Cabot in Canada from pollucite ore Pollucite ore Cs 0.7 Na 0.2 Rb 0.04 Al 0.9 Si 2.1 O 6 ·(H 2 0) Mined at Bernic Lake, Manitoba Processed on site to Cs formate brine Cs formate brine production 700 bbl/month
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Potassium formate brine has been used to drill deep HPHT gas wells since 1995 First use : ExxonMobil’s Walsrode field, onshore northern Germany - high-angle deep HPHT slim hole low perm gas wells TVD : 4,450-5,547 metres Reservoir: Sandstone 0.1-125 mD BHST : 157 o C Section length: 345-650 m Drilling fluid: SG 1.45-1.55 K formate brine
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Potassium formate from Addcon used in 15 deep HPHT gas well constructions in Germany,1995-99 Well NameApplicationFluid TypeDensity s.g. (ppg) Horizontal Length(m) Angle (°)BHST (°F)BHCT (°F)TVD (metres)MD (metres) Permeability (mD) Walsrode Z5W/CK Formate1.55 (12.93)34526315na4450 - 46324815 - 51510.1 - 125 mD Wasrode Z6W/CK Formate1.55 (12.93)42040315na4450 - 46324815 - 51510.1 - 125 mD Walsrode Z7Drill-InK Formate1.53 (12.77)690593152954541 - 47775136 - 55470.1 - 125 mD Söhlingen Z3ADrill-InFormix1.38 (11.52)8558930027049085600na Söhlingen Z3aDrill-InNa Formate1.30 (10.85)8558930027049085600na Volkersen Z3W/CFormix1.40 (11.68)51252320na Kalle S108Drill-InFormix1.45 (12.10)43160220na6000-65006200-6600na Weißenmoor Z1W/CFormix1.35 (11.27)63431300na Idsingen Z1aDrill-InK Formate1.55 (12.93)645613212904632 - 48005257 - 5821 0.1 - 125 mD Söhlingen Z12Drill-In Na Formate/Formix 1.35 (11.27)452283132854736 - 49374846 - 51661.0 - 75 mD Simonswolde Z1Drill-InK Formate/Formix1.52 (12.68)567352932754267 - 45724236 - 46480.1 - 25 mD Walsrode NZ1Drill-InFormix1.51 (12.60)460342902654632 - 48154541 - 46930.1 - 125 mD Idzingen Z2W/CFormix1.40 (11.68)na 320na4632 - 48005257 - 58210.1 - 125 mD Voelkersen NZ2W/CFormix1.40 (11.680na 320na Söhlingen Z13Drill-In/FracK Formate/Formix1.30 (-1.56)(10.85)12009030028547245486 - 64000,1 - 150 mD Fluids service provided by M-I and Baroid
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Summary of potassium formate brine use in HPHT gas wells in Germany,1995-99
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Formate brines – Some further important milestones : 1999-2004 199920002001200220032004 First production of non-caking crystalline K formate by Addcon First drilling jobs with K/Cs formate brine: Huldra and Devenick HPHT Formate brines used as packer fluids for HPHT wells in GOM. First well : ExxonMobil’s MO 822#7 (215 o C BHST) in 2001 Use of Cs-weighted oil-based completion fluids for oil reservoirs : Visund, Statfjord, Njord, Gullfaks, Snorre, Oseberg, Rimfaks 2001 – present First use of Cs-weighted LSOBM as perforating completion fluid (Visund) First use of K/Cs formate brine : Completion job in Shearwater well (Shell UK) Cs-weighted LSOBM used as OH screen completion fluid (Statfjord) First use of K/Cs formate brine as HPHT well suspension fluid (Elgin) Individual Draugen oil wells (1993) and Visund oil wells (2003) have similar flow rates of around 50,000 bbl oil/day First of 14 Kvitebjørn HPHT wells drilled and completed with K/Cs formate brines
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The first sustained use of K/Cs formate brine was in the world’s largest HPHT gas field development Cesium formate brine used by TOTAL in 34 well construction operations in 8 deep gas fields in period 1999-2010 Elgin/Franklin field – UK North Sea
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Formate brines – Some published milestones 2005 -2010 200520062007200820092010 OMV Pakistan start using K formate to drill and complete (with ESS) in HPHT gas wells K/Cs formate brines used as well perforating fluids in 11 HPHT gas fields in UK North Sea : Dunbar, Shearwater, Elgin, Devenick, Braemar, Rhum, Judy, Glenelg, Kessog, Jura and West Franklin 1999-2011 Saudi Aramco start using K formate to drill and complete (with ESS) in HPHT gas wells Gravel pack with K formate brine in Statfjord B First MPD operation in Kvitebjørn with K/Cs formate “designer fluid” First of 12 completions in the Kashagan field with K/Cs formate Total’s West Franklin F9 well (204 o C) perforated in K/Cs formate brine Petrobras use K formate brine for open hole gravel packs in Manati field
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Saudi Aramco have been drilling HPHT gas wells with potassium formate brine since 2003
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